Maxwell, James Clerk
MAXWELL, JAMES CLERK
(b. Edinburgh, Scotland, 13 June 1831; d. Cambridge, England, 5 November 1879)
Maxwell was a descendant of the Clerks of Penicuik, a family prominent in Edinburgh from 1670 on, who had twice intermarried during the eighteenth century with the heiresses of the Maxwells of Middlebie, illegitimate offspring of the eighth Lord Maxwell. His father, John Clerk (Maxwell), younger brother of Sir George Clerk, M.P., inherited the Middlebie property and took the name Maxwell in consequence of some earlier legal manipulations which prevented the two family properties being held together. The estate, some 1,500 acres of farmland near Dalbeattie in Galloway (southwestern Scotland), descended to Maxwell; and much of his scientific writing was done there. Maxwell’s mother was Frances Cay, daughter of R. Hodshon Cay, a member of a Northumbrian family residing in Edinburgh. She died when he was eight years old. On both parents’ sides Maxwell inherited intellectual traditions connected with the law, as was common in cultivated Edinburgh families. John Clerk Maxwell had been trained as an advocate, but his chief interest was in practical, technical matters. He was a fellow of the Royal Society of Edinburgh and published one scientific paper, a proposal for an automatic-feed printing press. Maxwell’s father was a Presbyterian and his mother an Episcopalian. Maxwell himself maintained a strong Christian faith, with a strain of mysticism which has affinities with the religious traditions of the Galloway region, where he grew up.
From 1841 Maxwell attended Edinburgh Academy, where he met his lifelong friend and biographer, the Platonic scholar Lewis Campbell, and P. G. Tait. He entered Edinburgh University in 1847 and came under the influence of the physicist and alpinist James David Forbes and the metaphysician Sir William Hamilton. In 1850 he went up to Cambridge (Peterhouse one term, then Trinity), where he studied under the great private tutor William Hopkins and was also influenced by G. G. Stokes and William Whewell. He graduated second wrangler and first Smith’s prizeman (bracketed equal with E. J. Routh) in 1854. He became a fellow of Trinity in 1855. Maxwell held professorships at Marischal College, Aberdeen, and King’s College, London, from 1856 to 1865, when he retired from regular academic life to write his celebrated Treatise on Electricity and Magnetism and to put into effect a long-cherished scheme for enlarging his house. During the four years 1866, 1867, 1869, and 1870, he also served as examiner or moderator in the Cambridge mathematical tripos, instituting some widely praised reforms in the substance and style of the examinations. In 1871 he was appointed first professor of experimental physics at Cambridge and planned and developed the Cavendish Laboratory. On 4 July 1858 he married Katherine Mary Dewar, daughter of the principal of Marischal College and seven years his senior. They had no children. He died in 1879 at the age of forty-eight from abdominal cancer.
Maxwell’s place in the history of physics is fixed by his revolutionary investigations in electromagnetism and the kinetic theory of gases, along with substantial contributions in several other theoretical and experimental fields: (1) color vision, (2) the theory of Saturn’s rings, (3) geometrical optics, (4) photoelasticity, (5) thermodynamics, (6) the theory of servomechanisms (governors),(7) viscoelasticity, (8)reciprocal diagrams in engineering structures, and (9) relaxation processes. He wrote four books and about one hundred papers. He was joint scientific editor with T. H. Huxley of the famous ninth edition of the Encyclopaedia Britannica, to which he contributed many articles. His grasp of both the history and the philosophy of science was exceptional, as may be seen from the interesting philosophical asides in his original papers and from his general writings. His Unpublished Electrical Researches of the Hon. Henry Cavendish (1879) is a classic of scientific editing, with a unique series of notes on investigations suggested by Cavendish’s work.
It was Maxwell’s habit to work on different subjects in sequence, sometimes with an interval of several years between successive papers in the same field. Six years elapsed between his first and second papers on electricity (1855, 1861), twelve years between his second and third major papers on kinetic theory (1867, 1879). The account of his work must therefore be grouped by subject rather than in strict chronological order; a description of his juvenile papers and the studies on color vision and Saturn’s rings is useful in illustrating his intellectual development up to 1859.
Juvenilia (1845–1854). Maxwell’s first paper was published when he was fourteen years old. It followed the efforts of D. R. Hay, a well-known decorative artist in Edinburgh, to find a method of drawing a perfect oval similar to the string property of the ellipse. Maxwell discovered that when the string used for the ellipse is folded back on itself n times toward one focus and m times toward the other, a true oval is generated, one of the kind first studied by Descartes in connection with the refraction of light. Although Descartes had described ways of generating the curves, Maxwell’s method was new. His father showed the results to J. D. Forbes, who secured publication in the Proceedings of the Royal Society of Edinburgh. Shortly afterward Maxwell wrote a remarkable manuscript, which is reproduced in facsimile by his biographers, on the geometrical and optical properties of ovals and related curves of higher order. It afforded a foretaste of two of his lifelong characteristics: thoroughness and a predilection for geometrical reasoning. Both qualities, traditional in Scottish education, were powerfully reinforced for Maxwell by his teacher at Edinburgh Academy, James Gloag, a man of “strenuous character and quaint originality” to whom “mathematics was a mental and moral discipline.”1
Three of Maxwell’s next four papers were on geometrical subjects. One, “On the Theory of Rolling Curves” (1848), analyzed the differential geometry of families of curves generated like the cycloid, by one figure rolling on another. Another (1853) was a brief investigation in geometrical optics, leading to the beautiful discovery of the “fish-eye” lens. The third was “Transformation of Surfaces by Bending,” which extended work begun by Gauss. The only paper from this period with a strictly physical subject was “On the Equilibrium of Elastic Solids,” written in 1850 shortly before Maxwell went up to Cambridge. In 1847 he had been taken by his uncle John Cay to visit the private laboratory of the experimental optician William Nicol, from whom he received a pair of polarizing prisms. With these he investigated the phenomenon of induced double refraction in strained glass, which had been discovered in 1826 by another famous Scottish experimenter, Sir David Brewster. Maxwell’s studies led him to the papers of Cauchy and Stokes. He developed a simple axiomatic formulation of the general theory of elasticity, solved various problems, and offered a conjectural explanation of induced double refraction based on strain functions. The alternative interpretation based on stress functions had been given earlier by F. E. Neumann, but Maxwell’s theory was independent and better. The usefulness of photoelastic techniques in studying stress distributions in engineering structures is well-known: retrospectively the paper is even more important as Maxwell’s first encounter with continuum mechanics. Its significance for his researches on the electromagnetic field and (more surprisingly) gas theory will shortly appear.
Color Vision (1850–1870). Maxwell created the science of quantitative colorimetry. He proved that all colors may be matched by mixtures of three spectral stimuli, provided subtraction as well as addition of stimuli is allowed. He revived Thomas Young’s three-receptor theory of color vision and demonstrated that color blindness is due to the ineffectiveness of one or more receptors. He also projected the first color photograph and made other noteworthy contributions to physiological optics.
Credit for reviving Young’s theory of vision is usually given to Helmholtz. His claim cannot be sustained. The paper it is based on, published in 1852, contained useful work, but Helmholtz overlooked the essential step of putting negative quantities in the color equations and explicitly rejected the three-receptor hypothesis;2 and although Grassmann in 1854 pointed out fallacies in his reasoning, there is no evidence that Helmholtz followed the argument through to a conclusion until after Maxwell’s work appeared. Artists had indeed known centuries before Maxwell or Helmholtz that the three so-called primary pigments, red, yellow, and blue, yield any desired hue by mixture; but several things clouded interpretation of the phenomena and hindered acceptance of Young’s idea. One was the weight of Newton’s claim that the prismatic spectrum contains seven primary colors rather than three. Another was the cool reception given to Young’s theory of light, which extended to his theory of vision. The course of speculation between Young and Maxwell has never been clearly charted. In Britain the three-receptor theory did nearly gain acceptance during the 1820’s. It was favorably discussed by John Herschel and Dalton as well as by Young: Herschel in particular suggested that Dalton’s red blindness might come from the absence of one of Young’s three receptors.3 A curious complication supervened, however. During the 1830’s Brewster performed experiments with absorption filters by which he claimed to demonstrate the existence of three kinds of light, distributed in various proportions throughout the spectrum. Color according to him was thus an objective property of light, not a physiological function of the human eye. Brewster’s interpretations were founded on his stubborn belief in the corpuscular theory of light, but the experiments seemed good and were accepted even by Herschel until Helmholtz eventually traced the effects to imperfect focusing. During the same period from 1830 on, wide general progress was made in physiological optics throughout Europe, in which the names of Purkinje, Haidinger, Johannes Müller, and Wartmann are memorable. In Britain the first statistical survey of color deficiency was conducted by George Wilson of Edinburgh—the chemist, and biographer of Cavendish—who brought to the subject a nice touch of topical alarmism through his lurid warnings about the dangers inherent in nighttime railway signaling. It was in an appendix to Wilson’s monograph On Colour Blindness (1855) that Maxwell’s first account of his researches appeared.
Maxwell began experiments on color mixing in 1849 in Forbes’s laboratory at Edinburgh. At that time Edinburgh was unusually rich in students of color: besides Forbes, Wilson, and Brewster, there were William Swan, a physician interested in the eye, and D. R. Hay, who, in addition to his work in the geometry of design, had written a book entitled Nomenclature of Colours (1839) and supplied Forbes and Maxwell with tinted papers and tiles for their investigations. The experiments consisted in observing hues generated by colored sectors on a rapidly spinning disk. Forbes first repeated a standard experiment in which a series of colors representing those of the spectrum combine to give gray. He then tried to produce gray from combinations of red, yellow, and blue but failed—“and the reason was found to be, that blue and yellow do not make green, but a pinkish tint, when neither prevails in the combination.”4 No addition of red to this could produce a neutral tint.
Using a top with adjustable sectors of tinted paper, Forbes and Maxwell went on to obtain quantitative color equations, employing red, blue, and green as primaries. Interestingly, Young, in one little-known passage, had made the same substitution.5 The standard rules for mixing pigments were explained by Maxwell, and independently by Helmholtz, as a secondary process, with the pigments acting as filters to light reflected from the underlying surface.
In 1854, after his graduation from Cambridge, Maxwell was able to resume these researches, which Forbes had been compelled by a severe illness to abandon. He improved the top by adding a second set of adjustable sectors of smaller diameter than the first, to make accurate color comparisons, and obtained equations for several groups of observers which could be manipulated algebraically in a consistent manner. For color-deficient observers only two variables were needed. Maxwell then went on to prove that Newton’s method of displaying colors on a circle with white at the center implicitly satisfies the three-receptor theory, since it is equivalent to representing each color datum by a point in a threedimensional space. With the experimental results plotted on a triangle having red, blue, and green corners, after the method of Young and Forbes, there is a white point w inside and an ordered curve of spectral colors outside the triangle very similar to Newton’s circle. Adapting terminology from D. R. Hay, Maxwell distinguished three new variables—hue (spectral color), tint (degree of saturation), shade (intensity of illumination)—corresponding to “angular position with respect to w, distance from w, and coefficient [of intensity].” There is an easy transformation from these variables and to the representation of colors as a sum of three primaries: hence “the relation between the two methods of reducing the elements to three becomes a matter of geometry.”6 All this is most modern. In later correspondence with Stokes (1862), Maxwell described manipulations of color coordinates to reduce data from different observers to a common white point. The advantages of this procedure were also pointed out by C. J. Monro in a letter to Maxwell, dated 3 March 1871, which was published in Campbell and Garnett’s Life of James Clerk Maxwell (1882), although other workers in colorimetry entirely ignored the idea until Ives and Guild rediscovered it fifty years later.7
To go further, a new instrument less susceptible than the color top to conditions of illumination and properties of paper was called for. Accordingly Maxwell devised what he called his “colour-box,” in which mixtures of spectral stimulants were directly compared with a matching white field. The original version, perfected in 1858, consisted of two wooden boxes, each about three feet long, joined at an angle, containing a pair of refracting prisms at the intersection. An eyepiece was placed at one end; at the other were three slits, adjustable in position and aperture, which could be set at positions corresponding to any three wavelengths A, B, C in the spectrum formed by projecting white light through the eyepiece. By the principle of reciprocity, white light entering the slits yielded mixtures of A, B, C at the eyepiece, with intensities determined by the widths of the slits. Light from the same source (a sheet illuminated by sunlight) entered another aperture and was reflected past the edge of the second prism to the eyepiece, where the observer saw, side by side, two fields which he could match in hue and intensity. The spectrum locus determined by Maxwell’s observer K (his wife) is shown in Figure 1, together with the results of König and Abney (1903, 1913) and the 1931 standard observer. The Maxwells come out of the comparison rather well. Maxwell designed two other “colourboxes” on the same general principle. The second was made portable by the use of folded optics on the principle afterward adapted to the spectroscope by Littrow. The third gave hues of exceptional spectral purity by adopting a “double monochromator” principle, illuminating the slits with the spectrum from a second train of prisms symmetrically disposed rather than with direct sunlight. With it Maxwell studied variations of color sensitivity across the retina, a subject he had become interested in through his observations of the “Maxwell spot.”
––– ○ Maxwell 1860 (observer K)
––– □ König, Abney 1903, 1913 (recalculated Weaver)
—— • C.I.E. standard observer 1931 (Wright, Guild)
Most people, when they look at an extended source of polarized light, intermittently perceive a curious pair of yellow structures resembling a figure eight, with purple wings at the waist. These are the “brushes” discovered by Haidinger in 1844. They may be seen especially clearly by looking at a blue surface through a Nicol prism. Maxwell studied them with the prisms he had received from Nicol; and at the British Association meeting of 1850 he proposed attributing them to a polarizing structure in the yellow spot on the retina, a hypothesis which brought him into an amusing confrontation with Brewster, who attributed them to the cornea.8 Maxwell’s explanation is now accepted. In 1855 he noticed, in the blue region of the spectrum formed by looking through a prism at a vertical slit, an elongated dark spot which moved up and down with the eye and possessed the same polarizing structure as Haidinger’s brushes. This is the Maxwell spot. Later his wife discovered that she could not see the spot, there being almost no yellow pigment on her retinas. Noticing also a large discrepancy between her white point and his, Maxwell then found that his own color matches contained much less blue in the extrafoveal region and he proceeded to investigate variations of sensitivity across the retina for a large number of observers. He was able to exhibit the yellow spot—as he wrote to C. J. Monro in 1870—to “all who have it,—and all have it except Col. Strange, F. R. S., my late father-in-law and my wife,—whether they be Negroes, Jews, Parsees, Armenians, Russians, Italians, Germans, Frenchmen, Poles, etc.”9 Summaries of the work appeared in two brief papers and in a delightful correspondence with Monro, which also contains an interesting discussion on differences in color nomenclature between ancient and modern languages.
In 1861 Maxwell projected the first trichromatic color photograph at the Royal Institution before an audience which included Faraday. The subject was a tartan ribbon photographed through red, green, and blue filters by Thomas Sutton, a colleague at King’s College, London, and then projected through the same filters. An odd fact which remained without explanation for many years was that the wet collodion plates used should not have given any red image, since that photographic process is completely insensitive to red. Yet contemporary descriptions make it clear that the colors were reproduced with some fidelity. In 1960 R. M. Evans and his colleagues at Kodak Research Laboratories, in a first-class piece of historical detective work, established that the red dyes in Maxwell’s ribbon also reflected ultraviolet light in a region just coinciding with a pass band in the ferric thiocyanate solution used as a filter. The “red” image was really obtained with ultraviolet light! The hypothesis is confirmed by the fact that the original red plate preserved at Cambridge is slightly out of focus, although Sutton carefully refocused the camera for visible red light. A repetition of the experiment under modern conditions gave a “surprisingly colorful reproduction of the original scene.”10
Saturn’s Rings (1855–1859) . In 1855 the topic of the fourth Adams prize at Cambridge was announced as an investigation of the motions and stability of the rings of Saturn. Some calculations on Saturn’s rings, treated as solid bodies, had been given as early as 1787 by Laplace. He established that a uniform rigid ring would disintegrate unless (1) it is rotating at a speed where the centrifugal force balances the attraction of the planet and (2) the ratio ρr/ρs of its density to the density of Saturn exceeds a critical value 0.8, such that the attractions between inner and outer portions of the ring exceed the differences between centrifugal and gravitational forces at different radii. Also, the motions of a uniform ring are dynamically unstable: any displacement from equilibrium leads to an increased attraction in the direction of displacement, precipitating the ring against the planet. Laplace conjectured, however, that the motion is somehow stabilized by irregularities in the mass distribution; and in his dogmatic way asserted that the rings of Saturn are irregular solid bodies. That was where the theory still stood in 1855; meanwhile, a new dark ring and further divisions in the existing rings had been observed, along with some evidence fox slow changes in the overall dimensions of the system during the 200 years since its discovery. The examiners, James Challis, Samuel Parkinson, and William Thomson (the future Lord Kelvin), called for explanations of each point and an investigation of dynamical stability on the hypothesis that the rings are: (1) solid, (2) fluid, (3) composed of “masses of matter not mutually coherent,”11 These were the questions on which Maxwell spent much time between 1855 and 1859 in the essay to which the prize was awarded.
Maxwell took up first the theory of the solid ring where Laplace had left it, and determined conditions for stability of a ring of arbitrary shape. Forming equations of motion in terms of the potential at the center of Saturn due to the ring, he obtained two restrictions on the first derivatives of the potential for uniform motion, and then, by a Taylor expansion, three more conditions on the second derivatives for stable motion. Maxwell next transformed these results into conditions on the first three coefficients of a Fourier series in the mass distribution. He was able to show that almost every conceivable ring was unstable except the curious special case of a uniform ring loaded at one point with a mass between 4.43 and 4.87 times the remaining mass. There the uneven distribution makes the total attraction act toward a point outside the ring in such a way that the instabilities affecting the moment of inertia are counteracted by a couple which alters the angular momentum. But such a ring would collapse under the uneven stress, and its lopsidedness would be plainly visible. The hypothesis of a solid ring is untenable.
In considering nonrigid rings Maxwell again utilized Fourier’s theorem, but in a different way, examining the stability of various rings by expanding disturbances in their form into a series of waves. He took as a starting model, with which more complex structures could later be compared, a ring of solid satellites, equally spaced and all of equal mass. The motions may be resolved into four components: rotation about Saturn with constant angular velocity ω and small displacement ρ, σ, ζ in directions radial, tangential, and normal to the plane of the ring, Normal displacements of any satellite are manifestly stable, for the components of attraction to the other bodies always constitute a restoring force. Tangential disturbances might be expected to be unstable, since the attractions to neighboring satellites are in the direction of displacement; but Maxwell discovered that radial and tangential waves of a given order may be coupled together in a stable manner because the radial motions generate Coriolis forces through the rotation about the planet, which counterbalance the gravitational forces due to tangential motions, Detailed analysis revealed four kinds of waves, grouped in two pairs, all of which are stable if the mass of the central body is great enough. The motions are rather complicated; and Maxwell, “for the edification of sensible image worshippers,”12 had a mechanical model constructed to illustrate them in a ring of thirty-six satellites. Waves of the first two kinds move in opposite directions with respect to a point on the rotating ring, with a velocity nearly equal to ω/n, where ω is the angular velocity of the ring and n the number of undulations, Thus if there are five undulations the wave velocity is 1/5 of the ring velocity. Each satellite describes an elliptical path about its mean position in a sense opposite to the rotation of the ring itself, the major axis of the ellipse being approximately twice the minor axis and King near the tangential plane. If the number of satellites is μ, the highest-order waves, which are most likely to disrupt the ring, have μ/2 undulations. The stability criterion is
S and R being the masses of Saturn and the ring, Stability is determined by tangential forces; the parameter defining them must lie between 0 and 0.07ω2.
For rings of finite breadth Maxwell’s procedure was to examine simplified models which bracket the true situation. He began with rings whose inner and outer parts are so strongly bound together that the rotate uniformly. Such rings may be called semirigid. They are evidently subject to Laplace’s criterion of cohesion ρr/ρs > 0.8 but, like a ring of satellites, are also subject to conditions of stability against tangential disturbances. Maxwell established that tangential forces disrupt a semirigid ring of particles unless ρr/ρs < 0.003 and the of incompressible fluid unless ρr/ρs < 0.024. Since neither is compatible with Laplace’s criterion, neither kind of semirigid ring is stable. Various arguments then disposed of other gaseous and liquid rings, leaving as the only stable structute concentric circles of small satellites, each moving at a speed appropriate lo its distance from Saturn. Such rings cannot be treated independently: they attract one another. Maxwell presented a lengthy investigation of mutual perturbations between two rings. Usually they are stable; but at certain radii waves of different order may come into resonance and cause disruption, making particles fly off in all directions and collide with other rings. Maxwell estimated the rate of loss of energy and concluded that the whole system of rings would slowly spread out, as the observations indicated. He did not then study the general problem of motion among colliding bodies, but his unpublished manuscripts include one from 1863 applying the statistical methods that he later developed in the kinetic theory of gases to Saturn’s rings.
In 1895 A. A. Belopolsky and C. Keeler independently confirmed the differential rotation of the rings by spectroscopic observations. Later the gaps between successive rings were attributed to resonance between orbital motions of the primary satellites of Saturn and local ring oscillations. More recently A. F. Cook and F. A. Franklin, using kinetic theory techniques, have shown that heat generated in collisions makes the rings expand in thickness unless it is removed by radiation, and have obtained closer restrictions on structure and density. Maxwell’s density limit ρr/ρs > 0.003 hits sometimes been interpreted as a limit on the actual rings; in reality it applies only to semirigid rings, where stability depends on tangential forces. With differential rotation the tangential waves are heavily damped and stability depends on radial motions. The true upper limit on ρr/ρs appears to be in the range 0.04 to 0.20. Spectroscopic evidence suggests the particles may be crystals of ice or carbon dioxide.13
The essay tin Saturn’s rings illustrates Maxwell’s debt to Cambridge as sharply as the experiments on color vision reveal his debt to Edinburgh. It also established his scientific maturity. Success with a classical problem of such magnitude gave a mathematical self-assurance vitally important to his later work. Many letters testify to the concentrated effort involved, not the least interesting amongst them being one to a Cambridge friend, H. R. Droop: “I am very busy with Saturn on top of my regular work. He is all remodelled and recast, but I have more to do to him yet for I wish to redeem the character of mathematicians and make it intelligible.”14 To the graceful literary style and analytical clarity established there, two further broad qualities were added in Maxwell’s work over the next two decades. The great papers of the 1860’s continued at much the same level of analytical technique, with epoch-making advances in physical and philosophic insight. The books and articles of the 1870’s display growing mastery of mathematical abstraction in the use of matrices, vectors and quaternions, Hamiltonian dynamics, special functions, and considerations of symmetry and topology. The contrasting ways in which these different phases of Maxwell’S mature researches reflect his interaction with his contemporaries and his influence on the next scientific generation form a fascinating study which has not yet received due attention.
Electricity, Magnetism, and the Electromagnetic Theory of Light (1854 1879) . Maxwell’s electrical researches began a few weeks after his graduation from Cambridge in 1854, and ended just before his death twenty-live years later with a referee’s report on a paper by G. F. FitzGerald. They fall into two broad cycles, with 1868 roughly the dividing point: the first a period of five major papers on the foundations of electromagnetic theory, the second a period of extension with the Treatise on Electricity and Magnetism, the Elementary Treatise on Electricity, and a dozen shorter papers on special problems. The position of the Treatise is peculiar. Most readers come to it expecting a svstemalie exposition of its authors ideas which makes further reference to earlier writings unnecessary. With many writers the expectation might be legitimate; with Maxwell it is a mistake. In a later conversation he remarked that the aim of the Treatise was not to expound his theory finally to the world but to educate himself by presenting a view of the stage he had reached.15 This is a clue well worth pondering. The truth is that by 1868 Maxwell had already begun to think beyond his theory. He saw electricity not as just another branch of physics but as a subject of unique strategic importance, “as an aid to the interpretation of nature … and promoting the progress of science.”16 Wishing, therefore, to follow up questions with wider scientific ramifications, he gave the Treatise a loose-knit structure, organized on historical and experimental rather than deductive lines. Ideas are exhibited at different phases of growth in different places; different sections are developed independently, with gaps, inconsistencies, or even flat contradictions in argument. It is a studio rather than a finished work of art. The studio, being Maxwell’S. is tidily arranged; and once one has grasped what is going on, it is wonderfully instructive to watch the artist at work; but anyone who finds himself there unawares is courting bewilderment, the more so if he overlooks Maxwells advice to read the four parts of the Treatise in parallel rather than in sequence. It is, for example, disconcerting to be told on reaching section 585, halfway through volume II , that Maxwell is now about to “begin again from a new foundation without any assumption except those of the dynamical theory as stated in Chapter VII ,” Similar difficulties occur throughout, The next fifty years endorsed Maxwells judgment about the special importance of electricity to physics as a whole, His premature death occurred just as his ideas were gaining adherents and he was starting an extensive revision of the Treatise. Not the least unfortunate consequence was that the definitive exposition of his theory which he intended was never written.
Seen in retrospect, the course of physics up to about 1820 is a triumph of the Newtonian scientific program. The “forces” of nature—heat, light, electricity, magnetism, chemical action—were being progressively reduced to instantaneous attractions and repulsions between the particles of a series of fluids. Magnetism and static electricity were already known to obey inverse-square laws similar to the law of gravitation. The first forty years of the nineteenth century saw a growing reaction against such a division of phenomena in favor of some kind of “correlation of forces.” Oersted’s discovery of electromagnetism in 1820 was at once the first vindication and the most powerful stimulus of the new tendency, yet at the same time it was oddly disturbing. The action he observed between an electric current and a magnet differed from known phenomena in two essential ways: it was developed by electricity in motion, and the magnet was neither attracted to nor repelled by—but set transversely to—the wire carrying the current. To such a strange phenomenon widely different reactions were possible. Faraday took it as a new irreducible fact by which his other ideas were to be shaped. Andrè Marie Ampere and his followers sought to reconcile it with existing views about instantaneous action at a distance.
Shortly after Oersted’S discovery Ampère discovered that a force also exists between two electric currents and put forward the brilliant hypothesis that all magnetism is electrical in origin. In 1826 he established a formula (not to be confused with the one attached to his name in textbooks) which reduced the known magnetic and electromagnetic phenomena to an inverse-square force along the line joining two current elements idl, i’ dl’ separated by a distance r,
where G is a complex geometrical factor involving the angles between r, dl, and dl’. In 1845 F. E. Neumann derived the potential function corresponding to Ampère’s force and extended the theory to electromagnetic induction. Another extension developed by Wilhelm Weber was to combine Ampere’s law with the law of electrostatics to form a new theory, which also accounted for electromagnetic induction, treating the electric current as the flow of two equal and opposite groups of charged particles, subject to a force whose direction was always along the line joining two particles e, e’, but whose magnitude depended on their relative velocity ṙ and relative acceleration r̈ along that line,
c being a constant with dimensions of velocity. In 1856 Kohlrausch and Weber determined c experimentally by measuring the ratio of electrostatic to electrodynamic forces. Its value in the special units of Weber’s theory was about two-thirds the velocity of light. Equations (2) and (3) and Neumann’s potential theory provided the starting points for almost all the work done in Europe on electromagnetic theory until the 1870’s.
The determining influences on Maxwell were Faraday and William Thomson. Faraday’s great discoveries—electromagnetic induction, dielectric phenomena, the laws of electrochemistry, diamagnetism, magneto-optical rotation—all sprang from the search for correlations of forces. They formed, in Maxwell’s words, “the nucleus of everything electric since 1830.”17 His contributions to theory lay in the progressive extension of ideas about lines of electric and magnetic force. His early discovery of electromagnetic rotations (the first electric motor) made him skeptical about attractive and repulsive forces, and his ideas rapidly advanced after 1831 with his success in describing electromagnetic induction by the motion of lines of magnetic force through the inductive circuit. In studying dielectric and electrolytic processes he imagined (wrongly) that their transmission in curved lines could not be reconciled with the hypothesis of direct action at a distance, attributing them instead to successive actions of contiguous portions of matter in the space between charged bodies. In his work on paramagnetism and diamagnetism he conceived the notion of magnetic conductivity (permeability); and finally, in the most brilliant of his conceptual papers, written in 1852, when he was sixty, he extended the principle of contiguous action in a general qualitative description of magnetic and electromagnetic phenomena, based on the assumption that lines of magnetic force have the physical property of shortening themselves and repelling each other sideways. A quantitative formulation of the last hypothesis was given by Maxwell in 1861.
Thomson’s contribution began in 1841, while he was an undergraduate at Cambridge. His first paper established a formal analogy between the equations of electrostatics and the equations for flow of heat. Consider a point source of heat P embedded in a homogeneous conducting medium. Since the surface area of a sphere is 4πr2 the heat flux ø through a small area dS at a distance r from P is proportional to 1/r2 in analogy with Coulomb’s electrostatic law; thus by appropriate substitution a problem in electricity may be transposed into one in the theory of heat. Originally Thomson used the analogy as a source of analytical technique; but in 1845 he went on to examine and dispose of Faraday’s widely accepted claim that dielectric action cannot be reconciled with Coulomb’s law and, conversely, to supply the first exact mathematical description of lines of electric force. Later Thomson and Maxwell between them established a general similitude among static vector fields subject to the conditions of continuity and incompressibility, proving that identical equations describe (1) streamlines of frictionless incompressible fluids through porous media, (2) lines of flow of heat, (3) current electricity, and (4) lines of force in magnetostatics and electrostatics.
Since it was Thomson’s peculiar genius to generate powerful disconnected insights rather than complete theories, much of his work is best described piecemeal along with Maxwell’s; but certain of his ideas from the 1840’s may first be mentioned, notably the method of electric images, a second formal analogy between magnetic forces and rotational strains in an elastic solid, and, most important, the many applications of energy principles to electricity which followed his involvement with thermodynamics. Amongst other things Thomson is responsible for the standard expressions and for energy in an inductance and in a condenser. He and (independently) Helmholtz also applied energy principles to give an extraordinarily simple derivation of Neumann’s induction equation. It so happened that the discussion of energy principles had a curious two-sided impact on Weber’s hypothesis. In 1846 Helmholtz presented an argument which seemed to show that the hypothesis was inconsistent with the principle of conservation of energy. His conclusion was widely accepted and formed one of the grounds on which Maxwell opposed the theory, but in 1869 Weber succeeded in rebutting it. By then, however, Maxwell had developed his theory, and the implication of the Thomson-Helmholtz argument had become clearer: that any theory which is consistent with energy principles automatically predicts induction. In retrospect, therefore, although Helmholtz was wrong in his first criticism, the agreement between Weber’s theory and experiment was also less compelling than Weber and his friends had supposed.
Maxwell’s first paper, “On Faraday’s Line of Force” (1855–1856), was divided into two parts, with supplementary) examples. Its origin may he traced in a long correspondence with Thomson, edited by Larmor in 1936.18 Part 1 was an exposition of the analogy between lines of force and streamlines in an incompressible fluid. It contained one notable extension to Thomson’s treatment of the subject and also an illuminating opening discourse on the philosophical significance of analogies between different branches of physics. This was a theme to which Maxwell returned more than once. His biographers print in full an essay entitled “Analogies in Nature,” which he read a few months later (February 1856) to the famous Apostles Club at Cambridge; this puts the subject in a wider setting and deserves careful reading despite its involved and cryptic style. Here, as elsewhere, Maxwell’s metaphysical speculation discloses the influence of Sir William Hamilton, specifically of Hamilton’s Kantian view that all human knowledge is of relations rather than of things. The use Maxwell saw in the method of analogy was twofold. It crossfertilized technique between different fields, and it served as a golden mean between analytic abstraction and the method of hypothesis. The essence of analogy (in contrast with identity) being partial resemblance, its limits must be recognized as clearly as its existence; yet analogies may help in guarding against too facile commitment to a hypothesis. The analogy of an electric current to two phenomena as different as conduction of heat and the motion of a fluid should, Maxwell later observed, prevent physicists from hastily assuming that “electricity is either a substance like water, or a state of agitation like heat.”19 The analogy is geometrical: “a similarity between relations, not a similarity between the things related.”20
Maxwell improved the presentation of the hydrodynamic analogy chiefly by considering the resistive medium through which the fluid moves. When an incompressible fluid goes from one medium into another of different porosity, the flow is continuous but a pressure difference develops across the boundary. Also, when one medium is replaced by another of different porosity, equivalent effects may be obtained formally by introducing appropriate sources or sinks of fluid at the boundary. These results were an important aid to calculation and helped in explaining several processes that occur in magnetic and dielectric materials. Another step was to consider a medium in which the porosity varies with direction. The necessary equations had been supplied by Stokes in a paper on the conduction of heat in crystals. They led to the remarkable conclusion that the vector a which defines the direction of fluid motion is not in general parallel to α , the direction of maximum pressure gradient. The two functions are linked by the equation
where K is a tensor quantity describing the porosity. Applying the analogy to magnetism, Maxwell distinguished two vectors, the magnetic induction and the magnetic force, to which he later attached the symbols B and H . The parallel quantities in current electricity were the current density I and the electromotive intensity E . The distinction between B and H provided the key to a description of “magnecrystallic induction,” a force observed in crystalline magnetic materials by Faraday. Maxwell later identified the two quantities with the two definitions of magnetic force that Thomson had found to be required in developing parallel magnetostatic and electromagnetic theories of magnetism. The question of the two magnetic vectors B and H has disturbed several generations of students of electromagnetism. Maxwell’s discussion gives a far clearer starting point than anything to be found in the majority of modern textbooks on the subject.
This physical distinction based on the hydrodynamic analogy led Maxwell to make an important mathematical distinction between two classes of vector functions, which he then called “quantities” and “intensities,” later “fluxes” and “forces.” A flux a is a vector subject to the continuity equation and is integrated over a surface; a force α (in Maxwell’s generalized sense of the term) is a vector usually, but not always, derivable from a single-valued potential function and is integrated along a line. The functions B and I are fluxes; H and E are forces.
The close parallel that exists between electric currents and magnetic lines of force, which had been seen qualitatively by Faraday, was the concluding theme of Part 1 of Maxwell’s paper. Part 2 covered electromagnetism proper. In it Maxwell developed a new formal theory of electromagnetic processes. The starting point was an identity established by Ampère and Gauss between the magnetic effects of a closed electric current and those of a uniformly magnetized iron shell of the same perimeter. In analytic method the discussion followed Thomson’s “Mathematical Theory of Magnetism” (1851), as well as making extensive use of a theorem first proved by Thomson in 1847, in a letter to Stokes, and first published by Stokes as an examination question in the Smith’s prize paper taken by Maxwell in February 1854. This was the well-known equality (Stokes’s theorem) between the integral of a vector function around a closed curve and the integral of its curl over the enclosed surface. The original analysis given by Maxwell was Cartesian, but since in 1870 he himself introduced the terms “curl,” “divergence,” and “gradient” to denote the relevant vector operations, the notation may legitimately be modernized. The relationship between the flux and force vectors a and α contained in equation (4) has already been discussed. Pursuing a line of analysis started by Thomson, Maxwell now proceeded to show that any flux vector a may be related to a second, distinct force vector α , through the equation
where β is a scalar function. Applying (4), (5) and other equations, Maxwell obtained a complete set of equations between the four vectors E, I, B, H , which describe electric currents and magnetic lines of force. He then went on to derive another vector function, for which he afterward used the symbol A , such that
where the second term on the right-hand side may, in the absence of free magnetic poles, be eliminated by appropriate change of variables. Maxwell proved that the electromotive force E developed during induction is −δ/δt and that the total energy of an electromagnetic system is ∫ I · A dv. Thus the new function provided equations to represent ordinary magnetic action, electromagnetic induction, and the forces between closed currents. Maxwell called it the electrotonic function, following some speculations of Faraday’s about a hypothetical state of stress in matter, the “electrotonic state.” Later he identified it as a generalization of Neumann’s electrodynamic potential and established other properties (to be discussed shortly).
The 1856 paper has been eclipsed by Maxwell’s later work, but its originality and importance are greater than is usually thought. Besides interpreting Faraday’s work and giving the electrotonic function, it contained the germ of a number of ideas which Maxwell was to revive or modify in 1868 and later: (1) an integral representation of the field equations (1868), (2) the treatment of electrical action as analogous to the motion of an incompressible fluid (1869, 1873), (3) the classification of vector functions into forces and fluxes (1870), and (4) an interesting formal symmetry in the equations connecting A, B, E , and H , different from the symmetry commonly recognized in the completed field equations. The paper ended with solutions to a series of problems, including an application of the electrotonic function to calculate the action of a magnetic field on a spinning conducting sphere.
Maxwell’s next paper, “On Physical lines of Force” (1861–1862), began as an attempt to devise a medium occupying space which would account for the stresses associated by Faraday with lines of magnetic force. It ended with the stunning discovery that vibrations of the medium have properties identical with light. The original aim was one Maxwell had considered in 1856, and although he explicitly rejected any literal interpretation of the analogy between magnetic action and fluid motion, the meaning of the analogy can be extended by picturing a magnet as a kind of suction tube which draws in fluid ether at one end and expels it from the other. That idea had been suggested by Euler in 1761;21 it leads to a most remarkable result first published by Thomson in 1870 but probably known to Maxwell earlier.22 Geometrically the flow between two such tubes is identical with the lines of force between two magnets, but physically the actions are reciprocal: like ends of the tubes are attracted according to the inverse-square law; unlike ends are repelled. The difference is that in a fluid the Bernoulli forces create a pressure minimum where the streamlines are closest, while Faraday’s hypothesis requires a pressure maximum.
The clue to to a medium having a right stress distribution came from an unexpected source. During the 1840’s the engineer W. J. M. Rankine (who like Maxwell had been a student of Forbes’s at Edinburgh) worked out a new theory of matter with applications to thermodynamics and the properties of gases, based on the hypothesis that molecules are small nuclei in an ethereal atmosphere, fixed in space but rotating at speeds proportional to temperature. In 1851 Thomson refereed one of Rankine’s papers. He was then concerning himself with thermodynamics, but five years later it dawned on him that molecular rotation was just the thing to account for the magneto-optical effect.23 Faraday had observed a slight rotation in the plane of polarization of light passing through a block of glass between the poles of a magnet. Using an analogy with a pendulum suspended from a spinning arm, Thomson concluded that the effect could be attributed to coupling between the ether vibrations and a spinning motion of the molecules of glass about the lines of force. Maxwell’s theory of physical lines of force consisted in extending this hypothesis of rotation in the magnetic field from ordinary matter to an ether. The influence of Thomson and Rankine is established by direct reference and by Maxwell’s use of Rankine’s term “molecular vortices” in the titles of each of the four parts of the paper. The charm of the story is that barely twelve months had passed since Maxwell had given the death blow to Rankine’s theory of gases through his own work on kinetic theory.
Consider an array of vortices embedded in incompressible fluid. Normally the pressure is identical in all directions, but rotation causes centrifugal forces which make each vortex contract longitudinally and exert radial pressure. This is exactly the stress distribution proposed by Faraday for physical lines of force. By making the angular velocity of each vortex proportional to the local magnetic intensity, Maxwell obtained formulas identical with the existing theories for forces between magnets, steady currents, and diamagnetic bodies. Next came the problem of electromagnetic induction. It required some understanding of the action of electric currents on the vortex medium. That tied in with another question: how could two adjacent vortices rotate freely in the same sense, since their surfaces move in opposite directions? Figure 2, reproduced from Part 2 of the paper, illustrates Maxwell’s highly tentative solution. Each vortex is separated from its neighbors by a layer of minute particles, identified with electricity, counter-rotating like the idle wheels of a gear train.
On this view electricity, instead of being a fluid confined to conductors, becomes an entity of a new kind, disseminated through space. In conductors it is free to move (though subject to resistance); in insulators (including the ultimate insulator, space) it remains fixed. The magnetic and inductive actions of currents are then visualized as follows. When a current flows in a wire A, it makes the adjacent vortices rotate; these in turn engage the next layer of particles and so on until an infinite series of vortex rings, which constitute lines of force, fills the surrounding space. For induction consider a second wire B with finite resistance, parallel to A. A steady current in A will not affect B; but any change in A will communicate an impulse through the intervening particles and vortices, causing a reverse current in B, which is then dissipated through resistance. This is induction. Quite unexpectedly
pectedly the model also suggested a physical interpretation of the electrotonic function. In analyzing machinery several engineers, including Rankine, had found it useful to add to the motion of a mechanical part terms incorporating effects of connected gears and linkages, which they called the “reduced” inertia or momentum of the system. Maxwell discovered that the electrotonic function corresponds to the reduced momentum of the vortex system at each point. The equation for induced electromotive force E =δA /δ t is the generalized electrical equivalent of Newton’s equation between force and rate of change of momentum.
There is good evidence internal and external to the paper that Maxwell meant originally to end here and did not begin Part 3 until Part 2 had been printed.24 Meanwhile, he had been considering the relation between electric currents and the induction of charge through a dielectric. In 1854 he had remarked to Thomson that a literal treatment of the analogy between streamlines and lines of electric force would make induction nothing more than an extreme case of conduction.25 Now, with the picture of electricity as disseminated in space, Maxwell hit upon a better description, based partly on Faraday’s ideas, by making the vortex medium elastic. The forces between charged bodies could be attributed to potential energy stored in the medium by elastic distortion, as magnetic forces are attributed to stored rotational energy; and the difference between conduction and static electric induction is analogous to the difference between viscous and elastic processes in matter.
Two amazing consequences swiftly followed. First, since the electric particles surrounding a conductor are now capable of elastic displacement, a varying current is no longer entirely confined like water in a pipe: it penetrates to some extent into the space surrounding the wire. Here was the first glimmering of Maxwell’s “displacement current.” Second, any elastic substance with density ρ and shear modulus m can transmit transverse waves with velocity . Making some ad hoc assumptions about the elastic structure of the vortex medium, Maxwell derived while he was in Scotland formulas connecting ρ and m with electromagnetic quantities, which implied a numerical relationship between v and Weber’s constant c. Returning to London for the academic year, Maxwell looked up the result of Kohlrausch and Weber’s experiment to determine c, and after putting their data in a form suitable for insertion into his equation he found that for a medium having a magnetic permeability μ equal to unity v was almost equal to the velocity of light. With excitement manifested in italics he wrote: “we can scarcely avoid the inference that light consists in the transverse undulations of the same medium which is the cause of electric and magnetic phenomena.”26 Thus the great discovery was made; and Maxwell, following a calculation on the dielectric properties of birefringent crystals, returned in Part 4 to his starting point, the magneto-optical effect, and replaced Thomson’s spinning pendulum analogy with a more detailed theory in better accord with experiment.
In 1861 the British Association formed a committee under Thomson’s chairmanship to determine a set of internationally acceptable electrical standards following the work of Weber. At Thomson’s urging, a new absolute system of units was adopted, similar to Weber’s, but based on energy principles rather than on a hypothetical electrodynamic force law. The first experiment was on the standard of resistance, and in 1862 Maxwell was appointed to the committee to help with that task. His third paper, “On the Elementary Relations of Electrical Quantities,” written in 1863 with the assistance of Fleeming Jenkin, supplied a vital step in his development, often overlooked through its having been, most unfortunately, omitted from the Scientific Papers.27 Extending a procedure begun by Fourier in the theory of heat, Maxwell set forth definitions of electric and magnetic quantities related to measures M, L, T of mass, length, and time, to provide the first—and one may also think the most lucid—exposition of that dual system of electrical units commonly but incorrectly known as the Gaussian system.28 The paper introduced the notation, which was to become standard, expressing dimensional relations as products of powers of M, L, T enclosed in brackets, with separate dimensionless multipliers. For every quantity the ratio of the two absolute definitions, based on forces between electric charges and forces between magnetic poles, proved to be some power of a constant c with dimensions [LT-1] and magnitude times Weber’s constant, or very nearly the velocity of light. The analysis disclosed five different classes of experiments from which c might be determined. One was a direct comparison of electrostatic and electromagnetic forces carried out by Maxwell and C. Hockin in 1868, and two others were started by Maxwell at Cambridge in the 1870’s.29 The results of many experiments over the next few years progressively converged with the measured velocity of light.
By 1863, then, Maxwell had found a link of a purely phenomenological kind between electromagnetic quantities and the velocity of light. His fourth paper, “A Dynamical Theory of the Electromagnetic Field,” published in 1865, clinched matters. It provided a new theoretical framework for the subject, based on experiment and a few general dynamical principles, from which the propagation of electromagnetic waves through space followed without any special assumptions about molecular vortices or the forces between electric particles. This was the work of which Maxwell, in a rare moment of unveiled exuberance, wrote to his cousin Charles Cay, the mathematics master at Clifton College: “I have also a paper afloat, containing an electromagnetic theory of light, which, till I am convinced to the contrary, I hold to be great guns.”30
Several factors, scientific and philosophical, settled the disposition of Maxwell’s artillery. From the beginning he had stressed the provisional character of the vortex model, especially its peculiar gearing of particles and vortices. Rankine was a cautionary example. In an article on thermodynamics written in 1877 Maxwell illuminated his own thought by observing that the vortex theory of matter, which at first served Rankine well, later became an encumbrance, distracting his attention from the general considerations on which thermodynamic formulas properly rest.31 Maxwell wished to avoid that trap. Yet he did not abandon all the ground gained in 1862. The idea of treating light and electromagnetism as processes in a common medium remained sound. Furthermore, the new theory was, as the title of the paper stated, a dynamical one: the medium remained subject to the general principles of dynamics. The novelty consisted in deducing wave propagation from equations related to electrical experiments instead of from a detailed mechanism; that was why the theory became known as the electromagnetic theory of light. Again Sir William Hamilton’s influence is discernible. Maxwell’s decision to replace the vortex model of electromagnetic and optical processes by an analysis of the relations between the two classes of phenomena is a concretization of Hamilton’s doctrine of the relativity of knowledge: all human knowledge is of relations between objects rather than of objects in themselves.
More specifically the theory rested on three main principles. Maxwell retained the idea that electric and magnetic energy are disseminated, merely avoiding commitment to hypotheses about their mechanical forms in space. Here it is worth noticing that his formal expressions B. H /8π and D. E /8π for the two energy densities simply extend and interpret physically an integral transformation of Thomson’s.32 Next Maxwell revived various ideas about the geometry of lines of force from the 1856 paper. Third, and most important, he replaced the vortex hypothesis with a new macroscopic analogy between inductive circuits and coupled dynamical systems. The analogy seems to have germinated in Maxwell’s mind in 1863, while he was working out the theory of the British Association resistance experiment.33 In part it goes back to Thomson, especially to Thomson’s use of energy principles in the theory of the electric telegraph.34 It may be illustrated in various ways, of which the model shown in Figure 3, which Maxwell had constructed in 1874, is the most convenient.35 Two wheels, P and Q, are geared together through a
differential mechanism with adjustable flyweights. Rotations of P and Q represent currents in two circuits; the moments of inertia represent coefficients of induction; a frictional band attached to Q represents the resistance of the secondary circuit. Every feature of electromagnetic induction is seen here. So long as P rotates uniformly, Q remains stationary; but when P is started or stopped, a reverse impulse is transmitted to Q. This impulse is determined by the acceleration, the coefficient of coupling, and the inertia and resistance of Q, in exact analogy with an electrical system. Again the definitive quantity has the nature of momentum, determined in the mechanical model by the positions of the flyweights and in the electromagnetic analog by the geometry of the circuits. The total “electrokinetic momentum” p is Li + Σj Mjij, where L and i are the self-inductance and current in a particular circuit and the Mj’s and ij’s are the mutual inductances and currents of neighboring circuits. Since p is the integral of the function A round the circuit, the analogy carries through at the macroscopic level Maxwell’s identification of A with the “reduced momentum” of the field. Combined with conservation of energy, it also gives the mechanical actions between circuits. Helmholtz and Thomson had applied energy principles to deduce the law of induction from Ampère’s force law; Maxwell inverted and generalized their argument to calculate forces from the induction formulas. Thus his first analytic treatment of the electrotonic function was metamorphosed into a complete dynamical theory of the field.
In the Treatise Maxwell extended the dynamical formalism by a more thoroughgoing application of Lagrange’s equations than he had attempted in 1865. His doing so coincided with a general movement among British and European mathematicians about then toward wider use of the methods of analytical dynamics in physical problems. The course of that movement in Britain may be followed through Cayley’s two British Association reports on advanced dynamics of 1857 and 1862, Routh’s Treatise on the Dynamics of a System of Rigid Bodies (1860, 1868), and Thomson and Tait’s Treatise on Natural Philosophy (first edition 1867). Maxwell helped Thomson and Tait with comments on many sections of their text. Then, with the freshness of outlook that makes his work so appealing, he turned the current fad to his own ends by applying it to electromagnetism. Using arguments extraordinarily modern in flavor about the symmetry and vector structure of the terms, he expressed the Lagrangian for an electromagnetic system in its most general form. Green and others had developed similar arguments in studying the dynamics of the luminiferous ether, but the use Maxwell made of Lagrangian techniques was new to the point of being almost a new approach to physical theory—though many years were to pass before other physicists fully exploited the ground he had broken. The beauty of the Lagrangian method is that it allows new terms to be incorporated in the theory automatically as they arise, with a minimum of physical hypothesis. One that Maxwell devoted a chapter of the Treatise to was the magneto-optical effect. By a powerful application of symmetry considerations he put Thomson’s argument of 1856 on a rigorous basis and proved that any dynamical explanation of the rotation of the plane of polarized light must depend on local rotation in the magnetic field. In later terminology, the induction B is an axial vector, and the electrons in matter precess about the applied field: these are the elements of truth behind the molecular vortex hypothesis. Characteristically Maxwell did not limit his thinking to the general symmetry argument: he tested it by attempting to invent counter-examples. Elsewhere he wrote, “I have also tried a great many hypotheses [to explain the magneto-optical effect] besides those which I have published, and have been astonished at the way in which conditions likely to produce rotation are exactly neutralized by others not seen at first.”36 A further instance of the power of the Lagrangian methods, covered in the Treatise, is Maxwell’s analysis of cross-terms linking electrical and mechanical phenomena. This he did partly at the suggestion of J. W. Strutt (Lord Rayleigh)37. He identified three possible electromechanical effects, later detected by Barnett (1908), Einstein and de Haas (1916), and Tolman and Stewart (1916). The Barnett effect is a magnetic moment induced in a rapidly spinning iron bar. Maxwell himself had looked for the inverse phenomenon in 1861 during an experiment in search of the angular momentum of molecular vortices.
In 1865, and again in the Treatise, Maxwell’s next step after completing the dynamical analogy was to develop a group of eight equations describing the electromagnetic field. They are set out in the table with subsidiary equations according to the form adopted in the Treatise. The principle they embody is that electromagnetic processes are transmitted by the separate and independent action of each charge (or magnetized body) on the surrounding space rather than by direct action at a distance. Formulas for the forces between moving charged bodies may indeed be derived from Maxwell’s equations, but the action is not along the line joining them and can be reconciled with dynamical principles only by taking into account the exchange of momentum with the field.39 Maxwell remarked that the equations might be condensed, but “to eliminate a quantity which expresses a useful idea would be rather a loss than a gain in this stage of our enquiry.”40 He had in fact simplified the equations in his fifth major paper, the short but important “Note on the Electromagnetic Theory of Light” (1868), writing them in an integral form without the function A , based on four postulates derived from electrical experiments. This may be called the electrical formulation of the theory, in contrast with the original dynamical formulation. It was later independently developed by Heaviside and Hertz and passed into the textbooks. It has the advantage of compactness and analytical symmetry, but its scope is more restricted and to some extent it concealed from the next generation of physicists ideas familiar to Maxwell which proved important later on. Two points in the table deserve comment for the modern reader. Equations(B) and (C) appear slightly unfamiliar, because (B) contains terms defined for a particular laboratory frame of reference, while (C), the so-called Lorentz force formula, contains a term in grad Ω for the force on isolated magnetic poles, should such exist. Elsewhere in the Treatise41 Maxwell began the investigation of moving frames of reference, a subject which in Einstein’s hands was to revolutionize physics. The second point concerns the addition of the displacement current D to the
Note: Maxwell used S rather than I for electric current density.
current of conduction I’ . In Maxwell’s treatment (unlike later textbooks) the extra term appears almost without explanation, arising as it does from his analogy between the paired phenomena of conduction and static induction in electricity and viscous flow and elastic displacement in the theory of materials. More will be said below about the implications of Maxwell’s view.
Maxwell gave three distinct proofs of the existence of electromagnetic waves in 1865, 1868, and 1873. The disturbance has dual form, consisting in waves of magnetic force and electric displacement with motions perpendicular to the propagation vector and to each other. An alternative view given in the Treatise is to represent it as a transverse wave of the function A. In either version the theory yields strictly transverse motion, automatically eliminating the longitudinal waves which had embarrassed previous theories of light.
Among later developments, the generation and detection of radio waves by Hertz in 1888 stands supreme; but there were others of nearly comparable interest. In the Treatise Maxwell established that light, on the electromagnetic theory, exerts a radiation pressure. Radiation pressure had been the subject of much speculation since the early eighteenth century; before Maxwell most people had assumed that its existence would be a crucial argument in favor of a corpuscular rather than a wave theory of light. When William Crookes discovered his radiometer effect in 1874, shortly after the publication of Maxwell’s Treatise, some persons thought that he had observed radiation pressure, but the disturbance was much larger than the predicted value and in the wrong direction, and was caused, as will be explained below, by convection currents in the residual gas. Maxwell’s formula was confirmed experimentally by Lebedev in 1900. The effect has implications in many branches of physics. It accounts for the repulsion of comets’ tails by the sun; it is, as Boltzmann proved in 1884, critical to the theory of blackbody radiation; it may be used in deriving classically the time-dilation formula of special relativity; it fixes the mass-range of stars.
Another very fruitful new area of research started by Maxwell was on the connections between electrical and optical properties of bodies. He obtained expressions for the torque on a birefringent crystal suspended in an electric field, for the relation between refractive index and dielectric constant in transparent media, and for the relation between optical absorption and electrical conductivity in metals. In the long wavelength limit the refractive index may be expected on the simplest theory to be proportional to the square root of the dielectric constant. Measurements by Boltzmann, J. E. H. Gordon, J. Hopkinson, and others confirmed Maxwell’s formula in gases and paraffin oils, but in some materials (most obviously, water) they revealed large discrepancies. These and like problems, including Maxwell’s own observation of a discrepancy between the observed and predicted ratios of optical absorption to electrical conductivity in gold leaf, formed a basis for decades of research on electro-optical phenomena. Much of what was done during the 1880’s and 1890’s should be seen as the beginnings of modern research on solid-state physics, though a full interpretation waited on the development of the quantum theory of solids.
In classical optics Maxwell’s theory worked a revolution that is now rarely perceived. A popular fiction among twentieth-century physicists is that mechanical theories of the ether were universally accepted and universally successful during the nineteenth century, until shaken by the null result of the Micheslon-Morley experiment on the motion of the earth through the ether. This little piece of textbook folklore is wrong in both its positive and its negative assertions. More will be said below about the Micheslon-Morley experiment, but long before that the classical ether theories were beset with grave difficulties on their own ground. The problem was to find a consistent dynamical foundation for the wave theory of light. During the 1820’s Fresnel had given his well-known formulas for double refraction and for the reflection of polarized light; they were confirmed later with extraordinary experimental accuracy, but Eresne’s successors had immense trouble in reconciling them with each other on any mechanical theory of the ether. In 1862 Stokes summarized forty years of arduous research, during which a dozen different ethers had been tried and found wanting, by remarking that in his opinion the true dynamical theory of double refraction was yet to be found.42 In 1865 Maxwell obtained Fresne’s wave surface for double refraction from the electro-magnetic theory in the most straightforward way, completely avoiding the ad hoc supplementary conditions required in the mechanical theories. He did not then derive the reflection formulas, being uncertain about boundary conditions at high frequency;43 but in 1874 H. A. Lorentz obtained them also very simply, using the static boundary condition Maxwell had given in 1856. An equivalent calculation, probably independent, appears in an undated manuscript of Maxwell’s at Cambridge. The whole matter was investigated in two very powerful critical papers by Rayleigh (1881) and Gibbs (1888), and in the cycle of work begun by Thomson in his 1884 Baltimore Lectures. Rayleigh and Gibbs proved that Maxwell’s were the only equations that give formulas for refraction, reflection, and scattering of light consistent with each other and with experiment.44 Brief reference is appropriate here to James MacCullagh’s semi-mechanical theory of 1845, in which the ether was assigned a property of rotational elasticity different from the elastic properties of any ordinary substance. After Stokes in 1862 had raised formidable objections against the stability of MacCullagh’s medium, it was taken as disproved until FitzGerald and Larmor noticed a formal resemblance between MacCullagh’s and Maxwell’s equations. Since then the two theories have usually been considered homologous. In truth neither Stokes’s objections to, nor Larmor’s claims for, MacCullagh’s theory can be sustained. A dynamically stable medium with rotational elasticity supplied by gyrostatic action was invented by Thomson in 1889.45 On the other hand, whereas MacCullagh made kinetic energy essentially linear and elastic energy rotational. Maxwell identified magnetism with rotational kinetic energy and electrification with a linear elastic displacement. Very peculiar assumptions about the action of the ether on matter are necessary to carry MacCullagh’s theory through at the molecular level; Maxwell’s extends naturally and immediately to the ionic theory of matter. Even as an optical hypothesis, apart from its other virtues, the position of Maxwell’s theory is unique.
Maxwell’s statements about the luminiferous ether have an ambiguity which needs double care in view of the intellectual confusion of much twentieth-century comment on the subject. Selective quotation can make him sound as mechanistic as Thomson became in the 1880’s or as Machian as Einstein was in the early 1900’s. The Treatise concludes flatly that “there must be a medium or substance in which … energy exists after it leaves one body and before it reaches [an] other”;46 a later letter dismisses the ether as a “most conjectural scientific hypothesis.”47 Some remarks simply express the ultimate skepticism behind Maxwell’s working faith in science. Others hinge on the view he inherited from Whewell that reality is ordered in a series of tiers, each more or less complete in itself, each built on the one below, and that the key to discovery lies in finding “appropriate ideas”48 to describe the tier one is concerned with. By 1865 Maxwell was convinced that magnetic and electric energy are disseminated in space. As a “very probable hypothesis” he favored identifying the two forms of energy with “the motion and the strain of one and the same medium,”49 but definite knowledge about one tier must be distinguished from reasonable speculation about the next. That was the philosophic point of the Lagrangian method. In Hamilton’s terminology the best short statement of Maxwell’s position is that we may believe in the existence of the ether without direct knowledge of its properties; we know only relations between the phenomena it accounts for. In a striking passage from the article on thermodynamics mentioned above, perhaps written after seeing the famous bells at Terling near Rayleigh’s estate, Maxwell compared the situation to that of a group of bellringers confronted with ropes going to invisible machinery in the bell loft. Lagrange’s equations supply the “appropriate idea” expressing neither more nor less than is known about the visible motions: whether more detailed information about the machinery can be gained later remains open. In Maxwell’s, as in many later applications of Lagrange’s method, the energies involve electrical, not mechanical, quantities. If the “very probable hypothesis” is followed out and one term is equated with ordinary kinetic energy, then, as Thomson found in 1855, a lower limit to the density ρ of a mechanical ether can be calculated from the known energy density of sunlight.50 The flaw in Thomson’s argument lies in assuming an energy density it is resolved in relativistic dynamics by the mass-energy relation; the rest mass of the photon is zero. Considerations of this kind indicate the subtlety of the scientific transformation wrought by relativity theory. It eliminated the arguments for an ether of fixed position and finite density, yet it preserved intact Maxwell’s equations and his fundamental idea of disseminated electrical energy. More light is thrown on Maxwell’s own opinions about the problem of relative and absolute motion and the connection between dynamics and other branches of physics by the delightful monograph Matter and Motion, published in 1876.
Maxwell’s influence in suggesting the Michelson-Morley ether-drift experiment is widely acknowleged, but the story is a curiously tangled one. It originates in the problem of the aberration of starlight. During the course of a year the apparent positions of stars, as fixed by transit measurements, vary by ±20.5 arc-seconds. This effect was discovered in 1728 by Bradley. He attributed it to the lateral motion of the telescope traveling at velocity v with the earth about the sun. On the corpuscular theory of light the motion causes a displacement of the image, while the particles travel from the objective to the focus, through an angular range ν/c just equal to the observed displacement. An explanation of aberration on the wave theory of light is harder to come by If the ether were a gas like the earth’s atmosphere (as was first supposed), it would be carried along with the telescope and one scarcely would expect any displacement. Young in 1804 therefore proposed that the ether must pass between the atoms in the telescope wall “as freely perhaps as the wind passes through a grove of trees.”51 The idea had promise, but in working it out other phenomena needed to be considered, many of which further illustrate the difficulties of classical ethers. To explain Maxwell’s involvement I depart from chronology and give the facts roughly in the order in which they presented themselves to him.
In 1859 Fizeau proved experimentally that the velocity of light in a moving column of water is greater downstream than upstream. A natural supposition is that the water drags the ether along with it. This contradicts Young’s hypothesis in its most primitive form; however, the modified velocity was not c + w but c + w(l — l/μ2) where μ is the refractive index of water, and that tallied with a more sophisticated theory of aberration due to Fresnel. Fresnel held the conviction (not actually verified until 1871) that the aberration coefficient in a telescope full of water must remain unchanged, which on Young’s theory it does not. He was able to satisfy that requirement by combining Young’s hypothesis with the further assumption that refraction is due to condensation of the ether in ordinary matter, the ether-density in a medium of refractive index μ being μ2 times its value in free space. With the excess ether carried along by matter one obtains the quoted formula, which is in consequence still known as the “Fresnel drag” term, though it stands on broader foundations, as Larmor afterwards proved. Indeed Fresnel’s condensation hypothesis is logically inconsistent with another principle that became accepted in the 1820’s, namely, that the ether, to convey transverse but not longitudinal waves, must be an incompressible solid. A dissatisfaction with Fresnel’s “startling assumptions” made Stokes in 1846 propose a radically new theory of aberration, treating the ether as a viscoelastic substance, like pitch or glass. For the rapid vibrations of light the ether acts as a solid, but for the slow motions of the solar system it resembles a viscous liquid, a portion of which is dragged along with each planetary body. A plausible circuital condition on the motion gives a deflection v/c for a beam of light approaching the earth, identical with the displacement that occurs inside the telescope in the other theories.
Some time in 1862 or 1863 Maxwell read Fizeau’s paper and thought out an experiment to detect the ether wind. Since refraction is caused by differences in the velocity of light in different media, one might expect the Fresnel drag to modify the refraction of a glass prism movingthrough the ether. Maxwell calculated that the additional deflection in a 60° prism moving at the earth’s velocity would be 17 arc-seconds. He arranged a train of three prisms with a return mirror behind them in the manner of his portable “colour-box,” and set up what would now be called an autocollimator to look for the deflection, using a telescope with an illuminated eyepiece in which the image of the crosshair was refocused on itself after passing to and fro through the prisms. The displacement from ether motion could be seen by mounting the apparatus on a turntable, where the effect would reverse on rotating through 180°, giving an overall deflection after the double passage of 2½ arc-minutes: easily measurable. Maxwell could detect nothing, so in April 1864 he sent Stokes a paper for the Royal Society concluding that “the result of the experiment is decidedly negative to the hypothesis about the motion of the ether in the form stated here.”52
Maxwell had blundered. Though he did not then know it, the French engineer Arago had done a crude version of the same experiment in 1810 (with errors too large for his result to have real significance), and Fresnel had based his theory on Arago’s negative result. Stokes knew all this, having written an article on the subject in 1845; he replied, pointing out Maxwell’s error, which had been to overlook the compensating change in density that occurs because the ether satisfies a continuity equation at the boundary.53 Maxwell withdrew the paper. He did give a description of the experiment three years later, with a corrected interpretation, in a letter to the astronomer William Huggins, who included it in his pioneering paper of 1868 on the measurement of the radial velocities of stars from the Doppler shifts of their spectral lines.54 There the matter rested until the last year of Maxwell’s life. Then in his article “Ether” for the Encyclopaedia Britannica he again reviewed the problem of motion through the ether. The only possible earth-based experiment was to measure variations in the velocity of light on a double journey between two mirrors. Maxwell concluded that the time differences in different directions, being of the order ν2/c2 would be too small to detect. He proposed another method from timing the eclipses of the moons of Jupiter, which he later described in more detail in a letter to the American astronomer D. P. Todd, published after his death in the Royal Society Proceedings and in Nature.55 His statements there about the difficulties of the earth-based experiment served as a challenge to the young Albert Michelson, who at once invented his famous interferometer to do it.
The negative result of the experiment swung Michelson and everyone else behind Stokes’s theory of aberration. In 1885, however, Lorentz discovered that Stokes’s circuital condition on the motion of the ether is incompatible with having the ether stationary at the earth’s surface. Lorentz advanced a new theory combining some of Stokes’s ideas with some of Fresnel’s he also pointed out an oversight in Michelson’s (and Maxwell’s) analysis of the experiment, which halved the magnitude of the predicted effect, bringing it near the limits of the observations, Michelson and Morley then repeated the experiment with many improvements. Their conclusive results were published in 1887. In 1889 FitzGerald wrote to the American journal Science explaining the negative result by his contraction hypothesis.56 The same idea was advanced independently by Lorentz in 1893. Physics texts often refer to the FitzGerald-Lorentz contraction as an ad hoc assumption dreamed up to save appearances. It was not. The force between two electric charges is a function of their motion with respect to a common frame: Maxwell had shown it (incompletely and in another context) in the Treatise.57 Hence, as FitzGerald stated, all one need assume to explain the negative result of the Michelson-Morley experiment is that intermolecular forces obey the same laws as electromagnetic forces. The real (and great) merit of the special theory of relativity was pedagogical. It arranged the old confusing material in a clear deductive pattern.
Reference may be made to some more technical contributions from Maxwell’s later work. A short paper of 1868, written after seeing an experiment by W. R. Grove, gave the first theoretical treatment of resonant alternating current circuits.58 Portions of the Treatise applied quaternion formulas discovered by Tait to the field equations, and paved the way for Heaviside’s and Gibbs’s developments of vector analysis. Maxwell put these and various related matters in a wider context in a paper of 1870, “On the Mathematical Classification of Physical Quantities.” He coined the terms “curl,” “convergence” (negative divergence), and “gradient” for the various products of the vector operator ▽ on scalar and vector quantities, with the less familiar but instructive term “concentration” for the operation ▽2 which gives the excess of a scalar V at a point over its average through the surrounding region.59 He extended also his previous treatment of force and flux vectors, introduced the important distinction between what are now (after W. Voigt) known as axial and polar vectors, and in other papers gave a useful physical treatment of the two classes of tensors later distinguished mathematically as covariant and contravariant.60 Further analytical developments in the Treatise include applications of reciprocal theorems to electrostatics, a general treatment of Green’s functions, topological methods in field and network theory, and the beautiful polar representation of spherical harmonic functions.61 The Treatise also contains important contributions to experimental technique, such as the well-known “Maxwell bridge” circuit for determining the magnitude of an inductance.62
A consequence of the displacement hypothesis which Maxwell himself did not truly grasp until 1869 is that all electric currents, even in apparently open circuits, are in reality closed.63 But with that a new interpretation of electric charge became necessary. This is a subject of great difficulty, one of the most controversial in all Maxwell’s writings. Many critics from Heinrich Hertz on have come to feel that a consistent view of the nature of charge and electric current, compatible with Maxwell’s statements, simply does not exist. I believe these authors to be mistaken, although I admit that Maxwell gave them grounds for complaint, both by his laziness over plus and minus signs and by the fact that in parts of his work where the interpretation of charge was not the central issue he slipped back into terminology—and even ideas—not really compatible with his underlying view. The question is all the harder because the problem it touches (the relation between particles and fields) has continued as a difficulty in physics down to the present day. A full critical discussion would take many pages. I shall content myself with a short dogmatic statement, cautioning the reader that other opinions are possible.
Before Maxwell, electricity had been represented as an independent fluid (or pair of fluids), the excess or deficiency of which constitutes a charge. But if currents are invariably closed, how can charge accumulate anywhere? Part, but only part, of the answer lies in the hypothesis, hinted at by Faraday and clearly stated by Maxwell in 1865, that electrostatic action is entirely a matter of dielectric polarization, with the conductor serving not as a receptacle for electric fluid but as a bounding surface for unbalanced polarization of the surrounding medium. The difference between the old and new interpretations of charge, illustrated in Figure 4(a) and (b), looks simple; but underneath are problems that Maxwell’s followers found bafflingly obscure. One source of confusion was that the polarization in 4(b) differs from that in the theory of material dielectrics proposed earlier by Thomson and Mossotti64 (Figure 4[c]), which made the effective charge Q at the boundary the sum of a real charge Q0 on the conductor and an apparent charge —Q′ on the dielectric surface. In Maxwell’s interpretation the polarization extends from material dielectrics to space itself; all charge is in a sense apparent charge, and the motion is in the opposite direction. All might have been well had Maxwell in the Treatise not discussed the difference between charge on a conductor and charge on a dielectric surface in language similar to Mossotti’s and if he had adopted a less liberal approach to the distinction between plus and minus signs. As it was, with the
further novelty of totally closed currents, most people from Hertz on shook their heads in despair.
Yet the two analogies on which Maxwell based his ideas—those between the motion of electricity and an incompressible fluid and between static induction and displacement—are both sound. The escape lies in recognizing the radical difference in meaning of the two charges illustrated in 4(a) and 4(b). Maxwell’s current is not the motion of charge, but the motion of a continuous uncharged quantity (not necessarily a substance); his charge is the measure of the displacement of that quantity relative to space. To the question puzzling Hertz—whether charge is the cause of polarization or polarization the cause of charge—the answer is “neither.” For Maxwell electromotive force is the fundamental quantity. It causes polarization; polarization creates stresses in the field; charge is the measure of stress. All these ideas are traceable to Maxwell; but nowhere, it must be conceded, are they fairly set out. The representation of electricity as an uncharged fluid may seem incompatible with electron theory. Actually it is not; and one of the oddities in Maxwell’s development is that the clue to reconciling the two ideas rests in the treatment of charges as sources and sinks of incompressible fluid given in his 1856 paper. That essentially was the principle of the ether-electron theory worked out by Larmor in 1899.
Few things illustrate better the subtlety of physical analogy than Maxwell’s developing interpretations of the function A . His original discussion in 1856 was purely analytic. The dynamical theory led him to its representation as a property of electricity analogous to momentum, which reached fulfillment after his death in the expression (mv + eA/c) for the canonical momentum of the electron, mv being the momentum of the free particle and eA/c the reduced momentum contributed by sources in the surrounding field. In 1871 he perceived another, entirely different analogy for A. Considered in relation to electro-dynamic forces it resembles a potential, as may be seen by comparing the equation F = grad(i · A) for force on a conductor carrying a current with the equation F grad(eΦ) for force on a charged body. Maxwell introduced the terms “vector” and “scalar potential” for A and Φ and recognized, probably for the first time, that A was a generalization of F. E. Neumann’s electrodynamic potential, though his formulation differed in spirit and substance from Neumann’s, since it started from the field equations and incorporated displacement current. The formulas were later rearranged by FitzGerald, Liénard, and Wiechert as retarded potentials of the conduction currents, thus uncovering their common ground with L. V. Lorenz’s propagated action theory of electrodynamics. Both of Maxwell’s analogies may be carried through in detail: that is, equations in A exist analogous to every equation in dynamics involving momentum and every equation in potential theory involving Φ. The resemblance of a single function to two quantities so different as momentum and potential depends on the peculiar relation between electro-motive and electrodynamic forces: the electromotive force generated by induction is proportional to the velocity of the conductor times the electrodynamic force acting on it. The momentum analogy was little appreciated until 1959, when Y. Aharonov and D. J. Bohm pointed out some unexpected effects tied to the canonical momentum in quantum mechanics.65
Statistical and Molecular Physics (1859–1878) . The problem of determining the motions of large numbers of colliding bodies came to Maxwell’s attention while he was investigating Saturn’s rings. He dismissed it then as hopelessly complicated; but in April 1859, as he was finishing his essay for publication, he chanced to read a new paper by Rudolf Clausius on the kinetic theory of gases, which convinced him otherwise and made him transfer his interest to gas theory.
The idea of attributing pressure in gases to the random impacts of molecules against the walls of the containing vessel had been suggested before. Prevailing opinion, however, still favored Newton’s hypothesis of static repulsion between molecules or one of its variants, such as Rankine’s vortex hypothesis. Maxwell had been taught the static theory of gases as a student at Edinburgh. Behind the victory of kinetic theory led by Clausius and Maxwell lay two distinct scientific advances: the doctrine of conservation of energy, and an accumulation of enough experimental information about gases to shape a worthwhile theory. Many of the new discoveries from 1780 on, such as Dalton’s law of partial pressures, the law of equivalent volumes, and measurements on the failure of the ideal gas equation near liquefaction, came as by-products of chemical investigations. Two developments especially important to Maxwell were Thomas Graham’s long series of experiments on diffusion, transpiration, and allied phenomena, also begun as chemical researches, and Stokes’s analysis of gas viscosity, made in 1850 as part of a study on the damping of pendulums for gravitational measurements. Maxwell had used Stokes’s data in treating the hypothesis of gaseous rings for Saturn. Viscosity naturally became one of his first subjects for calculation in kinetic theory; to his astonishment the predicted coefficient was independent of the pressure of the gas. The experiments of his wife and himself between 1863 and 1865, which confirmed this seeming paradox, fixed the success of the theory.
Clausius’ work appeared in two papers of 1857 and 1858, each of which contained results important to Maxwell. The first gave a greatly improved derivation of the known formula connecting pressure and volume in a system of moving molecules:
where m is the mass of a molecule, its mean square velocity, and n the total number of molecules, from which, knowing the density at a given pressure, Clausius deduced (as others had done earlier) that the average speed must be several hundred meters per second. Another matter, whose full significance only became apparent after Maxwell’s work, was the exchange of energy between the translational and rotational motions of molecules. Clausius guessed that the average energies associated with the two types of motion would settle down to a constant ratio σ and from thermodynamical reasoning he derived an equation relating σ to the ratio γ of the two specific heats of a gas.
Clausius’ second paper was written to counter a criticism by the Dutch meteorologist C. H. D. Buys Ballot, who objected that gas molecules could never be going as fast as Clausius imagined, since the odor of a pungent gas takes minutes to permeate a room. Clausius replied that molecules of finite diameter must be repeatedly colliding and rebounding in new directions, and he deduced from statistical arguments that the probability W of a molecule’s traveling a distance L without collision is
where l is a characteristic “mean free path.” Assuming for convenience that all molecules have equal velocity, Clausius found
where S is their diameter and N their number density. He could not determine the quantities explicitly but guessed that l/s might be about 1,000, from which l had to be a very small distance. Since by equation (8) only a minute fraction of molecules travel more than a few mean free paths without collision, Buys Ballot’s objection to kinetic theory was fallacious.
Although Clausius had based his investigation on the simplifying assumption that all molecules of any one kind have the same velocity, he recognized that the velocities would in reality spread over a range of values. The first five propositions of Maxwell’s “Illustrations of the Dynamical Theory of Gases” (1860) led to a statistical formula for the distribution of velocities in a gas at uniform pressure, as follows. Let the components of molecular velocity in three axes be x, y, z. Then the number dN of molecules whose velocities lie between x and x + dx, y and y + dy, z and z + dz is N f(x) f(y) f(z) dx dy dz. But since the axes are arbitrary, dN depends only on the molecular speed ʋ where ʋ2 = x + 2 + z2 and the distribution must satisfy the functional relation
the solution of which is an exponential. Applying the fact that N is finite, the resolved components of velocity in a given direction may be shown to have a distribution function identical in form with Laplace’s bell-shaped “normal distribution” in the theory of errors:
where α is a quantity with dimensions of velocity. The number of particles summed over all directions with speeds between ʋ and ʋ + dʋ is
Related formulas give the distributions in systems of two or more kinds of molecules. From them with (11) and (12) Maxwell was able to determine mean values of various products and powers of the velocities used in calculating gas properties.
The derivation of equations (11) and (12) marks the beginning of a new epoch in physics. Statistical methods had long been used for analyzing observations, both in physics and in the social sciences, but Maxwell’s idea of describing actual physical processes by a statistical function was an extraordinary novelty. Its origin and validity deserve careful study. Intuitively equation (12) is plausible enough, since dNʋ approaches zero as ʋ approaches zero and infinity and has a maximum at ʋ = α, consistent with the natural physical expectation that only a few molecules will have very high or very low speeds. Empirically it was verified years later in experiments with molecular beams. Yet the assumption that the three resolved components of velocity are distributed independently is one which, as Maxwell later conceded, “may appear precarious”;66 and the whole derivation conveys a strange impression of having nothing to do with molecules or their collisions. Its roots go back to Maxwell’s Edinburgh days. His interest in probability theory was aroused in 1848 by Forbes, who reexamined a statistical argument for the existence of binary stars put forward in 1767 by the Reverend John Michell. Over the next few years he read thoroughly the statistical writings of Laplace and Boole and also another item of peculiar interest, a long essay by Sir John Herschel in the Edinburgh Review for June 1850 on Adolphe Quetelet’s Theory of Probability as Applied to the Moral and Social Sciences. Herschel’s review ranged over many issues, social and otherwise; and a contemporary letter to Lewis Campbell leases no doubt that Maxwell had read it.67 One passage embodied a popular derivation of the law of least squares applied to random distributions in two dimensions, based on the supposed independence of probabilities along different axes. The family resemblance to Maxwell’s derivation of equation (11) is striking. Thus early reading on statistics, study of gaseous rings for Saturn, and ideas from Clausius about probability and free path all contributed to Maxwell’s development of kinetic theory.
In His slines appears to he one given by M. Kac in 1939. In his second paper, published in 1867, Maxwell offered a new derivation of the distribution law tied directly to molecular encounters. To maintain equilibrium the distribution function must satisfy the relation where v1 and are velocities of molecule 1 and v2 and of molecule 2 before and after encounter. Combination with the energy equation yielded formulas corresponding to (11) and (12). This established the equilibrium of the exponential distribution but not its uniqueness. From considerations of cyclic collision processes Maxwell sketched an argument that any velocity distribution would ultimately converge to the same form. The proof of the theorem in full mathematical rigor is still an open problem. Boltzmann gave an interesting extended version of Maxwell’s argument in his Lectures on Gas Theory (1892). Earlier he had formulated another approach (the H-theorem), which bears on the subject and is even more important as part of the development that eventually transcended gas theory and led to the separate science of statistical mechanics. One further point that has been examined by various writers is the status of Maxwell’s original derivation of the exponential law. Since the result is correct the hypotheses on which it was based must in some sense be justifiable. The best proof along Maxwell’s first lines appears to be one given by M. Kac in 1939.68
Maxwell next applied the distribution function to evaluate coefficients of viscosity, diffusion, and heat conduction, as well as other properties of gases not studied by Clausius. He interpreted viscosity as the transfer of momentum between successive layers of molecules moving, like Saturn’s rings, with different transverse velocities. The probability of a molecule’s starting in a layer dz and ending in dz′ is found from Clausius’ equation (8) in combination with the distribution function. Integration gives the total frictional drag and an equation for the viscosity coefficient,
where ρ is the density, Ī the mean free path, and v the mean molecular speed. Since Ī is inversely propertional to ρ, the viscosity is independent of pressure. The physical explanation of this result, given by Maxwell in a letter to Stokes of 30 May 1859, is that although the number of molecules increases with pressure, the average distance over which each one carries momentum decreases with pressure.69 It holds experimentally over a wide range, only breaking down when ρ is so high that Ī becomes comparable with the diameter of a molecule or so low that it is comparable with the dimensions of the apparatus. Maxwell was able to calculate a numerical value for the free path by substituting into (13) a value for μ/ρ from Stokes’s data and a value for v from (7). The result was 5.6 x 106 cm. for air at atmospheric pressure and room temperature, which is within a factor of two of the current value. The calculations for diffusion and heat conduction proceeded along similar lines by determining the number of molecules and quantity of energy transferred in the gas. Applying the diffusion formulas to Graham’s experiments, Maxwell made a second, independent estimate of the free path in air as 6.3 x 106 cm. The good agreement between the results greatly strengthened the plausibility of the theory. There were, however, errors of principle and of arithmetic in some of the calculations, which Clausius exposed—not without a certain scholarly relish—in a new paper of 1862. The chief mistake lay in continuing to use an isotropic distribution function in the presence of density and pressure gradients. Clausius offered a corrected theory; but since he persisted in assuming constant molecular velocity, it too was unsatisfactory. Maxwell wrote out his own revised theory in 1864; but having meanwhile become dissatisfied with the whole mean free path method, he withheld the details. The true value of Clausius’ criticism was to show the need for a formulation of kinetic theory consistent with known macroscopic equations. Maxwell was to produce it in 1867.
One further important topic covered in the 1860 papers was the distribution of energy among different modes of motion of the molecules. Maxwell first established an equality, which had previously been somewhat sketchily derived by both Waterston and Clausius, between the average energies of translation of two sets of colliding particles with different molecular weights. He deduced that equal volumes of gas at fixed temperature and pressure contain the same number of molecules, accounting for the law of equivalent volumes in chemistry. Later, following out Clausius’ thoughts on specific heat, he studied the distribution of energy between translational and rotational motions of rough spherical particles and found that there too the average energies are equal. These two statistical equalities, between the separate translational motions of different molecular species and between the rotational and translational motions of a single species, are examples of a deep general principle in statistical mechanics, the “equipartition principle.” The second was an embarrassing surprise; for if molecules are point particles incapable of rotation, Clausius’ formula makes the specific heat ratio 1.666, and if they are rough spheres it makes it 1.333. The experimental mean for several gases was 1.408. Maxwell was so upset that he stated that the discrepancy “overturned the whole hypothesis.”70 His further wrestlings with equipartition in the 1870’s will be discussed below.
The measurements of gaseous viscosity at different pressures and temperatures made by Maxwell and his wife71 in 1865 were their most useful contribution to experimental physics. The “Dynamical Theory of Gases,” which followed, was Maxwell’s greatest single paper. The experiment consisted in observing the decay of oscillations of a stack of disks torsionally suspended in a sealed chamber. Over the ranges studied, the viscosity μ was independent of pressure, as predicted, and very nearly a linear function of the absolute temperature T. But equation (12) implies that μ should vary as T½. The hypothesis that gas molecules are freely colliding spheres is therefore too simple, and Maxwell accordingly developed a new theory treating them as point centers of force subject to an inverse nth power repulsion. In a theory of this kind the mean free path ceases to be a clear-cut concept: molecules do not travel in straight lines but in complicated orbits with deflections and distances varying with velocity and initial path. Yet some quantity descriptive of the heterogeneous structure of the gas is needed. Maxwell replaced the characteristic distance l by a characteristic time, the “modulus of time of relaxation” of stresses in the gas. A second need, exposed by Clausius’ critical paper of 1862, was for a systematic procedure to connect molecular motions with the known macroscopic gas laws. On both points Maxwell’s thinking was influenced by Stokes’s work on the general equations of viscosity and elasticity.
Elasticity may be defined as a stress developed in a body in reaction to change of form. Both solids and fluids exhibit elasticity of volume; solids alone are elastic against change of shape. A fluid resists changes of shape through its viscosity, but the resistance is evanescent: motion generates stresses proportional to velocity rather than displacement. In 1845 Stokes wrote a powerful paper giving a new treatment of the equations of motion of a viscous fluid. He noticed while doing so that if the time derivatives in the equations are replaced by spatial derivatives, they become the equations of stress for an elastic solid. Poisson also had noticed this transformation, but Stokes went further and remarked that viscosity and elasticity seem to be physically related through time. Substances like pitch and glass react as solids to rapid disturbances and as viscous liquids to slow ones. Stokes utilized this idea in the theory of aberration already described; other physicists also followed it up, among them Forbes, who, as an alpinist, applied it to the motions of glaciers. Maxwell’s early letters contain several references to Forbes’s opinions.72 His youthful work on elasticity made him acquainted with Stokes’s paper, and in 1861, as explained above in the section on electricity, he applied the analogy of viscosity and elasticity in another way to the processes of conduction and static induction through dielectrics.
During the experiments on gases Maxwell’s attention was again directed to viscoelastic phenomena through having to correct for losses in the torsion wire from which his apparatus was suspended. His 1867 paper proposed a new method of specifying viscosity in extension of Stokes’s theory. In an ideal solid free from viscosity, a distortion or strain S of any kind creates a constant stress F equal to E times S, where E is the coefficient of elasticity for that particular kind of strain. In a viscous body F is not constant but tends to disappear. Maxwell conjectured that the rate of relaxation of stress is proportional to F, in which case the process may be described formally by the differential equation
which gives an exponential decay of stress governed by the relaxation time τ. Processes short compared with τ are elastic; processes of longer duration are viscous. The viscosity μ is equal to Es times τ, where Es is the instantaneous rigidity against shearing stresses. A given substance may depart from solidity either by having small rigidity or short relaxation time, or both. Maxwell seems to have arrived at (14) from a comparison with Thomson’s telegraphy equations, inverting the anatogy between electrical and mechanical systems that he had developed in 1865. A test that immediately occurred to him was to look for induced double refraction in a moving fluid, comparable to the double refraction in strained solids discovered by Brewster, which he himself had analyzed in his paper of 1850 on the equilibrium of elastic solids. After some difficulty Maxwell eventually demonstrated in 1873 that a solution of Canada balsam in water exhibits temporary double refraction with a relaxation time of order 10−2 seconds.73 Maxwell’s theory of stress relaxation formed the starting point of the science of rheology and affected indirectly every branch of physics, as may be seen from the widespread use of his term “relaxation time.” Its immediate purpose lay in reaching a new formulation of the kinetic theory of gases.
Consider a group of molecules moving about in a box. Their impact on the walls exerts pressure. If the volume is changed from V to V + dV, the pressure will change by an amount —p dV/V. But in the theory of elasticity the differential stress due to an isotropic change of volume is —E dV/V, where E is the cubical elasticity. The elasticity of a gas is proportional to its pressure. Suppose now the pressure is reduced until the mean free path is much greater than the dimensions of the box; and let the walls be rough, so that the molecules rebound at random, and also flexible. Then in addition to the pressure there will be continued exchange of the transverse components of momentum from wall to wall, making the box, even though it is flexible, resist shearing stresses. In other words, a rarefied gas behaves like an elastic solid! Let this property be called quasisolidity. Following the ideas expressed in equation (14), the viscosity of a gas at ordinary pressures may be conceived of as the relaxation of stresses by molecular encounters. Since elasticity varies as pressure, μ is proportional to pτ and the relaxation time of a gas at normal pressures is inversely proportional to its density. Although the concept of free path is elusive when there are forces between molecules, some link evidently exists between it and the relaxation time. Maxwell gave it in 1879 in a footnote to his last paper, added in response to a query by Thomson.74 For a gas composed of rigid-elastic spheres, the product of T with the mean speed ʋ of the molecules is a characteristic distance λ, whose ratio to the mean free path l¯ is 8/3π The free path is a special formulation of the relaxation concept applicable only to freely colliding particles of finite diameter.
To calculate the motions of a pair of molecules subject to an inverse nth power repulsion was a straightforward exercise in orbital dynamics. For the statistical specification of encounters, Maxwell wrote the number dN, of molecules of a particular type with molecular weight M, and vetocities between ξ1 ξ1 + dξ, etc. as f (ξ1 η ζ1) dξ1 dη1 d ζ1, as in the first paper, with a similar expression for molecules of another type with molecular weight M2. The vetocities of two such groups being defined, their relative vetocity V12 is also a definite quantity; and the number of encounters between them occurring in time δt can be expressed in terms of orbit parameters. It is V12 db dø dN1 dN2 δt, Where b is the distance between parallel asymptotes before and after an encounter and ø is the angle determining the plane in which V12 and b lie. If Q is some quantity describing the motion of molecules in group 1, which may be any power or product of powers of the velocities or their components, and if Q′ is its value after an encounter, the net rate of change in the quantity for the entire group is (Q′ — Q) times the number of encounters per second, or
Equation (13) is the fundamental equation of Maxwell’s revised transfer theory, replacing the earlier equations based on Clausius probability formula (8). With the explicit relation between Vl2 and b inserted from the orbit equation, the relative vetocity enters the integral of (15) as a factor V12(n-5)/(n-1), which means that although integration generally requires knowledge of the distribution function f2 under nonequilibrium conditions, In The Special Case Of Molecules subject to an inverse fifth-power repulsion V12 drops out and the final result may be written immediately as Q̅N2 where Q̅ is the mean value of the quantity and N2 is the total number of molecules of type 2. The simplification may be understood, as Boltzmann later pointed out, by noticing that the number of deflections through a given angle is the product of two factors, one of which (the cross section for scattering) decreases with V12, while the other (the number of collisions) increases with V12·75 When n is 5, the two factors are exactly balanced. Molecules subject to this law are now called Maxwellian. By a happy coincidence their viscosity is directly proportional to the absolute temperature, in agreement with Maxwell’s experiment, although not with more precise measurements made later.
With this Maxwell was in a position to determine the scattering integrals and calculate physical properties of gases. Even with the simplification of inverse fifth-power forces the mathematical task remained formidable, and an impressive feature was the notation Maxwell developed to keep track of different problems. One general equation described transfer of quantities across a plane with different Q′s giving the velocities, pressures, and heat fluxes in a gas. Next to he considered were variations of Q¯ within a given element of volume. These might occur through the actions of encounters or external forces on molecules within the element or, alternatively, through the passage of molecules to or from the surrounding region. Denoting variations of the first kind by the symbol δ and variations of the second kind by δ Maxwell got his general equation of transfer:
where u, v, w are components of the translational velocity of the gas; the differential symbol d gives total variations with respect to position and time; and subscripts are added to δ to distinguish variations due to encounters with molecules of the same kind, molecules of a different kind, and the action of external forces. With Q equal to mass, (16) reduces to the ordinary equation of continuity in hydrodynamics. With Q equal to the momentum per unit volume, (16) in combination with the appropriate expression for QN derived from (15) reduces to an equation of motion. From this, or rather from its generalization to mixtures of more than one kind of molecule, Maxwell derived Dalton’s law of partial pressures, and formulas for diffusion applicable to Graham’s experiments. With Q energy, (16) yields an equation giving the law of equivalent volumes and formulas for specific heats, thermal effects of diffusion, and coefficients of viscosity in simple and mixed gases. The viscosity equation replacing (12) for Maxwellian molecules is
where k is Boltzmann’s constant, M is molecular weight, and K is the scaling constant for the forces.
The hardest area of investigation was heat conduction. That was where Maxwell had gone astray in 1860. In the exact theory effects of thermal gradients occur when Q in equation (16) is of the third order in ξ, η ζ,. Maxwell found an expression for the thermal conductivity of a gas in terms of its viscosity, density, and specific heat. The ratio of these quantities, which is known as the Prandtl number, “but which ought to be called the Maxwell number,”76 is one of several dimensionless ratios used in applying similarity principles to the solution of problems in fluid dynamics. For a monatomic gas it is nearly a constant over a wide range of temperatures and pressures. Another matter, in which Maxwell became interested through considering the stability of the earth’s atmosphere, was the equilibrium of temperature in a vertical column of gas under gravity. The correct result was known from thermodynamics, but its derivation from gas theory gave Maxwell great trouble. It comes out right only if the ratio of the two statistical averages has the particular value 3 given by the exponential distribution law. The calculation thus supplied evidence in favor of the law. More light on the same subject came in Boltzmann’s first paper on kinetic theory, written in 1868. Boltzmann Investigated the Distribution law by a method based on Maxwell’s, but included the external forces directly in the energy equation to be combined with Maxwell’s collision equation . The distribution function assumed the form e−E/KT, where E is the sum of the kinetic and potential energies of the molecule. In 1873 Maxwell gave a greatly simplified derivation of Boltzmann’s result during a correspondence in Nature about the equilibrium of the atmosphere. He then confessed that his first calculation for the 1867 paper, which gave a temperature distribution that would have generated unending convection currents, nearly shattered his faith in kinetic theory.
Maxwell never attempted to solve the transfer equations for forces other than the inverse fifth power. In 1872 Boltzmann rearranged (16) into an integro-differential equation for f, from which the transport coefficients could in principle be calculated; but despite much effort he failed to reach any solution except for Maxwellian molecules. It was not until 1911–1917 that S. Chapman and D. Enskog developed general methods of determining the coefficients. One interesting result was Chapman’s expression for viscosity of a gas made up of hard spheres, which had a form equivalent to (12) but with a numerical coefficient 50 percent higher than Maxwell’s and 12 percent higher than that obtained from the mean free path method with corrections for statistical averaging and persistence of velocities derived by Tait and Jeans. So even for the hard-sphere gas the simple theory fails in quantitative accuracy.
For some years after 1867 Maxwell made only sporadic contributions to gas theory. In 1873 he gave a revised theory of diffusion for the hard-sphere gas, from which he developed estimates of the size of molecules, following the work of Loschmidt (1865), Johnstone Stoney (1868), and Thomson (1870). In 1875, following van der Waals, he applied calculations on intermolecular forces to the problem of continuity between the liquid and gaseous states of matter.
In 1876 he gave a new theory of capillarity, also based on considerations about intermolecular forces, which stimulated new research on surface phenomena. Of all the questions about molecules which Maxwell puzzled over during this period the most urgent concerned their structure. His uneasiness about the discrepancy between the measured and calculated specific heat ratios of gases has already been referred to. The uneasiness increased after 1868 when Boltzmann extended the equipartition theorem to every degree of freedom in a dynamical system composed of material particles; and it turned to alarm with the emergence of a new area of research: spectrum analysis. From 1858 onwards, following the experiments of Bunsen and Kirchhoff, several people, including Maxwell, worked out a qualitative explanation of the bright lines in chemical spectra, attributing them to resonant vibrations of molecules excited by their mutual collisions. The broad truth of the hypothesis seemed certain; but it led, as Maxwell immediately saw, to two questions, neither of which was answered until after his death. First, the identity of spectra implies that an atom in Sirius and an atom in Arcturus must be identical in all the details of their internal structure. There must be some universal dimensional constant determining vibration frequency: “each molecule … throughout the universe bears impressed on it the stamp of a metric system as distinctly as does the metre of the Archives of Paris, or the double royal cubit of the Temple of Karnac.”77 The royal cubit proved to be Planck’s quantum of action discovered in 1900. The other question, also answered only by quantum theory, concerned the influence of molecular vibrations on the specific heat ratio. There were not three or six degrees of freedom, but dozens. There was no way of reconciling the specific heat and spectroscopic data with each other and the equipartition principle. The more Maxwell examined the problem the more baffled he became. In his last discussion, written in 1877, after summarizing and rejecting all the attempts from Boltzmann on to wriggle out of the difficulty, he concluded that nothing remained but to adopt that attitude of “thoroughly conscious ignorance that is the prelude to every real advance in knowledge.”78
During his last two years Maxwell returned to molecular physics in earnest and produced two full-length papers, strikingly different in scope, each among the most powerful he ever wrote. The first, “On Boltzmann’s Theorem on the Average Distribution of Energy in a System of Material Points,” followed a line of thought started by Boltzmann, who in 1868 had offered a new conjectural derivation of the distribution law based on combinatorial theory. A strange feature of the analysis was that it seemed to be free from restrictions on the time spent in encounters between molecules. Hence, as Maxwell was quick to point out,79 both the distribution factor e−E/kT and the equipartition theorem should apply to solids and liquids as well as gases: a conclusion as fascinating and disturbing as equipartition itself.
Maxwell now gave his own investigation of the statistical problem, based partly on Boltzmann’s ideas and partly on an extension of them contained in H. W. Watson’s Treatise on the Kinetic Theory of Gases.80 Following Watson, Maxwell used Hamilton’s form of the dynamical equations, and adopted the device of representing the state of motion of a large number n of particles by the tocation of a single point in a “phase-space” of 2n dimensions, the coordinates of which are the positions and momenta of the particles. Boltzmann had applied similar methods in configuration space, but the Hamiltonian formalism has advantages in simplicity and elegance. Maxwell then postulated, as Boltzmann had done, that the system would in the course of time pass through every phase of motion consistent with the energy equation. This postulate obviously breaks down in special instances, of which Maxwell gave some examples, but he argued that it should hold approximately for large numbers of particles, where discontinuous jumps due to collisions make the particles jog off one smooth trajectory to another. The validity of this hypothesis, sometimes called the ergodic hypothesis, was afterwards much discussed, often with considerable misrepresentation of Maxwell’s opinions. Maxwell next introduced a new formal device for handling the statistical averages. In place of the actual system of particles under study, many similar systems are conceived to exist simultaneously, with identical energies but different initial conditions. The statistical problem is then transformed into determining the number of systems in a given state at any instant, rather than the development in time of a single system. The method had in some degree been foreshadowed by Boltzmann in 1872. It was later very greatly extended by Gibbs, following whom it is known as the method of “ensemble averaging,” Maxwell’s main conclusion was that the validity of the distribution and equipartition laws in a system of material particles is not restricted to binary encounters. An important result of a more technical kind was an exact calculation of the microcanonical density of the gas, with an expression for its asymptotic form as the number n of degrees of freedom in the system goes to infinity, while the ratio E/n is held constant. According to C. Truesdell, although the hypotheses on which the theorem was based were rather special, “no better proof was given until the work of Darwin and Fowler.”76 Together with Boltzmann’s articles this paper of Maxwell’s marks the emergence of statistical mechanics as an independent science.
One feature of the paper “On Boltzmann’s Theorem,” eminently characteristic of Maxwell, is that the analysis, for all its abstraction, ends with a concrete suggestion for an experiment, based on considering the rotational degrees of freedom. Maxwell proved that the densities of the constituent components in a rotating mixture of gases would be the same as if each gas were present by itself. Hence gaseous mixtures could be separated by means of a centrifuge. The method also promised much more accurate diffusion data than was hitherto available. Maxwell’s correspondence before his death discloses a plan to set up experiments at Cambridge.81 Many years later it became a standard technique for separating gases commercially.
Maxwell’s last major paper on any subject was “On Stresses in Rarefied Gases Arising From Inequalities of Temperature.” Between 1873 and 1876 the scientific world had been stirred by William Crookes’s experiments with the radiometer, the well-known device composed of a partially evacuated chamber containing a paddle wheel with vanes blackened on one side and silvered on the other, which spins rapidly when radiant heat impinges on it. At first many people, Maxwell included, were tempted to ascribe the motion to light pressure, but the forces were much greater than predicted from the electro-magnetic theory, and in the wrong direction. The influence of the residual gas was soon established; and from 1874 on partial explanations were advanced by Osborne Reynolds, Johnstone Stoney, and others. The tenor of these explanations was that the blackened surfaces absorb radiation and, being hot, make the gas molecules rebound with higher average velocity than do the reflecting surfaces. That plausible but false notion is still perpetuated in many textbooks. A striking observation is that the stresses increase as the pressure is reduced. In 1875 Tait and James Dewar drew the significant conclusion that large stresses occur when the mean free path is comparable with the dimensions of the vanes. At higher pressures some equalizing process enters to reduce the effect.
Such was the state of affairs in 1877, when Maxwell and Reynolds independently renewed the attack. Maxwell was thoroughly familiar with the radiometer controversy, having acted as a referee for many of the original papers, as well as seeing and experimenting with radiometers himself. His work went forward in several stages, during which the comments of Thomson, who refereed his paper, and his own reaction as a referee for Reynolds’ paper had important influences. He began by applying the exact transfer theory to the hypothesis that the stresses arise from the increased velocity of molecules rebounding from a heated surface, expanding the distribution function in the form
where F is a sum of powers and products of ξ, η ζ up to the third degree, and then calculating the effect of temperature gradients in the gas. This expansion later became the first step of Chapman’s elaborate procedure for determining transport coefficients under any force law, but Maxwell kept to inverse fifth-power forces “for the sake of being able to effect the integrations.”82 The result was a stress proportional to d2T/dn2, the second derivative of temperature with respect to distance, correcting a formula given earlier by Stoney, where the stress was proportional to dT/dn. The stress increases when the pressure is lowered, reaching a maximum when the relaxation time τ becomes comparable with the time , in which a molecule traverses the dimension d of the body—that is, Tait and Dewar’s conjecture in the language of the exact theory.
At this point Maxwell made an awkward discovery. Although the stresses are indeed large, when the flow of heat is uniform (as in the radiometer) they automatically distribute themselves in such a way that the forces on each element of gas are in equilibrium. The result is a very general consequence of the fact that the stresses depend on d2T/dn2; it is almost independent of the shape of the source; the straightforward explanation of the motions by normal stresses must, therefore, be rejected. Yet the radiometer moves. To escape the dilemma, Maxwell turned to tangential stresses at the edges of the vanes. Here the phenomenon known as “slip” proved all-important. When a viscous fluid moves past a solid body, it generates tangential stresses by sliding over the surface with a finite velocity ʋs According to experiments by Kundt and Warburg in 1875, ʋs in gases is equal to SG/μ, where S is the stress and G is a coefficient expressed empirically by G = 8/ρ. Thus slip effects increase as the pressure is reduced; and as Maxwell pointed out in 1878,83 convection currents due to tangential stresses should become dominant in the radiometer, completely destroying the simplicity of the original hypothesis.
The second phase of Maxwell’s investigation followed a report by Thomson urging him to treat the gas—surface interaction, and his own report on Reynolds’ paper. Reynolds’ also had decided that the effect must depend on tangential stresses, and he devised an experiment to study them under simplified conditions. When a temperature difference ΔT is set up across a porous plug between two vessels containing gas at pressure p, a pressure difference Δp develops between them proportional to δ/p. Reynolds called this new effect “thermal transpiration.” Maxwell gave a simple qualitative explanation in his report, and in an appendix added to his own paper in May 1879 he developed a semiempirical theory accounting for it and for the radiometer effect. The method was to assume that a fraction ƒ of molecules striking any surface are temporarily absorbed and reemitted diffusely, while the remaining (1-ƒ) are specularly reflected. Application of the transfer equations gave a formula for the velocity vs of gas moving past an unequally heated surface, in which one term was the standard slip formula and two further terms predicted convection currents due to thermal gradients. The theory Provided an explicit expression for the coefficient G, where is the effective mean free path; from this, using Kundt and Warburg’s data, Maxwell deduced that ƒ is about 0·5 for air in contact with glass. Maxwell also obtained a formula for transpiration pressure, and showed that both radiometer and transpiration effects are in the correct direction and increase with reduction of pressure, in agreement with experiment.
Maxwell’s paper created the science of rarefied gas dynamics. His formulas for stress and heat flux in the body of the gas were contributions of permanent value, while his investigation of surface effects started a vast body of research extending to the present day. Quantities similar to ƒ later became known as “accommodation coefficients” and were applied to many kinds of gas-surface interaction. One other contribution of great beauty contained in notes added to the paper in May and June 1879 was an application of the methods of spherical harmonic analysis to gas theory. It exemplified the process which Maxwell elsewhere called the “cross-fertilization of the sciences.”84 He was engaged in revising the chapter on spherical harmonics for the second edition of the Treatise on Electricity and Magnetism, when he realized that the harmonic expansion used in potential theory could equally be applied to the expansion of the components ξ, η, ζ of molecular velocity. A standard theorem on products of surface and zonal harmonics, which is discussed in the Treatise, eliminates odd terms in the expansion of variations of F, greatly simplifying the calculations.85 With this and other simplifications Maxwell carried the approximations to higher order and added an extra term to the equation of motion of a gas subject to variations in temperature.
It is a tribute to Maxwell’s genius that on two occasions his papers on transfer theory stimulated fresh work long after the period at which science usually receives historical embalming. In 1910 Chapman read them, and “with the ignorant hardihood of youth,”86 knowing nothing of the fruitless toil that had been spent on the equations during the interval, began his investigation that yielded solutions under any force law. In 1956 E. Ikenberry and C. Truesdell again returned to Maxwell. They obtained an exact representation formula for the collision integral of any spherical harmonic for inverse-fifth-power molecules, using which they explored various iterative techniques for solving the transfer equations. One technique, which they called “Maxwellian iteration” from its resemblance to Maxwell’s procedure in the 1879 paper, yielded much more compact derivations than the ChapmanEnskog procedure; and with it Ikenberry and Truesdell carried solutions for pressure and energy flux in the gas one stage further than had previously been attempted. Truesdell also discovered an exact solution for steady rectilinear flow, by means of which he exposed certain shortcomings of the iterative methods. Speaking of the “magnificent genius of Maxwell” these authors concluded their appraisal by remarking that it passed over all developments in kinetic theory since 1879 and went back “for its source and inspiration to what Maxwell left us.”87
Other Scientific Work . Maxwell’s remaining work may be summarized more shortly, though not as being of small account. His early discovery of the perfect imaging properties of the “fish-eye” lens extended to a lifelong interest in the laws of optical instruments. In a medium whose refractive index varies as μ0a2/(a2 + r2), where μ0 and a are constants and r is the distance from the origin, all rays proceeding from any single point are focused exactly at another point. The calculation was “suggested by the contemplation of the structure of the crystalline lens in fish,”88 Real fishes’ eyes of course only approximate roughly to Maxwell’s medium. Not until R. K. Luneberg revived the subject in 1944 were other instances of perfect imaging devices found.89 In 1853, shortly after discovering the “fish-eye,” Maxwell came across the early eighteenth-century writings on geometrical optics by Roger Cotes and Archibald Smith, in which, as he said to his father, “I find many things far better than what is new.”90 He went on to formulate a new approach to the subject, combining the principle of perfect imaging with Cotes’s neglected theorem on “apparent distance.” Recent years have seen a revival of interest in Maxwell’s method.91 During the 1870’s he returned to it and wrote three papers on the application of Hamilton’s characteristic function to lens systems, which seems to have been about the earliest attempt to reduce Hamilton’s general theory of ray optics to practice. Another striking paper was on cyclidal wave surfaces. It was illustrated with stereoscopic views of different classes of cyclide and contained a description of Maxwell’s real-image stereoscope.
The most pleasing of the minor inventions was his adjustable “dynamical top” (1856), which carried a disk with four quadrants (red, blue, green, yellow) that formed gray when spinning axially, “but burst into brilliant colors when the axis is disturbed.” He was led to search records at Greenwich for evidence of the earth’s 10-month nutation predicted by Euler, which was detected in modified form by Chandler in 1891.
During his regular lectures at King’s College, London, Maxwell was accustomed to present some of Rankine’s work on the calculation of stresses in frameworks. In 1864 Rankine offered an important new theorem,92 which Maxwell then developed into a geometrical discussion entitled “On Reciprocal Figures and Diagrams of Forces.” The principle was an extension of the well-known triangle of forces in statics. Corresponding to any rectilinear figure, another figure may be drawn with lines parallel to the first, but arranged so that lines converging to a point in one figure form closed polygons in the other. The lengths of lines in the polygon supply the ratios of forces needed to maintain the original point in equilibrium. Maxwell gave a method for developing complex figures systematically, and derived a series of general theorems on properties of reciprocal figures in two and three dimensions. He combined the method with energy principles and later, after refereeing a paper on elasticity by G. B. Airy, extended it to stresses in continuous media.93 Figure 5 reproduces diagrams of a girder bridge and its reciprocal given by Maxwell in 1870. Reciprocal theorems and diagrams are useful in many fields of science besides elasticity. Maxwell investigated similar theorems (some of them already known) in electricity. His student Donald MacAlister, the physiologist, applied the method to bone structures. Another application from a later period is the use of reciprocal lattices to determine atomic configurations by X-ray crystallography.
In the British Association experiment on electrical resistance, Maxwell and his colleagues used a speed governor to ensure that the coil rotated uniformly. In principle it resembled James Watt’s steam-engine governor: centrifugal force made weights attached to the driven shaft fly out and adjust a control valve.94 Maxwell studied its behavior carefully; and four years later, in 1868, after reading a paper by William Siemens95 on the practical limitations of governors, he gave an analytical treatment of the subject. He determined conditions for stability in various simple
cases, including one fifth-order system representing a combination of two devices invented by Thomson and Fleeming Jenkin, and investigated effects of natural damping and of variations in the driven load as well as the onset of instabilities. Maxwell’s paper “On Governors” is generally regarded as the foundation of control theory. Norbert Wiener coined the name “cybernetics” in its honor, from kυβερνητηs, the Greek for “steersman,” from which, via a Latin corruption, the word “governor” is etymologically descended.96
Maxwell’s textbook Theory of Heat was published in 1870 and went through several editions with extensive revisions. Chiefly an exposition of standard results, it did contain one far-reaching innovation, the “Maxwell relations” between the thermodynamical variables, pressure, volume, entropy, and temperature, and their partial derivatives. In conceptual spirit they resemble Maxwell’s field equations in electncity, by which they were obviously suggested; they are an ordered collection of relationships between fundamental quantities from which practically useful formulas follow. Several of the individual terms had previously been given by other writers. Maxwell’s derivation was a deceptively simple geometrical argument based on the pressure-volume diagram. Applications of geometry to thermodynamics underwent an extraordinary development in 1873 through Gibbs’s work on entropy-volume-temperature surfaces, of which Maxwell instantly became a powerful advocate. Maxwell’s papers and correspondence contain much of related interest, including an independent development of the chemical potential and an admirable discussion of the classification of thermodynamic quantities in a little-known article, “On Gibbs’s Thermodynamic Formulation for Coexistent Phases.” In 1908 this paper was reprinted at the request of the energeticist W. Ostwald, with notes by Larmor.97 One more important personage in the Theory of Heat was Maxwell’s “sorting demon” (so named by Thomson), a member of a class of “very small BUT lively beings incapable of doing work but able to open and shut valves which move without friction and inertia”98 and thereby defeat the second law of thermodynamics. The demon points to the statistical character of the law. His activities are related to the so-called “reversibility paradox” discussed first by Thomson in 1874—that is, the problem of reconciling the irreversible increase in entropy of the universe demanded by thermodynamics with the dynamical laws governing the motions of molecules, which are reversible with respect to time. A more formal view of the statistical basis of thermodynamics was supplied by Boltzmann in 1877 in the famous equation , which relates entropy S to a quantity W expressing the molecular disorder of a system.
Much of Maxwell’s last eight years was devoted to Cambridge and the Cavendish Laboratory. Many papers by Cambridge mathematicians of the period acknowledge suggestions by him. The design of the laboratory embodied many ingenious features: clear corridors and stairwells for experiments needing large horizontal and vertical distances, an iron-free room for magnetic measurements, built-in anti vibration tables for sensitive instruments supported by piano wires from the roof brackets, and so on. The construction of the building and much of the equipment were paid for by the Duke of Devonshire, but after 1876 Maxwell had to spend substantial sums out of his own pocket to keep the laboratory going. A characteristic of the work done under his direction was an emphasis on measurements of extreme precision, in marked contrast to the “string-and-sealing-wax” tradition of research later built up by J. J. Thomson. Examples were D. MacAlister’s test of the inverse-square law in electrostatics; G. Chrystal’s test of the linear form of Ohm’s law; J. H. Poynting’s improved version (the first of many) of Cavendish’s experiment to measure the gravitational constant; and R. T. Glazebrook’s determination of the optical wave surface for birefringent crystals. In each instance the precision was several orders of magnitude higher than anything previously attempted. “You see,” wrote Maxwell to Joule, “that the age of heroic experiments is not yet past.99
1. C. G. Knott, Life and Scientific Work of Peter Guthrie Tait (Cambridge, 1911), 4, 5.
2. C. W. F. Everitt, in Applied Optics, 6 (1967), 644–645.
3. W. C. Henry Life of Dalton (London, 1854), 25–27. letter of 20 May 1833; the letter Was familiar to Maxwell through G. Wilson, Researches on Colour Blindness (Edinburgh, 1855), 60, in which his own work was first published. See also J. Herschel, “Treatise on Light,” in Encyctopaedia Metropolitana (London. 1843), 403.
4.Papers, I 146.
5. T. Young, Lectures on Natural Philosophy, I (London, 1807), 440; as was known to Maxwell, Papers, I, 150. The choice had also been suggested by C. E. Wünsch, Versuche und Beobachtungen uber die Farben des Lichtes (Leipzig, 1792), of which an abstract is given in Annales de chimie, 64 (1807),135. This rare reference is noted in one of Maxwell’s memorandum books preserved at King’s College, London.
6.Papers, I, 135.
7. J.Larmor, ed., Memoir and Scienctific Correspondence of Sir G. G. Stokes, II (London, 1910), 22; Life, 376–379; W. D. Wright, The Measurement of Colour (London, 1944), 62 f.
10. R. M. Ewans, in Journal of Photagraphic Science, 9 (1961), 243; Scientific American, 205 (1961), 118.
11.Papers, I, 288. There is much of interest in the Challis-Thomson correspondence, Kelvin Papers, Cambridge University Library, file box 2.
13. A. F. Cook and F. A. Franklin, in Astronomical Journal, 69 (1964), 173–200; 70 (1965), 704–720; 71 (1966), 10–19; also (G. P. Kuiper, D. P. Cruikshank, and V. Fink, in Bulletin of the American Astronomical Society, 2 (1970), 235 236; and C. B. Pilcher, C R. Chapman, L. A. Lebotsky, and H. H. Kieffer, ibid., 239.
15. Quoted by J. Larmor, in Proceedings of the Royal Society, 81 (1908), xix.
16.Treatise, preface, vi.
18.Proceedings of the Cambridge Philosophical Society. Mathematical and Physical Sciences, 32 (1936), 695–750.
19.Treatise, I, sec. 72.
20.Elementary Treatise, see. 64.
21. L. Euler. Letters to a German Princess …, H. Hunter, trans, II (London, 1795), 265 271; and known to Faraday, Experimental Researches, III , sec. 3263.
22. W. Thomson. Papers on Electrostatics and Magnetism (London, 1873), secs. 573 f., 733 f. See Maxwell’s Papers, I, 453.
23. W. Thomson, in Proceedings of the Royal Society, 8 (1856), 150–158; repr. in Baltimore Lectures (London, 1890), app. F, 569–583.
24. J. Bromberg, Ph.D. thesis (Univ. of Wis., 1966); A. M. Bork, private communication.
25.Proceedings of the Cambridge Philosophical Society, 32 (1936), 704, letter of 13 Nov, 1854.
26.Papers, I, 500.
27.Report at the British Association for the Advancement of Science, 1st ser., 32 (1863), 130–l63; repr, with interesting additions in F. Jenkin, Reports of the committee of Electrical Standards (London, 1873), 59–96.
28. Gauss introduced only the definition of the magnetic pole; credit for the remaining parts of the system is shared by Weber, Thomson, and Maxwell.
29. I. B. Hopley, in Annals of Science, 15 (1959), 91–107.
30.Life, 342. Letter of 5 Jan. 1865.
31.Papers, II, 662–663.
32. W. Thomson, Paper on Electrostatics and Magnetism (London, 1873). 447–448n.
33.Report of the British Association for the Advancement of Science, 1st ser., 32 (1863), 163–176.
34. W. Thomson, Mathematical and Physical Papers (Cambridge, 1882–1911) II, 61–103
35.Treatise, 3rd ed., II, 228. Other illustraions were given by Boltzmann and Rayleigh. The original MS of Maxwell’s 1865 paper, preserved in the archives of the Royal Society, contains a curious canceled passage likening the action of two inductive circuits on the field to the action of two horses pulling on the swingletree of a carriage. This in essence is Rayleigh’s analogy.
36. Comment on a paper by G. Forbes, in Proceedings of the Royal Society of Edinburgh, 9 (1878), 86.
37.Treatise, II. sec. 575. Rayleigh (4th Baron), Life of Lord Rayleigh (London, 1924), 48, letter from Maxwell to Rayleigh of 18 May 1870. Papers, I, 485n; Treatise, II, sec. 575.
39. The clearest physical treatment is by L. Page and N. I. Adams, in American Journal of Physics, 13 (1945), 141.
40.Treatise, II, sec. 615.
41.Ibid., secs. 600–601.
42. G. G, Stokes, Mathematical and Physical Papers, IV (Cambridge, 1904), 157–202.
43. J. Larmor, ed., Memoir and Scientific Correspondence of Sir G. G. Stokes, II (London, 1910), 25–26. Letter to Stokes of 15 October 1864.
44. Lord Rayleigh, Scientific Papers, I (Cambridge, 1900), 111-134, 518–536; J. Willard Gibbs, Scientific Papers, II (London, 1906), 223–246; see Papers, II, 772 f. for Maxwell’s account.
45. Thomson, Mathematical and Physical Papers, III , 466,–468.
46.Treatise, II, sec. 866.
47.Life, 394, letter to Bishop Ellicott of 22 Nov. 1876.
48. W. Whewell, Philosophy of the Inductive Sciences, 2 vols. (London, 1840), passim. See Life, 215, letter to R. B. Litchfield of 6 June 1855.
49.Papers, I, 564.
50. Thomson, Mathematical and Physical Papers, II, 28; for Maxwell’s comments, see Papers, II, 767–768.
51. T. Young, in Phitosophical Transactions of the Royal Society, 94 (1804), 1.
52. Unpublished MS at Cambridge, “On an Experiment to Determine Whether the Motion of the Earth Influences the Refraction of Light.”
53. The letter is lost but see Maxwell’s reply dated 6 May 1864 in J. Larmor, ed., Memoir and Scientific Correspondence of Sir G. G. Stokes, II (London, 1910), 23–25. I am indebted to Dr. A. M. Bork for the connection, which is obscured by the first part of Larmor’s footnote on p. 23.
54. W. Huggins, in Phitosophical Transacttons of the Royal Society, 158 (1868), 532.
55.Nature, 21 (1880), 314, 315, See Michelson’s comments in American Journal of Science, 122 (1881), 120; also J. C. Adams to Maxwell (17 July 1879) on the feasibility of the astronomical test (Cambridge MSS).
56. Reprinted with the FitzGerald-Lorentz correspondence in S. G. Brush, Isis, 58 (1967) 230–232.
57.Treatise, II, sec. 769.
58.Papers, II, 121–124.
59. Cf. J. E. McDonald, in American Journal of Physics, 33 (1965), 706–711.
60.Papers, II, 329–331, 391–392.
61. In Order of citation, secs, 86, 95–102, 19–21, 280–282 with app.; and 129.
62. Secs. 756–757 and app. to ch. 17.
63. The first statement is in a letter to Thomson of 5 June 1869, in Proceedings of the Cambridge Philosophical Society, 32 (1936), 738–739, See J, Bromberg. in American Journal of Physics, 36 (1968), 142–151.
64. Thomson, Papers on Electrostatics and Magnetism, 15–41, paper of 1845; F. O. Mossotti, in Archives des sciences physiques et naturelles, 6 (1847), 193.
65. Y. Aharonov and D. Bohm, in Physical Review, 115 (1959), 485–491; 123 (1961), 1511–1524.
66.Papers, II, 43.
67.Life, 142 143; C. C. Gillispie, Scientific Change, A. C. Crombie, ed, (London, 1963) 431 ff.; S. G. Brush, Kinetic Theory, I (Oxford, 1965), 30n; Elizabeth Wolfe Garber, thesis (Case Institute, 1966) and in Historical Studies in the Phvshaf Sciences, 2 (1970), 299; P. M. Heimann, in Studentes in History and Philosophy of Science, I (1970), 189.
68. M. Kac, in American Journal of Mathematics, 61 (1939), 726–728, See also T. H.. Gronwall, in Acta mathematica, 17 (1915), I.
69. J. Larmor, ed., Memoir and Scientific Correspondence of Sir G. G. Stokes, II (London, 1910), 10.
70.Report of the British Association for the Advancement of Science, 28 , pt. 2 (1860), 16.
71. “My better ½ who did all the real work of the kinetic theory is at present engaged in other researches. When she is done I will let you know her answer to your enquiry [about experimental data].” Postcard from Maxwell to Tait, 29 Dec, 1877, Cambridge MSS.
73.Papers, II, 379–380.
74.Papers, II, 681. Royal Society Archives 1878, Maxwell 70, Thomson’s report marked 123 in upper right-hand corner.See S. G. Brush and C. W. L. Everitt, in Historical Studies in the Physical Sciences, I (1969), 105–125.
75. See S. G. Brush, in American Journal of Physics, 24 (1962), 274n.
76. Letter from C. Truesdell to C. W. F. Everitt, 16 Dec, 1971.
77.Papers, II, 376.
78.Nature, 20 (1877), 242.
79.Life, 570; A. Schuster. The Progress of Physics 1875–1878 (Cambridge, 1911), 29; also History of Cavendish Laboratory (London, 1910), 31.
80. See the two eds. of Watson’s Treatise on the Kinetic Theory of Gases (Oxford, 1876; 2nd ed., 1893); and the commentaries on Maxwell’s paper by Boltzmann, in Phitosophical Magazine, 14 (1882), 299–312; by Rayleigh, ibid., 33 (1892), 356–359, and Scientific Papers, III 554; and by J. Larmor, Mathematical and Physical Papers, II (Cambridge, 1929), app. III 743–748. Rayleigh incorrectly attributes one of Watson’s results to Maxwell, as Watson, in the 2nd ed. of his book (pp. 22–23), succeeds in pointing out, without appearing to do so, with the beautiful oblique courtesy to be expected from the man who was, after all, the Rector of Berkswell.
82.Papers, II, 692.
83.Proceedings of the Royal Society, 27 (1878), 304.
84.Papers, II 742.
85.Treatise, I, sec. 135a.
86. Letter of 11 July 1961 from S. C Chapman to S. G. Brush quoted in S. G. Brush, in American Journal of Physics, 24 (1962), 276n.
87. E. Ikenberry and C. Truesdell, in Journal of Rational Mechanics and Analysis, 5 (1956), 4–128.
88.Papers, 1, 79.
89. R. K. Luneberg, Lectures on Optical Design (Providence R.I., 1944), mimeographed notes.
91. For example, C. G. Wynne, in Proceedings of the Physical Society of London, 65B (1952), 429.
92. W. J.M. Rankine, Miscellaneous Scientific Papers (London, 1881), 564.
93.Papers, II, 161–207; Royal Society Archives 1869.
94. A photograph of the governor designed by Fleeming Jenkin is given by I. B. Hopley, in Annals of Science, 13 (1951), 268. See also Otto Mayr, in Isis, 62 (1971), 425–444; and Notes and Records. Royal Society of London, 26 (1971), 205 228.
95. C. W. Siemens, in Phitosophical Transactions of the Royal Society, 156 (1866), 657–670.
96. Norbert Wiener, Cybernetics, or Control and Communication in the Animal and the Machine (Cambridge, Mass., 1948), 11–12.
97.Philosophical Magazine, 16 (1908), 818.
98. C. G. Knott. Life and Scientific Work of Peter Guthrie Tait, 214–215.
99.History of the Cavendish Laboratory, 31.
I. Original Works, Most of the technical papers were reprinted in the Scientific Papers of J. Clerk Maxwell, W. D. Niven, ed., 2 vols. (Cambridge, 1890; repr. NewYork, 1952), cited in the footnotes as Papers. About twenty papers and short articles were omitted from the collection; most may be found in Nature, Electrician, Reports of the British Association, Proceedings of the London Mathematical Society, Proceedings of the Royal Society of Edinburgh, and Cambridge Reporter. The abstracts of longer papers printed in the Proceedings of the Royal Society are also often of interest. Maxwell’s books are ’Theory of Heat (London, 1870; 4th ed. greatly rev., 1875; 11th ed. rev, with notes by Tord Rayleigh, 1894); Treatise on Electricity and Magnetism, 2 vols. (Oxford, 1873): 2nd ed., W. D. Niven, ed.(1881); 3rd ed., J. J. Thomson, ed. (1891), cited as Treatise—revision of the 2nd ed. was cut short by Maxwell’s death; the changes in the first eight chs. are extensive and significant; references here are to the 3rd ed.; Matter and Motion (London, 1877), 2nd ed., with appendixes by J. Larmor (1924); Elementary Treatise on Electricity, W. Garnett, ed. (Oxford, 1881; 2nd ed., rev., 1888), cited as Elementary Treatise; and The Unpublished Electrical Writings of Hon. Henry Cavendish (Cambridge, 1879), 2nd ed., with further notes by J. Larmor (1924), which contains an introductory essay and extensive notes by Maxwell.
II. Secondary Literature. The standard biography is L. Campbell and W. Garnett, The Life of James Clerk Maxwell (London, 1882), cited as Life; 2nd ed., abridged but containing letters not given in 1st ed. (1884). Extensive correspondence appears in Memoir and Scientific Correspondence of Sir George Gabriel Stokes, J. Larmor, ed., 2 vols. (London, 1910); C. G. Knott, Life and Scientific Work of Peter Guthrie Tait (Cambridge, 1911); Silvanus P. Thomson, Life of Lord Kelvin, 2 vols. (London, 1912); J. Larmor, “The Origin of Clerk Maxwell’s Electric Ideas as described in Familiar Letters to W. Thomson.” in Proceedings of the Cambridge Philosophical Society. Mathematical and Physical Sciences, 32 (1936), 695–750, repr. as a separate vol. (Cambridge, 1937). Other letters or personal material will be found in standard biographies of W. C. and G. P. Bond, H. M. Butler, J. D. Forbes, J. G. Fraser, F. Galton, D. Gill, F. J. A. Hort, T. H. Huxley, Fleeming Jenkin, R. B. Litchfield, by Henrietta Litchfield (London, 1903), privately printed; a copy is in the library of the Working Men’s College, London; C. S. Peirce, Tord Rayleigh, H. Sidgwick, W. Robertson Smith, Sir James FitzJames Stephen, and George Wilson, and in the collected papers of T. Andrews, Sir William Huggins, J. P. Joule, J. Larmor, and H. A. Rowland.
See also C. Popham Miles, Early Death not Premature: Memoir of Francis L. Mackenzie (Edinburgh, 1856), 216-218; W. Garnett, Heroes of Science (London, 1886); R. T. Glazebrook, James Clerk Maxwell and Modern Physics (London, 1896); F. W. Farrar, Men I Have Known (London, 1897); A. Schuster, The Progress of Physics 1875–1908 (London, 1911); Biographical Fragments (London, 1932); and “The Maxwell Period,” in History of the Cavendish Laboratory 1871–1910 (London, 1910), no editor identified; Aberdeen University Quarter-Centenary Volume (Aberdeen, 1906); D. Gill, History of the Royal Observatory, Cape of Good Hope (London, 1913), xi-xiv, for Maxwell at Aberdeen; F. J. C. Hearnshaw, History of King’s College, London (London, 1929; J. J. Thomson, ed., James Clerk Maxwell 1831–1931 (Cambridge, 1931); J. G. Crowther, British Scientists of the Nineteenth Century (London, 1932); K. Pearson, “Old Tripos Days at Cambridge,” in Mathematical Gazette, 20 (1936), 27; C. Domb, ed., Clerk Maxwell and Modern Science (London, 1963); and R. V. Jones, “James Clerk Maxwell at Aberdeen 1856–1860,” in Notes and Records. Royal Society of London, 28 (1973), 57–81.
Useful general bibliographies are given by W. T. Scott, in American Journal of Physics, 31 (1963), 819–826, for the electromagnetic field concept; and by S. G. Brush in Kinetic Theory (Oxford, 1965, 1966, 1972) and in American Journal of Physics, 39 (1971), 631-640 tor kinetic theory. For thermodynamics see Martin J. Klein in American Scientist, 58 (1970), 84–97. For the theory of governors see two articles by Otto Mayr in Isis, 62 (1971), 425–444; and Notes and Records. Royal Society of London, 26 (1971), 205–228; references to other early papers on governors are given in the later editions of E. J. Routh, Treatise on the Dynamics of a System of Rigid Bodies, II (6th ed., London, 1905), sec. 107.
For reciprocal diagrams see A. S. Niles, Engineering, 170 (1950), 194–198, and S. Timoshenko, History of the Strength of Materials (New York, 1953); both authors exaggerate the neglect of Maxwell’s work by his contemporaries. Studies in History and Philosophy of Science, 1 (1970), 189–251 contains four articles on Maxwell with lengthy bibliographies.
The two principal collections of unpublished source materials are in the Archives of the Royal Society and in Cambridge University Library, Anderson Room, where the Stokes and Kelvin MSS should also be consulted. Materials elsewhere at Cambridge are in the Cavendish Laboratory, Peterhouse and Trinity College libraries, and the Cambridge Library. Other items are at Aberdeen University; St. Andrews University (Forbes MSS); Berlin, Staatsbibliothek der Stiftung Preussischer kultur Besitz; Bodleian Library, Oxford (Mark Pattison MSS); Burndy library, Norwalk, Conn.; Edinburgh University (Tait MSS); Glasgow University (Kelvin MSS); Göttingen, Niedersächisische Staats- und Universitätsbibliothek; Harvard University (Bond MSS); Imperial College, Lyon Playfair Library (Huxley MSS); Institute of Electrical Engineers (Heaviside MSS); Johns Hopkins University (Rowland MSS); Manchester Institute of Science and Technology (Joule MSS); Queen’s University, Belfast (Andrews, J. Thomson MSS); Royal Institution (Faraday, Tyndall MSS); University of Rochester, Rush Rhees Library; U.S. Air force Cambridge Center (Rayleigh MSS).
A large collection of watercotor paintings of Maxwell’s childhood by Jemima Wedderburn (later Mrs. Hugh Blackburn) and others are now in the possession of Brigadier J. Wedderburn-Maxwell, D.S.O., M.C.
C. W. F. Everitt
James Clerk Maxwell
James Clerk Maxwell
The Scottish physicist James Clerk Maxwell (1831-1879) formulated important mathematical expressions describing electric and magnetic phenomena and postulated the identity of light as an electromagnetic action.
James Clerk Maxwell was born in Edinburgh on June 13, 1831. His father, who was a lawyer, was first named John Clerk but adopted the surname of Maxwell upon his succession to an estate, Glenlair, situated near Dalbeattie. James was a quiet child "much given to reading, drawing pictures, chiefly of animals, and constructing geometric models." A favorite pastime was reflecting the sun about his room with a highly polished tinplate, an activity which seemed to presage his adult preoccupation with optical phenomena.
Education and Early Researches
James's strange mode of dress helped earn him the nickname "Dafty" at Edinburgh Academy, where he was enrolled in 1841. His father, aware of his son's scholarly aptitude, began taking James to meetings of the Edinburgh Society of Arts and of the Royal Society. Through his school studies James had become interested in a problem in applied mathematics, the construction of a perfect oval. At the age of 15 he communicated a paper to the Edinburgh Royal Society, "On the Description of Oval Curves and Those Having a Plurality of Foci." He remained at Edinburgh Academy until 1847.
Optical studies occupied much of Maxwell's time in 1847. At Glenlair he experimented with Newton's rings, a chromatic effect produced by pressing lenses together, and studied the color variations of soap bubbles. In the spring of that year his uncle took him to see a demonstration of a "polarizing prism," and he engaged in observing the effects of polarized light by means of specimens of Iceland spar. A paper read to the Edinburgh Royal Society in 1850, "On the Equilibrium of Elastic Solids," was the outcome of these studies. There Maxwell described strains set up in elastic substances such as gelatin and compared his experimental results which had been optically obtained with his newly derived theory of such equilibrium. This work was written in Maxwell's third, and last, year at the University of Edinburgh; he had enrolled in 1847.
In 1850 Maxwell went to Cambridge University as an undergraduate. He enrolled at Peterhouse but in December moved to Trinity College. In due course he became a scholar of the college and a member of the select Essay Club, familiarly known as the "apostles" since its membership was limited to 12. He took the bachelor's degree in 1854. Following graduation Maxwell was elected a fellow of Trinity College and joined its staff of lecturers, with responsibility for the subjects of hydrostatics and optics. He also carried out optical investigations with tops which were proportionally colored and rapidly revolved to determine the true mixture of colors.
Aberdeen and King's College Professorships
Maxwell left Cambridge in 1856 to accept an appointment as professor of natural philosophy in Marischal College, Aberdeen. There he met Katherine Mary Dewar, daughter of the principal of the college. They were married in 1858. During the years of his Aberdeen professorship Maxwell continued his study of the theory of colors. However, a problem regarding the stability of the rings of Saturn also occupied much of his attention.
The French mathematician Pierre Simon de Laplace had shown that if Saturn's ring were a solid it could not be stable. Maxwell decided to study a hypothetical mathematical model of the planet in which the ring was "loaded" at one or more points. In this manner he found a solution which accounted for the motion of the ring on Newtonian laws of physics but which predicted that the loads would be visible as satellites. Eventually, however, he discovered an alternative solution which entailed a fluid ring or one constructed of a colloidal arrangement of separate small solid particles. For this work Maxwell received the Adam Prize offered by St. John's College in 1857, in honor of the discovery of Neptune by John Couch Adams.
The following year Maxwell's professorship was dissolved when Marischal College was amalgamated with King's College to form the University of Aberdeen. He obtained, however, the professorship of natural philosophy and astronomy in King's College, London. There his formal responsibilities to the college were quite demanding, involving regular evening classes for working men and artisans in addition to 9 months of lecturing for the regular students. Nevertheless he continued his scientific researches.
At the British Association meeting in Oxford in 1860, Maxwell exhibited a device for mixing colors of the spectrum. He also presented an important paper on Daniel Bernoulli's theory of gases. The theory depicted gas as consisting of a number of independent particles moving without mutual interference except upon collision. Maxwell demonstrated mathematically that the apparent viscosity of gases, their low heat conductivity, and the known laws of gas diffusion could be satisfactorily explained by this theory.
Maxwell resigned his professorship at King's College in 1865 and retired to Glenlair, where he produced some of his most important scientific writing. He presented his dynamic theory of gases to the Royal Society of London in 1866. His treatise on heat appeared in 1870, and the great work on electricity and magnetism was published in 1873.
Organization of the Cavendish Laboratory
In 1870 the Duke of Devonshire, who was chancellor of Cambridge, indicated his desire to build and outfit a physical laboratory for the university. In accepting the offer, university officials established a chair of experimental physics for the laboratory directorship. Maxwell became the first director of the Cavendish Laboratory in 1871.
Two important investigations undertaken at the Cavendish Laboratory when it opened in 1874, and supervised personally by Maxwell, concerned the accurate measurement of electrical resistance. The first was the testing of Ohm's law, a mathematical statement of the linear proportionality between electrical potential and the product of electrical resistance and current. Prior to the Cavendish researches there was no evidence that the law was more than a good approximation of the behavior of nature, nor was there any theoretical reason why the law should hold accurately over extended ranges of current or potential. The Cavendish investigations demonstrated the adequacy of Ohm's statement to within 1 part in 200,000 over large variations of these variables. Paralleling this work was an investigation of electrical standards and the determination of the ohm in absolute units of measure.
Influence on American Physics
In the early 1870s Maxwell not only played an important role in the scientific renaissance at Cambridge, but he was also instrumental in encouraging the development of high-level experimental physics in America. Original researchers who could understand the sophisticated mathematical formalism of European physicists such as Maxwell were rare at that time in the United States. The most eminent American scientific publication, American Journal of Science, was largely devoted to geological, botanical, and zoological topics; its editors simply did not understand exact science and its methods.
This was the situation faced by Henry Augustus Rowland, a young civil engineer from Rensselaer Institute, when he attempted to publish some magnetic researches. The American Journal editors repeatedly rejected Rowland's papers, forcing him in desperation to write directly to Maxwell. Maxwell received Rowland's work "with great interest" and saw to its immediate publication in the English Philosophical Magazine.
When Daniel Coit Gilman set out to find a faculty for a newly endowed university in Baltimore in 1875, he heard of Maxwell's interest in Rowland's work. For Gilman this endorsement was worth more than a "whole stack of recommendations." Thus Rowland became the first chairman of the physics department at Johns Hopkins University and until his death in 1901 led the way in establishing high-quality experimental physics in America.
Maxwell's work in optics, kinetic theory of gases, and electromagnetism forms some of his most important contributions to science. His paper "On the Theory of Compound Colours" of 1860 summarized numerous experiments with the colored tops mentioned above. By means of another device of his own invention, the "Colour-box," he investigated the effect of mixing given proportions of light taken from the spectrum. He showed that any given color sensation may be produced by combinations in due proportion of rays taken from three parts of the spectrum; that is, from three so-called primary colors. These experiments also tended to confirm the hypothesis that color blindness was due to the viewer's insensitivity to one of the three primary colors. For this work Maxwell received the Rumford Medal of the Royal Society of London.
The concept of discrete particles in his solution of the Saturn's rings problem may have led Maxwell to the study of gases; his first papers on this subject appeared in 1860. He pointed out that the velocities of different molecules of a gas, even if equal to start with, would become different in consequence of collisions with their neighbors. He therefore employed a statistical method of treating the problem in which the total number of molecules was divided into a series of groups. The velocities of all of the molecules constituting a group were the same within narrow limits. By taking the average velocity of each group into account, he was able to determine an important relationship between this velocity and the number of molecules in the group. He published papers on gas theory almost continuously until his death.
However, Maxwell is best remembered for his work on electricity and magnetism, which began with the important study of 1856 on lines of force as conceived by the English physicist Michael Faraday. Maxwell took Faraday's view that electrical and magnetic effects did not arise from attractions at a distance of electric or magnetic matter. Rather these effects were the means by which changes of some unknown description in an "ether" which filled all space became known to the experimenter.
Maxwell studied attractions of magnetic lines of force by means of a model based on the vortices or whirlpools of a fluid or mobile medium. This model was used as a mechanical illustration "to assist the imagination, but not to account for the phenomena." The centrifugal force of the vortices was accompanied by a tension directed parallel to the lines of force issuing from a magnetic pole. He found great difficulty, however, in conceiving of vortices revolving side by side in the same direction about parallel axes. The difficulty lay in understanding how contiguous portions of consecutive vortices could move in opposite directions.
Maxwell's well-known solution was to imagine that a layer of "particles, acting as idle wheels" was interposed between each vortex and its neighbor. Contiguous sides of the vortices then acted on the idle wheels to produce a direction of rotation opposite to that of the vortices themselves. The remarkable feature of this model discovered by Maxwell was that the action of the "idle wheels" could be used to analyze electric currents. His discovery yielded a mathematical relationship between electricity and magnetism.
Maxwell also studied dynamical changes in the lines of force and introduced the concept of energy storage and distribution in the ether. These ideas were developed in a great paper, "On a Dynamical Theory of the Electromagnetic Field," read to the Royal Society of London in 1864. He portrayed electromagnetic action as traveling through space at a definite rate in waves which were transverse to the direction of propagation. The paper was expanded into his classic Treatise on Electricity and Magnetism (1873), in which he postulated the identity of light as an electromagnetic phenomenon. The test of this theory in various experimental forms occupied the time of a large number of physicists throughout the world for the remainder of the century.
During the last years of his life Maxwell devoted much time to editing the Electrical Researches of Henry Cavendish (1879). He also wrote a textbook on heat and a small treatise on dynamics called "Matter and Motion." Among his other papers are some on geometric optics and several, published mostly in the Transactions of the Royal Edinburgh Society, on reciprocal figures and diagrams of force.
Maxwell died at Cambridge on Nov. 5, 1879. A memorial edition of his scientific papers was organized and published by the Cambridge University Press in 1890. Several lines from one of his essays written at Cambridge in 1856 serve as a fitting memorial to this great electrical theorist: "They know the laws by heart, and do the calculations by fingers…. When will they begin to think? Then comes active life: What do they do that by? Precedent, wheeltracks, and finger-posts."
An authoritative and well-documented biography of Maxwell is Lewis Campbell and William Garnett, The Life of James Clerk Maxwell (1882; rev. ed. 1884); the authors, who were personally acquainted with Maxwell, made use of a family diary as well as numerous papers and correspondence collected from members of the British scientific community. A highly readable account is R. T. Glazebrook, James Clerk Maxwell and Modern Physics (1901). Other studies are in J. G. Crowther, British Scientists of the Nineteenth Century (1935) and Men of Science (1936). A recent study is David K. C. MacDonald, Faraday, Maxwell and Kelvin (1964). C. Domb, ed., Clerk Maxwell and Modern Science: Six Commemorative Lectures by Sir Edward V. Appleton and Others (1964), provides extensive discussion of Maxwell's work by a number of highly competent British scientists. □
Maxwell, James Clerk (1831-1879)
MAXWELL, JAMES CLERK (1831-1879)
James Clerk Maxwell is the one theoretical physicist between Isaac Newton and Albert Einstein of a stature comparable to theirs. Maxwell's contributions to science ranged over many areas, of which the two greatest were his creation of the electromagnetic theory of light, and his work on molecular physics, gas theory, and statistical mechanics. He entered the scientific scene in the early 1850s, immediately after the principle of conservation of energy had been established. Its impact is seen everywhere in his work.
A descendant of a distinguished Scottish family, the Clerks of Penicuik, and, by an illegitimate line, of the ninth Lord Maxwell, he was born in Edinburgh but lived much of his life at his estate in Galloway in southwest Scotland, where he inherited 2,000 acres of rich farmland. From the ages of ten to nineteen he was educated in Edinburgh, entering the University of Edinburgh in 1847. At nineteen he went on to Cambridge University to take the rigorously severe mathematical tripos, from which he graduated in 1854 second in order of merit. He became Fellow of Trinity College in the following year and then, in 1856, at twenty-five, was appointed professor of natural philosophy at Marischal College, Aberdeen. In 1858 he married Katherine Mary Dewar, daughter of the principal. Though lacking any prior scientific training, she became an enthusiast in experimental research and worked closely with Maxwell on several experiments, first in color vision and then in physics. They had no children.
In 1860 Maxwell became a professor at King's College, London, where he served for five years. He retired from professorial life in 1866, at the age of thirty-five, to spend six years writing his famous Treatise on Electricity and Magnetism (1873). During the same time he also produced his small but important Theory of Heat (1871). In 1871 he was appointed Cavendish Professor of Experimental Physics at Cambridge and was responsible for designing and setting up the Cavendish Laboratory. Maxwell died of abdominal cancer in 1879 at age forty-eight.
When Maxwell began studying electricity and magnetism in 1854, the field was in a state of confusion. The laws of electric and magnetic force had been established by Charles Augustin de Coulomb in the 1780s, and impressive mathematical structures had been built on them. However, the triumph was unsettled by Hans Christian Oersted's discovery in 1820 of electromagnetism—a peculiar twisting action exerted by an electric current on a magnet. This departure from Newtonian attractions and repulsions met two contrasting reactions. André Marie Ampère sought to reinterpret Oersted's force as a disguised form of attraction. Michael Faraday treated it as primary and related it geometrically to properties of lines of magnetic and electric force.
It is wrong to see Maxwell's achievement as one of merely translating Faraday's ideas into precise mathematical language. Though he once described Faraday as "the nucleus of everything electric since 1830," two other men, William Thomson (Lord Kelvin) and Wilhelm Weber, were equally influential. From Faraday Maxwell gained a way of thinking; from Thomson, the first mathematizations of Faraday's ideas and several groundbreaking connections to the concept of energy; from Weber, the remarkable insight that the ratio of the two kinds of force, electrostatic and electromagnetic, somehow involves a velocity.
Between 1855 and 1868 Maxwell devoted great effort (five substantial papers) to clearing up the confusions in electromagnetism. The outcome was the dramatic discovery that light is an electromagnetic phenomenon, and the prediction—twenty-seven years before they were detected by Heinrich Hertz—of radio waves. Crucial was Maxwell's devising in 1861 of a speculative "ether" transmitting Faraday's lines of magnetic force. To his astonishment he found that this ether would transmit waves. Using some measurements by Weber and Friedrich Kohlrausch, Maxwell then calculated their velocity and found, to his even greater astonishment, that it was just equal to the velocity of light. Thus the great discovery was made and thus began the great intellectual metamorphosis, shaped by Maxwell and Einstein, in which the velocity of light was transformed from an isolated quantity into a universal fundamental constant influencing every part of physics.
The essence of Maxwell's later development of his theory was in the electromagnetic equations and the idea that electric and magnetic energies, instead of being located on charged bodies, are disseminated through space. That he could so quickly discard his ether model was closely related to the new doctrines of energy. Rather than attempt to explain light or electromagnetism in terms of a mechanism, Maxwell demonstrated that one set of unexplained equations describes both. Philosophically, the theory became a theory of relations. In this line of thought, Maxwell was strongly influenced by his mentor at Edinburgh, Sir William Hamilton, who held that all human knowledge is of relations rather than absolutes.
Maxwell's Treatise on Electricity and Magnetism (1873) covered every branch of the science and was a source of ideas and discoveries for fifty years to come.
GASES, MOLECULES, AND STATISTICS
In 1859 Maxwell, who had just completed a famous essay on the structure of the rings of Saturn, chanced to read a paper by Rudolph Clausius on gas theory. Maxwell had proved that the rings had to be composed of large numbers of independent bodies constantly colliding with each other. Clausius, expanding on earlier work by James Prescott Joule and August Karl Krönig, proposed that in a gas the rapidly moving molecules are constantly colliding. His interest at once aroused, Maxwell in a few months had written the first of several papers that created the modern kinetic theory of gases.
Maxwell's and Clausius's innovations were of two kinds, mathematical and physical. Mathematically, the key to dealing with large numbers of molecules was statistics, used not as a means of processing scientific data but as a fundamental explanatory idea. Clausius recognized that molecules must travel a certain average distance between collisions—the mean free path—but restrictively assumed that they all have the same speed. Maxwell transformed the discussion by introducing his velocity distribution function, giving the proportion of molecules traveling with a particular speed. Armed with this mathematical weapon, he could attack many previously intractable physical phenomena. He obtained theoretical formulas for viscosity, diffusion, and heat conduction in gases that then could be compared with experimental data. One startling consequence was that the viscosity of a gas should be independent of its pressure. When this was confirmed in independent experiments by Oskar Emil Meyer and by Maxwell and his wife, it added tremendous credibility to the theory.
The work on gas theory had many extensions. In 1865 Johann Josef Loschmidt used estimates of the mean free path to make the first generally accepted estimate of atomic diameters. In later papers Maxwell, Ludwig Boltzmann, and Josiah Willard Gibbs extended the mathematics beyond gas theory to a new generalized science of statistical mechanics. When joined to quantum mechanics, this became the foundation of much of modern theoretical condensed matter physics.
Through his famous "demon" Maxwell addressed one mystery of energy physics: the relation between the first law of thermodynamics, which states that energy as a whole is conserved, and the second law, which states that mechanical energy will be gradually dissipated. Maxwell was the first person to realize and forcefully argue that the second law is a statistical rather than a dynamical truth. Following this clue, Boltzmann in 1872 found the exact formal expression relating entropy to probability. Their work, together with earlier reflections by Kelvin, framed a discussion of irreversibility in physics, embracing even the nature of time, that has continued to this day.
C. W. F. Everitt
See also: Ampère, André-Marie; Clausius, Rudolf Julius Emmanuel; Electricity; Electricity, History of; Faraday, Michael; Gibbs, Josiah Willard; Magnetism and Magnets; Molecular Energy; Oersted, Hans Christian; Thomson, William.
Brush, S. G. (1976). The Kind of Motion We Call Heat, Vols. 1-2. Amsterdam: North-Holland.
Buchwald, J. T. (1985). From Maxwell to Microphysics. Chicago: University of Chicago Press.
Campbell, L., and Garnett, W. (1882). The Life of James Clerk Maxwell. London: Macmillan.
Everitt, C. W. F. (1975). James Clerk Maxwell, Physicist and Natural Philosopher. New York: Scribner.
Harman, P. (1998). The Natural Philosophy of James Clerk Maxwell. Cambridge, Eng.: Cambridge University Press.
Siegel, D. M. (1991). Innovation in Maxwell's Electromagnetic Theory. Cambridge, Eng.: Cambridge University Press.
Whittaker, E. T. (1954). History of the Theories of Aether and Electricity, Vols. 1-2. New York: Philosophical Library.
Maxwell, James Clerk
MAXWELL, JAMES CLERK
MAXWELL, JAMES CLERK (1831–1879), Scottish physicist and natural philosopher.
The natural philosophy of James Clerk Maxwell includes both his physics and his inseparable broader philosophical views on science and the world and reflects a historical transition in Great Britain from the culture of Scottish Enlightenment (he was born in Edinburgh) and the gentlemanly generalism of his family to the combined culture of the Industrial Revolution, Cambridge physics, German philosophy, empire, and the Victorian era. Maxwell's natural philosophy also reflects the rich intersection of a number of fields of inquiry that have since become distinct: mathematics, experimental physics, logic, philosophy of language, rhetoric, cognitive psychology, aesthetics, natural and personal theology, engineering, political economy, and muscle and optical physiology. His contributions to physics span the areas of color theory and optics, elastic solids, geometry, mechanics, physical astronomy, molecular physics, and electro-magnetism. They are characterized by a combination of abstract mathematical sophistication, methodological and linguistic awareness and rigor (in the form of the methods of scientific analogy, metaphor, and illustration), theoretical unification and cross-fertilization, and the engagement of concrete imagination in the service of understanding in the form of geometrical and mechanical models and analogies.
Maxwell attended Edinburgh Academy with future fellow researches Peter G. Tait and Fleeming Jenkin. He became a skilled draftsman, poet, and amateur scientific experimenter. In 1847 he entered the University of Edinburgh, where he studied literature and natural philosophy for three years, became the protégé of natural philosopher James Forbes, and studied philosophy with William Hamilton. With recommendations from Forbes, Blackburn, and William Thomson (his cousin's husband), he moved to Cambridge in 1850, studying, like Thomson and Stokes before him, with a private tutor (the physical geologist William Hopkins), as well as under the supervision of the master of Trinity College, the scientist, philosopher, and educator William Whewell. In 1856 he took a post at Marischal College, in Aberdeen, where he married the principal's daughter, Katherine Dewar. In 1860 he moved to London to take a position at King's College London, and in 1861 he became a fellow of the Royal Society. He also joined the efforts to establish new electrical units, which were crucial to the new telegraphic cable networks that sustained the British Empire. In 1865 he retired to Glenlair and he remained there until 1871, when he was appointed professor of experimental physics at Cambridge and designer and director of the Cavendish Laboratory. In 1873 he became the physics editor of the ninth edition of the Encyclopaedia Britannica.
In the area of color theory, Maxwell established a coordinate system and an algebraic equation in terms of quantities for three primitive colors: red, green, and blue. He also designed a spinning color disk to study the mixture of colors and a color box to compare different colored lights, and he elaborated a theory of optical instruments. It is against this background that he developed his interest in the optical properties of elastic systems under mechanical stress. The combination of mechanics and optics reappeared in his best known contribution to science, his theory of electromagnetism. Maxwell borrowed Michael Faraday's experimental results about the relation between electricity and magnetism and the rotational nature of magnetism shown by its effect on light and his notion that electric and magnetic forces act contiguously and along curved lines of force between polar opposite states. In order to capture mathematically the physics of contiguous action, which is opposed to the Newtonian model of action at a distance, Maxwell also borrowed the differential calculus that William Thomson, first baron Kelvin, applied to analogies between heat flow and the mechanics of continuous systems on the one hand and electric and magnetic action on the other. He thus formulated a unified mathematical theory of electromagnetism based on the notion of fields and of a mechanical ether that pervades the universe and can store and communicate energy. A famous paper from 1861 presents a molecular model of the electromagnetic ether with rotating vortices in rolling contact. To incorporate the connotation of an imaginary mechanical model illustrating electro-magnetic phenomena and quantities, Maxwell introduced scientific metaphors such as "electric tension." The theory predicted the existence of electromagnetic waves and the value of their velocity of propagation, which was very close to the adopted value of the velocity of light. On this basis Maxwell asserted the electromagnetic nature of light and the reduction of optics to electromagnetism. His ideas appeared in the survey Treatise on Electricity and Magnetism (1873).
Maxwell's application of mechanics, or dynamics (with force and energy) in the form of molecular physics, extended to macroscopic astronomy and microscopic molecules. He explained the stability of Saturn's rings in terms of the velocity of an indefinite number of small independent particles orbiting the planet at different distances. This model strengthened his interest in statistical models of macroscopic, apparently non-mechanical properties such as temperature, pressure, and viscosity, and led him to his dynamic theory of gases. He explained the viscosity of gases as the diffusion of momentum between layers of spherical elastic particles in collision, independent of their density. His successful predictions and experiments supported belief in the existence of molecules of matter and helped establish some of their properties. They also cemented the use of a statistical method, describing only the group properties of populations of identical molecules. By contrast, the historical method describes the properties and evolution of individuals. Maxwell's "demon" is a thought experiment intended to show that the possibility of reversing the flow of heat from hot to cold at the molecular level establishes the uncertain and incomplete nature of statistical knowledge, including that of the irreversibility of macroscopic processes described by the second law of thermo-dynamics. Maxwell's contributions to physics, then, represent the grand culmination of the mechanical view of the world on the brink of its collapse in the early twentieth century.
Maxwell, James Clerk. Treatise on Electricity and Magnetism. Oxford, U.K., 1873.
——. The Scientific Papers of James Clerk Maxwell. 2 vols. Edited by W. D. Niven. Cambridge, U.K., 1890.
Campbell, Louis, and William Garnett. The Life of James Clerk Maxwell. 1882. New York, 1969.
Cat, Jordi. "On Understanding: Maxwell on the Methods of Illustration and Scientific Metaphors." Studies in History and Philosophy of Modern Physics 32B, no. 3 (2001): 395–442.
Goldman, Martin. The Demon in the Aether: The Life of James Clerk Maxwell. Edinburgh, 1983.
Harman, P. M. The Natural Philosophy of James Clerk Maxwell. Cambridge, U.K., 1995.
Siegel, Daniel M. Innovation in Maxwell's Electromagnetic Theory: Molecular Vortices, Displacment Current, and Light. Cambridge, U.K., 1991.
Maxwell, James Clerk (1831-1879)
Maxwell, James Clerk (1831-1879)
James Clerk Maxwell was a physicist who introduced a new paradigm with his electromagnetic theory, influencing generations of researchers. Maxwell was without a doubt a child prodigy. At an early age, he solved geometric problems and wrote explanations that intrigued academics. Just as he considered how charged particles interact with their surrounding area , one might consider the interaction of the conditions of his inherent nature and the environment of his early childhood. Maxwell's life could make a good case study for the strength of the influences of heredity compared to environment as he had strong influences from both sources.
James Clerk Maxwell was a descendent of the Clerk and the Maxwell families, both with distinguished heritages. His father inherited a house in Edinburgh and land in the countryside. Maxwell was born in 1831 in Edinburgh while his parents were waiting for their country house to be built. They moved shortly after he was born. His father was a lawyer but was not very aggressive in pursuing new business. John Clerk Maxwell enjoyed studying science and building mechanical devices. As young as three years old, James was following his father insisting to know how everything worked. He was very close to his father all of his life. Maxwell's mother died suddenly when he was eight years old. For two years after his mother's death, he was educated by a series of tutors, but none were found suitable for Maxwell and his unique way of learning. His father and his aunt arranged for him to begin studies at the Edinburgh Academy. At the academy, Maxwell started to show his true capabilities and his classmates were less cruel.
In 1847, at age 16, Maxwell began his college studies at the University of Edinburgh. He spent three years there and during this time, he contributed two papers to the Edinburgh Royal Society. When he finished his studies at Edinburgh, his father sent him to Peterhouse, but shortly after beginning there, he transferred to Trinity where he believed he had a better chance for a fellowship. Maxwell studied at Trinity from early 1851 until he graduated in 1854. After graduation, he was awarded the fellowship. Maxwell then applied for a position at Marischal College to be close to his ailing father. However, his father did not live much longer. After his father's death in April 1855, he accepted the position at Marischal.
In 1858, he married the well-educated Katherine Dewar. Two years later, he had to leave Marischal, the victim of an institutional merger. He was immediately invited to teach at King's College, London. It was in London that he did his most prominent work. He remained there until he resigned his post (probably due to exhaustion) in the spring of 1865. He spent most of the next five years at his country home writing a book on his theory. He considered himself retired.
To stay involved in academia, Maxwell did consulting work for Cambridge. His encouraging of Cambridge to offer courses on heat and electromagnetism directly influenced the foundation of the Cavendish Laboratory. It was only natural that the first Cavendish professorship should be offered to him and he accepted. During his eight years as Cavendish professor, he worked to prepare for publication the experiment papers Henry Cavendish had written. It is well accepted that this self-imposed responsibility was influential in bringing due respect to Cavendish's work. In May 1879, as the school year wound down, it was obvious to many that Maxwell's health was beginning to fail. He tried to return to Cambridge in the autumn, but he could scarcely walk. Maxwell died the same year of abdominal cancer at the age of 48.
Maxwell's work leading to his kinetic theory of gases and his theory of electromagnetic fields was a logical advance from James Prescott Joule's work. Both researchers measured the velocity of gas molecules and both recognized that heat was not the fluid that it once was thought to be. The importance of Maxwell's work was the direction that it gave to new understanding. Joule showed only the scientific community what was possible to measure and what might be proven. Maxwell went forward with detailed mathematical models that left no holes unfilled, with one important exception. Maxwell used statistics to show the high probability that proposed laws would direct the behavior of matter. Discussing the probability of natural law took science away from determinism. This opened the door for the modern study of physics . Albert Einstein's theory of relativity and the recently nurtured chaos theory could not have been developed except for this new philosophical direction.
Maxwell began measuring the average velocity of a gas molecule with the objective to investigate whether the perceived random order of its movement could be predicted with some degree of accuracy. What he found was that the greater the velocity of the molecules, the greater the heat generated. There was a direct relationship between the amount of movement among the molecules and the amount of heat in a gas. In this experimental demonstration, heat was shown undeniably to be a property of particle movement and not a fluid flowing from one object to another. Furthermore, Maxwell's findings showed that the movement of particles could be controlled through increasing or reducing heat.
Maxwell understood Michael Faraday's theory of electric and magnetic fields. He worked to demonstrate what Faraday could not explain himself through complex calculations. Assuming that the space surrounding a charged particle contained a field of force, Maxwell created a mathematical model demonstrating all the possible phenomena of electric and magnetic fields. Through this model, Maxwell demonstrated that the electric and magnetic fields worked together. He coined the term "electromagnetic" to name this new breakthrough.
This discovery is important for chemistry because it ultimately led to the discovery of the electron. Joseph John Thomson discovered the electron when he was investigating the effects of the electromagnetic field on gases, applying the principles that Maxwell had established. Research on the effects of light on elements was furthered by Maxwell's work. His subsequent work on the velocity of the oscillation of electromagnetic fields demonstrated that light should be considered a form of electromagnetic radiation.
See also Atomic structure; Electromagnetic spectrum; Quantum electrodynamics (QED); Relativity theory
Maxwell, James Clerk
Maxwell, James Clerk
James Clerk Maxwell is generally regarded as one of the outstanding physicists of the nineteenth century. He made important advances in the theory of electricity and magnetism, as well as in thermodynamics and the kinetic theory of gases. Many modern ideas about these topics are still based on his work from the mid-1800s.
Maxwell was born in Edinburgh, Scotland, and his father greatly encouraged him in his intellectual pursuits. At the age of fourteen, while a student at the Edinburgh Academy, he wrote a paper on ovals and geometric figures with more than two foci. His paper was read to the Royal Society of Edinburgh by an adult member because it was considered inappropriate for a young boy to present it to the society himself. Although some of the ideas in this paper had been discussed earlier by the renowned French mathematician René Descartes, it was still an amazing achievement for a teenage boy.
At sixteen, Maxwell entered Edinburgh University, where he studied physics, mathematics, and logic. Three years later he went to Cambridge University, from which he graduated in 1854 with a degree in mathematics.
In 1856 Maxwell became professor of natural philosophy at Marischal College in Aberdeen. There he became interested in the theory of gases and in the study of electricity and magnetism. His position as professor, however, was eliminated in 1860 when Marischal and another college merged.
Maxwell spent the next five years at King's College in London. He successfully applied statistical methods to describe the movements of the tiny invisible particles of a gas, an approach adopted a century earlier by the Swiss mathematician Daniel Bernoulli, but with less sophisticated mathematics. The Austrian physicist Ludwig Boltzmann also studied the problem of gas behavior at the same time as Maxwell, and the names of both men are usually associated with the kinetic theory of gases.
Because of his overwhelming interest in the science of electricity, Maxwell was drawn to the writings of the English physicist Michael Faraday, who had begun publishing his three-volume Experimental Researches in Electricity in 1839. Faraday's approach was almost entirely experimental, and Maxwell saw this as an opportunity to treat the subject in mathematical terms. Beginning in the 1850s, Maxwell published several papers on electricity, including the analogy between electricity and heat from a mathematical point of view. These research efforts culminated in his important writings in the 1860s and 1870s on electromagnetic theory and his identification of light as an electromagnetic wave. Maxwell's theoretical conclusions about electro-magnetism are summarized in a set of four equations known as Maxwell's equations, which first appeared in his Treatise on Electricity and Magnetism in 1873 and were later cast in their modern form by other physicists.
In 1865 Maxwell resigned his position in London and returned to his family estate Glenair in Scotland, where he continued his scientific work for five years. In 1870, however, a new chair and laboratory of physics were established at Cambridge University, and Maxwell eventually accepted an offer after two other physicists had refused. Maxwell continued his work in electricity and magnetism, organized the new laboratory, and edited the papers of Henry Cavendish for whom the laboratory was named. Early in 1879 Maxwell's health began to decline, and he died several months later during his forty-ninth year.
see also Boltzmann, Ludwig; Cavendish, Henry; Faraday, Michael; Magnetism; Physical Chemistry.
Richard E. Rice
Cropper, William H. (2001). "The Scientist as Magician: James Clerk Maxwell." In Great Physicists: The Life and Times of Leading Physicists from Galileo to Hawking. New York: Oxford University Press.
Haley, Christopher. "James Clerk Maxwell (1831–1879) Mathematical Physicist." Available from <http://22.214.171.124/science/maxwell1.html>.
O'Connor, J. J., and Robertson, E. F. "James Clerk Maxwell." Available from <http://www-gap.dcs.st-and.ac.uk/~history/Mathematicians/Maxwell.html>.
O'Connor, J. J., and Robertson, E. F. "A Visit to James Clerk Maxwell's House." Available from <http://www-gap.dcs.st-and.ac.uk/~history/HistTopics/Maxwell_House.html>.
James Clerk Maxwell
James Clerk Maxwell
James Clerk Maxwell developed the mathematical theory of electricity and magnetism, and introduced statistical methods to the kinetic theory of gases and thermodynamics. Arguably the nineteenth-century scientist who exerted the greatest influence on twentieth-century science, his work had widespread significance in a variety of fields, including the development of relativity and quantum mechanics. The importance of Maxwell's work is ranked with that of Isaac Newton (1642-1727) and Albert Einstein (1879-1955).
Maxwell was born into a family whose original surname was Clerk; his father added the name Maxwell when he inherited the Maxwell estate. Maxwell's mother, who was 40 years old when he was born, died of abdominal cancer when he was eight. He was initially tutored at home, then attended Edinburgh Academy where he published his first scientific paper at age 14.
Maxwell entered the University of Edinburgh at age 16 and moved on to Cambridge at age 19. He subsequently became one of the most influential members of the group of nineteenth-century scientists, now known as the Cambridge School, who provided leadership in the application of mathematics, especially calculus, to physical problems.
In 1856 Maxwell became professor of natural philosophy at Marischal College in Aberdeen, Scotland, and in 1860 was appointed professor of natural philosophy at King's College in London. Between 1860-65 he wrote two papers that introduced his mathematical treatment of the field theory of electricity and magnetism. He also had a continuing interest in vision, color, color blindness, and geometric optics, and in 1861 showed the feasibility of color photography by demonstrating that photographs of the same subject, successively taken through filters of the three primary colors, could be combined to produce a colored image of the subject.
Among the most important contributions that resulted from Maxwell's application of mathematical methods to a variety of physical phenomena was the introduction of statistical methods to thermodynamics. In his treatment of the thermodynamics of gaseous systems he assumed that the amount of kinetic energy possessed by individual molecules is distributed statistically about an average energy that is related to the temperature of the system. This became the basis of a general statistical kinetic theory of gases and the statistical interpretation of thermodynamics.
Maxwell became a member of the Royal Society in 1860. In 1865, at age 34, he retired to the family estate to concentrate on his scientific work. The principal result was the full development of his field theory of electromagnetism, recognized as one of history's greatest shifts in scientific thinking. He published his results as A Treatise on Electricity and Magnetism in 1873. This theory treats electricity and magnetism as aspects of a single force—electromagnetism. Maxwell demonstrated that this force could be regarded as extending out through space as a field that did not require the presence of matter for its propagation. He showed that the rate of movement of this force through space is equal to the speed of light and, furthermore, that visible light itself is electromagnetic in nature and is a part of a broad range of electromagnetic radiation. The field and wave nature of his electro-magnetic equations introduced an approach that would later be fundamental in the development of Einstein's special theory of relativity and the wave equations of quantum mechanics.
In 1871 Maxwell returned to Cambridge to become the first Cavendish Professor at that university. He died of colon cancer in 1879 at age 48, the same terminal age and disease as his mother.
J. WILLIAM MONCRIEF
CHARLES LYELL AND THE RETURN OF THE DINOSAURS
Charles Lyell, the father of modern geology, is widely accepted as the person who made geology into a predictive science. He did this by pointing out that "the present is the key to the past"; in other words that we can make inferences about the past because the same processes are taking place today and can be observed and measured. However, in one case, he appears to have taken a slightly too literal approach to Uniformitarianism because he felt that, at some time in the future, dinosaurs would return to replace man on Earth.
Lyell firmly believed in a strong Uniformitarianism—that geological change on Earth is the result of long-acting, relatively uniform processes. From this perspective the absence of dinosaurs from the world had to be explained, because this was something that had obviously changed. He resolved this dilemma by positing that Earth followed a cyclical form of history, not unlike the seasons, and that the classes of animals changed throughout the "great year." Mammals dominated the colder "seasons" of this great year, but when the calendar turned to summer again, "Then might those genera of animals return, of which the memorials are preserved in the ancient rocks of our continents. The huge iguanodon might reappear in the woods and the ichthyosaur in the sea, while the pterodactyle might flit again through umbrageous groves of tree-ferns."
This passage occasioned no end of ridicule among Lyell's contemporaries, even inspiring one of his colleagues, de la Beche, to draw a mocking cartoon showing "Professor Ichyosaur" lecturing a class about the skull of an extinct human.
Maxwell, James Clerk