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Karl Wilhelm Scheele

Karl Wilhelm Scheele

The Swedish pharmacist and chemist Karl Wilhelm Scheele (1742-1786) discovered chlorine and oxygen and isolated and characterized a variety of organic acids.

Karl Wilhelm Scheele was born on Dec. 9, 1742, at Stralsund in Swedish Pomerania. His formal education ended at age 14, when he was apprenticed to a pharmacist in Gothenburg. In this shop Scheele's scientific education began. Here was at hand a treasury of chemical materials and apparatus which excited the curiosity and latent talents of the young apprentice. In addition, he had access to his master's library, which included many of the most noteworthy chemical works of the 18th century.

Following 8 years' apprenticeship in Gothenburg, Scheele moved to Malmö as an apothecary clerk. Again he was fortunate in his master, who allowed him facilities and time for research. In Malmö, Scheele's talents received their first recognition in the person of Anders Johan Retzius, who was later to become professor of chemistry and natural history at the University of Lund. Retzius encouraged Scheele to keep a systematic record of his researches and brought his name to public attention in a paper on tartaric acid published in 1770 in the memoirs of the Royal Swedish Academy of Sciences.

Spurred by Retzius's encouragement, Scheele decided to seek employment closer to the intellectual and scientific centers of Sweden. From 1768 to 1770 he was an apothecary clerk in Stockholm and from 1770 to 1775 held a similar position in a pharmacy in Uppsala. He earned a leading position among the savants and university professors who formed the very notable elite of Swedish science at this time.

Chemical Researches

The bulk of Scheele's scientific work was published between 1770 and 1786 in the memoirs of the Swedish Academy of Sciences. He was also the author of one book, the famous Chemical Treatise on Air and Fire (1777). His researches cover such a broad range of topics that one can pinpoint only the highlights.

In the realm of inorganic chemistry Scheele's first important discoveries were made in 1774 in connection with a study of pyrolusite (manganese dioxide). He also discovered a new earth (baryta, or barium oxide) associated with pyrolusite. But the most important outcome of his researches on pyrolusite was his discovery of chlorine. This he prepared by heating a solution of pyrolusite in acid of salt (hydrochloric acid). He collected the greenish-yellow gas in a bladder and studied its highly reactive properties and noted its bleaching action. He thought this gas was acid of salt deprived of its phlogiston, and hence he called it dephlogisticated acid of salt.

In the realm of organic chemistry Scheele is noted for his isolation of a large number of organic acids derived from a variety of vegetables, fruits, and other sources. These included citric acid (from lemons), oxalic acid (from sorrel and rhubarb), malic acid (from apples and other fruits), gallic acid (from nut galls), lactic acid (from milk), and uric acid (from urine). These were among the first organic substances obtained in a chemically pure and well-identified form. Scheele has thus good claim to be considered the founder of modern organic chemistry.

Scheele's greatest claim to fame, however, rests on his discovery of oxygen. He performed his experiments on oxygen sometime between 1770 and 1773, but they were not published until 1777 in his Chemical Treatise on Air and Fire, by which time Joseph Priestley had published his independent discovery of the gas (1775). In this book Scheele first proved that common air was composed of two components: "spoiled," or "foul," air and "fire" air (oxygen). The latter was named fire air because only it will support combustion and it is therefore necessary for the production of fire. He prepared this fire air by heating a mixture of nitric and sulfuric acid in a retort and collecting the gas in a bladder attached to the neck. He also prepared the fire air by heating mercuric oxide (Priestley's method) and mixtures of manganese dioxide and sulfuric and phosphoric acids.

Later Career

In 1775 Scheele was admitted to the Royal Swedish Academy of Sciences—perhaps the only apothecary's assistant to be so honored. This same year he also achieved his lifelong ambition: his own pharmacy in the small town of Köping. Although the time he could devote to his scientific research was reduced, he continued to work in a makeshift wooden laboratory behind the shop, and he produced some of the researches described above. By 1782 he had prospered sufficiently to build himself a new house and laboratory. He did not enjoy this newfound prosperity for long, however, for he died on May 26, 1786.

Further Reading

A selection of Scheele's works is The Collected Papers of Carl Wilhelm Scheele, translated by Leonard Dobbin (1931). See also J. Murray, The Chemical Essays of Karl Wilhelm Scheele (1901). Uno Boklund, distinguished Swedish historian of chemistry, is currently preparing a definitive biography together with editions of all Scheele's works. A very readable account of his life is in Sir Edward Thorpe, Essays in Historical Chemistry (1894). A well-illustrated account is in Georg Urdang, Pictorial Life History of the Apothecary Chemist Carl Wilhelm Scheele (1942). □

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Scheele, Karl Wilhelm

Karl Wilhelm Scheele (kärl vĬl´hĕlm shā´lə), 1742–86, Swedish chemist, b. Stralsund. He is known as the discoverer of many chemical substances. He was a pharmacist in Stockholm, in Uppsala (1770–75), and then in Köping. He prepared and studied oxygen c.1773, but his account in Chemical Observations and Experiments on Air and Fire (1777, tr. 1780) appeared after the publication of Joseph Priestley's studies. He discovered nitrogen independently of Daniel Rutherford and showed it to be a constituent of air. His treatise on manganese (1774) was influential in leading to the discovery of that element as well as to the discovery of barium and chlorine. He also isolated glycerin and many acids, including tartaric, lactic, uric, prussic, citric, and gallic.

See his Collected Papers (tr. 1931, repr. 1971).

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Karl Wilhelm Scheele

Karl Wilhelm Scheele

1742-1786

Swedish chemist who made many contributions to chemistry, including the discovery of oxygen. He probably prepared oxygen, which he called "fire-air," as early as 1772, two years before Joseph Priestley. Scheele, however, published little and his work was not as well known. Scheele's book Chemical Observations and Experiments on Air and Fire (1777) presented evidence that the atmosphere is composed of two gases, one of which prevented combustion and another that supported combustion. Other substances discovered by Scheele include tartaric acid, arsenic acid, lactic acid, citric acid, oxalic acid, tungstic acid, and hydrocyanic acid.

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Karl Wilhelm Scheele

Karl Wilhelm Scheele

1742-1786

Swedish Chemist and Druggist

Swedish-born chemist whose record as a discoverer of new elements, compounds, and chemical reactions has long remained unequaled.

Karl Wilhelm Scheele was born in Stralsund, Germany (formerly the capital of Swedish Pomerania.) Scheele's interest in chemistry began during his experience as an apprentice to an apothecary in the town of Goteborg. He had no formal education. His teacher, Swedish chemist Torbern Bergman (1735-1784), obtained a small pension for Scheele from the Stockholm Academy of Science, which the young apprentice in turn used to fund his chemical experiments. Scheele spent most of life in poverty, serving as an apprentice in Malmö and Stockholm before settling in as a pharmacist in the small town of Koping. He preferred remaining an apothecary to becoming a university professor.

His lack of career advancement, however, in no way parallels his scientific achievements. While in Koping, Scheele discovered more new substances than any scientist of his time, and perhaps ever since. In 1773 he proposed that air was composed of two gases, oxygen and nitrogen. Scheele prepared oxygen from various oxides but is rarely credited with the discovery. While his research anticipated English chemist Joseph Priestley's (1733-1804) discovery of oxygen, Scheele's only book Chemical Observations and Experiments on Air and Fire did not appear until 1777, after Priestley announced his results. There is little doubt, however, that he obtained the gas about 1772, two years before Priestley. Both Scheele and Priestly, however, failed to recognize the significance of their findings and today Antoine-Laurent Lavoisier (1743-1794) takes credit for the discovery.

Scheele published his first scientific paper in 1770, documenting his isolation of tartaric acid from cream of tartar. The free acid is widely used in carbonated drinks, effervescent tablets, and some gelatin products.

The young chemist discovered an extraordinary number of elements: chlorine, barium, molybdenum, tungsten, and manganese. He was the first to isolate chlorine and show that it could bleach cloth. Manufacturers in England and France put his research to commercial use.

While Scheele is credited with identifying chlorine and barium, he believed they were compounds, not elements. In the early 1800s, British chemist Sir Humphry Davy (1778-1829) correctly identified chlorine as an element.

In 1776 Scheele discovered uric acid while analyzing a kidney stone. In the last years of his life, he proved it was lactic acid that made milk sour. He was also the first to prepare the chemical compounds arsine and hydrogen sulfide. In 1783 he discovered the poisonous hydrocyanic acid, without realizing its toxic character.

Among his other discoveries were glycerine, copper arsenite (also referred to as the pigment Scheele's green), and the toxic gases hydrogen sulfide and hydrogen fluoride. Scheele also helped open doors to the modern world of photography by illustrating that sunlight removed salts from silver chloride, leaving only the metal behind.

Scheele died in 1786 at the age of 43. In 1931 the Collected Papers of Carl Wilhelm Scheele was published.

KELLI MILLER

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