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Praseodymium (revised)

PRASEODYMIUM (REVISED)

Note: This article, originally published in 1998, was updated in 2006 for the eBook edition.

Overview

During the late 1830s and early 1840s, Swedish chemist Carl Gustav Mosander (1797-1858) was studying two puzzling minerals, ceria and yttria. Both minerals had been discovered more than fifty years earlier in remote parts of Sweden. The minerals were puzzling because they seemed to consist of a mixture of new elements. Mosander eventually showed that one of the elements in ceria produced pink compounds. He called the new element didymium.

A few years after didymium was discovered, Austrian chemist Carl Auer (Baron von Welsbach) (1858-1929) made a correction to Mosander's research. Didymium was not a pure element, Auer announced, but a combination of two other new elements. He called these elements meodymium and praseodymium.

SYMBOL
Pr

ATOMIC NUMBER
59

ATOMIC MASS
140.9077

FAMILY
Lanthanide
(rare earth metal)

PRONUNCIATION
PRAY-zee-oh-DIM-ee-um

Praseodymium lies in Row 6 of the periodic table. The periodic table is a chart that shows how chemical elements are related to each other. The elements that make up Row 6 are sometimes called the rare earth metals. But the term is not very accurate. The rare earth elements are not especially rare in the Earth's crust. They were given this name because they have very similar properties. This similarity makes them difficult to separate from each other. A better name for the rare earth elements is the lanthanides. This name comes from the first element in Row 6, lanthanum.

Praseodymium is a typical metal, somewhat similar to aluminum, iron, or magnesium. It is quite expensive to prepare and does not have many practical uses.

Discovery and naming

Mosander had been educated as a physician and a pharmacist. In the early 1830s, he was put in charge of the minerals collection at the Stockholm Academy of Sciences. He became very interested in two minerals that had been discovered in Sweden many years before, yttria and cerite. He devoted many years to studying the composition of these two minerals.

In 1841, Mosander announced that he had obtained two new elements from cerite. He called these elements lanthanum and didymium. He was correct about lanthanum being a new element, but he was wrong about didymium. This new "element" turned out to be a mixture of two other new elements, now called neodymium and praseodymium.

The man who made this discovery was Auer. He selected these two names because they mean "new twin" (neodymium) and "green twin" (praseodymium). The elements were called "twins" because they were both so much like lanthanum.

The praseodymium prepared by Auer was not very pure. It was contaminated with other elements. The first really pure sample of praseodymium was not made until 1931.

Physical properties

Praseodymium is a soft, malleable, ductile metal with a yellowish, metallic shine. Malleable means capable of being hammered into a thin sheet. Ductile means capable of being made into thin wires. Praseodymium has a melting point of 930°C (1,710°F) and a boiling point of about 3,200°C (about 5,800°F). Its density is 6.78 to 6.81 grams per cubic centimeter. Two allotropes of praseodymium exist. Allotropes are forms of an element with different physical and chemical properties. One allotrope, the "alpha" form, changes into a second allotrope, the "beta" form, at about 800°C.

Chemical properties

When it becomes moist, praseodymium reacts with oxygen in air to form praseodymium oxide. Praseodymium oxide (Pr2O3) forms as a greenish-yellow scale (like rust) on the surface of the metal. To protect praseodymium for this reaction, it is stored under mineral oil or covered with a plastic wrap.

Like many other metals, praseodymium also reacts with water and with acids. In these reactions, hydrogen gas is released.

Occurrence in nature

Praseodymium is one of the more common lanthanides. It is thought to occur with an abundance of about 3.5 to 5.5 parts per million in the Earth's crust. It occurs primarily with the other rare earth elements in two minerals, monazite and bastnasite.

Isotopes

Only one naturally occurring isotope of praseodymium is known. Isotopes are two or more forms of an element. Isotopes differ from each other according to their mass number. The number written to the right of the element's name is the mass number. The mass number represents the number of protons plus neutrons in the nucleus of an atom of the element. The number of protons determines the element, but the number of neutrons in the atom of any one element can vary. Each variation is an isotope.

At least 15 radioactive isotopes of praseodymium are known also. A radioactive isotope is one that breaks apart and gives off some form of radiation. Radioactive isotopes are produced when very small particles are fired at atoms. These particles stick in the atoms and make them radioactive. None of the radioactive isotopes has any commercial use.

The original "discovery" of a "new" element called didymium turned out to be a mixture of neodymium and praseodymium.

Extraction

The first step in obtaining praseodymium is to treat monazite, bastnasite, or another ore to separate the lanthanides from each other. The various elements are then changed to compounds of fluorine, such as praseodymium fluoride (PrF3). Praseodymium metal can then be obtained by passing an electric current through praseodymium fluoride:

or by making it react with an active metal:

It is still quite expensive to make praseodymium, and the metal sells for about $1,200 a kilogram ($2,500 a pound).

Uses

One of the oldest uses for praseodymium is in the manufacture of misch metal. Misch metal is pyrophoric, meaning that the metal gives off sparks when it is scratched. The most common use of misch metal is in lighter flints and tracer bullets. When a metal wheel is rubbed across misch metal in a cigarette lighter, the metal gives off sparks. Those sparks then set fire to lighter fluid, giving a flame to light a cigarette.

Like other lanthanides, praseodymium is also used to give color to glass, ceramics, enamels, and other materials. The characteristic color provided by compounds of praseodymium is a bright yellow.

A related use of praseodymium is in carbon arc lamps, like those used in the motion picture industry. When an electric current is passed through a carbon arc, the arc gives off a brilliant white light. The addition of a small amount of praseodymium gives a brilliant yellow cast to the light.

Praseodymium is also a component of didymium glass. Didymium glass contains a mixture of rare earth elements, including lanthanum, praseodymium, neodymium, samarium, cerium, and gadolinium. This glass is used to make welder's goggles. It helps protect the welder's eyes from the intense light produced during welding.

Compounds

Relatively few compounds of praseodymium have any commercial uses.

Praseodymium is used to give a bright yellow color to glass, ceramics, and enamels.

Health effects

The health effects of praseodymium are not well studied. As a safety measure, chemists treat the metal as if it were toxic and handle it with caution.

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Praseodymium

Praseodymium


melting point: 935°C
boiling point: 3,017°C
density: 6.475 g/cm3
most common ions: Pr3+ , Pr4+

In 1885 C. A. von Welsbach isolated two elements as oxides, praseodymium (the word meaning "green twin") and neodymium (meaning "new twin"), from a mixture of lanthanide oxides called didymia. The oxides can be transformed to fluorides by reaction with HF at 700°C (1,292°F), or with NH4HF2 at 300°C (572°F). The hydrated fluorides are then dehydrated in vacuo in a current of HF gas. The metals praseodymium and neodymium are obtained via metallothermic reduction with calcium at approximately 1,450°C (2,642°F), or via electrolytic reduction of the melts. The metals can also be obtained from anhydrous chlorides, obtained via reaction of the oxides with ammonium chloride at 350°C (662°F), which are then reduced with lithium-magnesium at approximately 100°C (212°F).

Praseodymium halides (except the fluoride), nitrate, and acetate are soluble. The hydroxide, carbonate, oxalate phosphate, and oxide compounds are insoluble. Praseodymium's solutions and most of its solids are green.

When oxo-compounds of Pr(III) are ignited in the atmosphere, a black oxide of composition Pr6O11 (approximately) is obtained. Fluorocomplexes of Pr(IV) that have the compositions Na2PrF6, Na7Pr6F31, and PrF4 have been obtained.

Pr(III) salts and complexes are weakly luminescent. The salts are used to color some special glasses and as pigments in ceramics. The compound Zr1x Prx SiO4 is used often as a yellow pigment in the ceramic industry; it is very stable in color and resistant to high temperatures. Pr(III), in Pr2S3, is an excellent pigment for plastics and paints. Other uses of praseodymium include tires (Pr-doped ZrSiO4), photographic filters (Pr2O3), and welding masks (Pr-Nd).

see also Lanthanides.

Lea B. Zinner

Geraldo Vicentini

Bibliography

Maestro, P. (1998). "From Properties to Industrial Applications." In Rare Earths, ed. R. S. Puche and P. Caro. Madrid: Editorial Complutense.

Moeller, Therald (1973). "The Chemistry of the Lanthanides." In Comprehensive Inorganic Chemistry, ed. J. C. Bailar, Jr.; H. J. Emeléus; Sir Ronald Nyholm; and A.F. Trotman-Dickenson. Oxford, UK: Pergamon Press.

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praseodymium

praseodymium (prā´zēōdĬm´ēəm, –sēō–) [Gr., =green twin], metallic chemical element; symbol Pr; at. no. 59; at. wt. 140.90765; m.p. 931°C; b.p. 3,512°C; sp. gr. about 6.8; valence +3 or +4. Praseodymium is a soft, malleable, ductile, silver-yellow metal. It exhibits allotropy; the α-form (hexagonal crystalline structure) has the density given above, but the β-form (above 800°C, body-centered cubic crystalline structure) is less dense. Praseodymium is a rare-earth metal of the lanthanide series in Group 3 of the periodic table. When exposed to air it forms a green oxide that does not protect it from further oxidation. Although the pure metal may be prepared by reduction of the chloride, it has few commercial uses. A major use of the metal is in a pyrophoric alloy used in cigarette lighter flints, but it need not be purified for this application. Praseodymium compounds have many uses. The oxide is used in carbon electrodes for arc lighting. The salts are used to color enamels and glass. Didymium glass used in glassblower's goggles contains praseodymium; this glass absorbs the yellow sodium glare of light from the torch flame. The major commercial source of praseodymium is the rare-earth minerals monazite and bastnasite. Praseodymium was discovered in 1885 by C. A. Von Welsbach, who separated Mosander's "didymium" into two components, the earths neodymia and praseodymia.

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praseodymium

praseodymium (symbol Pr) Silver-yellow metallic element of the lanthanide series (rare-earth metals). First isolated by Austrian chemist Carl von Welsbach (1858–1929) in 1885, its chief ores are monazite and bastnasite. Soft, malleable and ductile, praseodymium is used in carbon electrodes for arc lamps, and its green salts are used in coloured glasses, ceramics, and enamels. Properties: at.no.59; r.a.m. 140.9077; r.d. 6.77; m.p. 931°C (1708°F); b.p. 3512°C (6354°F); only one isotope Pr141 (100%).

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