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rare-earth metals

rare-earth metals, in chemistry, group of metals including those of the lanthanide series and actinide series and usually yttrium, sometimes scandium and thorium, and rarely zirconium. Promethium, which is not found in nature, is not usually considered a rare-earth metal. The metals usually occur together in minerals as their oxides (rare earths) and are somewhat difficult to separate because of their chemical similarity. A subgroup of the rare-earth metals, consisting of those with atomic numbers between 57 and 63 and ytterbium, is often called the cerium metals. Misch metal is an alloy of the cerium metals often used in lighter flints, in alloys with other metals (especially magnesium), and to remove residual gases in the manufacture of vacuum tubes. Individual metals may be isolated as their compounds by ion exchange methods, solvent extraction, or fractional crystallization, and chemically or electrolytically reduced to the pure metal. Uses are discussed in articles on individual elements.

See F. H. Spedding and A. H. Daane, ed., The Rare Earths (1961, repr. 1971); E. C. Subbarao and W. E. Wallace, ed., Science and Technology of Rare Earth Metals (1980).

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rare earths

rare earths, in chemistry, oxides of the rare-earth metals. They were once thought to be elements themselves. They are widely distributed in the earth's crust and are fairly abundant, although they were once thought to be very scarce. Generally, the name of an earth is formed from the name of its element by replacing -um with -a; e.g., the earth of cerium is ceria. Mixed rare earths are used in glassmaking, ceramic glazes, glass-polishing abrasives, carbon arc-light electrode cores, and catalysts for petroleum refining. Individual purified rare earths have many uses, e.g., in laser, fiber-optic transmission amplifiers, and night-vision goggles. Important rare-earth minerals include bastnasite, cerite, euxenite, gadolinite, monazite, and samarskite.

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rare-earth element

rare-earth element (REE, lanthanide) One of those elements with atomic numbers between 57 and 71, that have closely similar chemical properties. The ionic radius decreases with increasing atomic number, a phenomenon referred to as the lanthanide contraction. Rare-earth elements occur in minerals only in trace amounts, sometimes replacing Ca2+ in apatite and hornblende. They tend to become concentrated in the residual fluid of magmas, and in some pegmatites the REE cerium replaces the calcium in epidote to form the mineral allanite. Lunar rocks, apart from anorthosite, show considerable enrichment in most of the rare-earth elements relative to the REE cosmic abundance. See EUROPIUM ANOMALY.

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rare earth

rare earth (also rare earth el·e·ment or rare earth met·al) • n. Chem. any of a group of chemically similar metallic elements comprising the lanthanide series and (usually) scandium and yttrium. They are not esp. rare, but they tend to occur together in nature and are difficult to separate from one another.

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"rare earth." The Oxford Pocket Dictionary of Current English. . Encyclopedia.com. 28 Jun. 2017 <http://www.encyclopedia.com>.

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rare earth

rare earth See lanthanide series

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"rare earth." World Encyclopedia. . Encyclopedia.com. 28 Jun. 2017 <http://www.encyclopedia.com>.

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