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Faraday, Michael

Faraday, Michael

(b. Newington, Surrey [now part of Southwark, London], England, 22 September 1791; d. Hampton Court, Middlesex, England, 25 August 1867)

chemistry, physics.

Early Life and Education. Michael Faraday was born into a poor family, of which he was the third of four children. His father, James, was a blacksmith who had left his own smithy in Outhgill, near Kirkby Stephen, early in 1791 to seek work in London. His increasing ill health prevented him from providing more than the bare necessities for his family. Faraday later recalled that he was once given a loaf of bread, which was to feed him for a week. James Faraday died in 1809. Michael’s mother, the former Margaret Hastwell, was the mainstay of the family. She made do with what she had for material needs, but clearly offered her younger son that emotional security which gave him the strength in later life to reject all social and political distinctions as irrelevant to his own sense of dignity. She died in 1838.

There are no sources for Faraday’s early years, so it is impossible to say what effects they had on him; we can only infer them from his adult life. His contemporaries uniformly described him as kind, gentle, proud, and simple in both manner and attitude. He loved children, although he had none of his own, and never lost his enthusiasm for natural beauty, especially such grandiose spectacles as a thunderstorm or an alpine waterfall. Such traits, when taken in conjunction with his solicitude for the success of his older brother, Robert, as a gas fitter and for the education of his younger sister, Margaret, bespeak a close-knit family, enjoying simple pleasures but raised in all propriety by stern but loving parents.

The one early influence of which there can be no doubt was that of religion. Faraday’s parents were members of the Sandemanian Church, and Faraday was brought up within its discipline. The Sandemanian religion is a peculiar offshoot of Protestant Christianity. It is fundamentalist in the sense that Sandemanians believe in the literal truth of Scripture, but its emphasis is not on the fire and brimstone of most fundamentalist sects. Rather, it stresses that love and sense of community which marked the primitive Christian Church. It was this love and sense of community which were to sustain Faraday throughout his life. His friend and close associate at the Royal Institution, John Tyndall, a self-styled agnostic, wrote in some puzzlement in his journal for Sunday, 24 October 1852:“I think that a good deal of Faraday’s week-day strength and persistency might be referred to his Sunday Exercises. He drinks from a fount on Sunday which refreshes his soul for a week” (Royal Institution,“Tyndall’s Journals,” MS, V, 163).

Faraday drew more than strength from his religion. It gave him both a sense of the necessary unity of the universe derived from the unity and benevolence of its Creator and a profound sense of the fallibility of man. Both are worth stressing. The origins of field theory are to be found in Faraday’s detailed experimental researches on electricity, but the speculations and imaginings which led him to the experiments and the courage which permitted him to publish physical heresies owe something to his unquestioning belief in the unity and interconnections of all phenomena. This belief, in turn, derived from his faith in God as both creator and sustainer of the universe. The fallibility of man was clearly described in the Book of Job, and this was the book in Faraday’s Bible which he had marked the most with marginal emphases. Faraday never engaged in scientific polemics. He presented his results to his peers, having done his best to assure that his experiments were accurate and his reasoning sound. If he were wrong, better experiments and sounder reasoning would prevail and his beloved science would progress. He considered himself to be merely an instrument by which truth was revealed. To insist upon his infallibility would border on blasphemy. He was content to publish his results and let posterity judge how close he had come to being right.

These qualities of Faraday became apparent only when he was in the full tide of fame. In his youth, it seemed unlikely that he would ever have the opportunity to exercise them, at least in the pursuit and presentation of scientific truths. His formal education was almost nil, consisting of the rudiments of reading, writing, and ciphering. When he was thirteen years old, Faraday helped contribute to the family earnings by delivering newspapers for a Mr. G. Riebau of 2 Blandford Street. Riebau was an émigré from France who had fled the political maelstrom of the French Revolution. He not only let out newspapers but also sold and bound books. When Faraday turned fourteen, he was apprenticed to Riebau to learn the art of bookbinding. It was in the seven years of his apprenticeship that Faraday developed the extraordinary manual dexterity that was to distinguish his later experimental researches. The proximity of books stocked for sale and brought in to be rebound stimulated his mind. He became an omnivorous reader, absorbing fact and fancy in equal amounts. The result was a severe case of intellectual indigestion as Faraday became the repository of hosts of unconnected statistics and ideas.

His condition was relieved by the discovery of an elementary treatise, The Improvement of the Mind, written by an eighteenth-century clergyman, Isaac Watts. This treatise, as Riebau reported, was “frequent took in his Pocket,” and Faraday followed each of Watts’s suggestions for self-improvement. He began to keep a commonplace book, in which he could record ideas and interesting observations; he attended lectures and took notes; he began a correspondence with a young man, Benjamin Abbott, with the express hope of improving himself; he later helped found a discussion group devoted to the exchange of ideas. All these things Watts strongly recommended. But Watts went further than providing mechanical aids to learning; he also presented a philosophy which appeared to protect its adherents from false theories and intellectual delusions. Accurate observation of facts and precision in language would prevent a philosopher from premature generalization, which had led many an unwary student astray. This advice, together with his deep sense of human fallibility, reinforced the caution with which Faraday later approached natural philosophy. He never embarked upon an explanation without first testing for himself the facts that needed explanation. Mere reading of the results of others never satisfied him. Some of his most brilliant investigations owed their origin to a casual observation of an anomaly when Faraday checked his facts. And it was not until every fact had been checked and rechecked that Faraday would generalize. Watts had a very attentive pupil.

Faraday’s passion for science was first aroused by a chance reading of the article “Electricity” in a copy of the Encyclopaedia Britannica which he was rebinding. His curiosity was piqued, and he set out to check what facts he could by means of a small electrostatic generator which he constructed out of some old bottles and waste lumber. The article had been written by one James Tytler, who espoused a somewhat idiosyncratic view of the nature of electricity. For Tytler, all electrical effects could be explained by assuming the existence of a peculiar fluid whose various modes of motion would account for optical and thermal, as well as electrical, phenomena. Electricity was likened by Tytler to a vibration, rather than a flow of material particles through space, and this view permitted him to suggest answers to such thorny questions as why conductors conduct electricity and insulators do not. In the course of his article, Tytler also took the opportunity to demolish the two-fluid theory of electricity then current on the Continent and the Franklinian one-fluid theory popular in Great Britain.

One should be wary of drawing too far-reaching consequences from any single influence, but there are a number of aspects of Tytler’s article and its possible effects on Faraday that deserve mention. Tytler was, first of all, a scientific heretic presenting a view that had few supporters. As such, he was both belligerent and challenging, and undoubtedly stirred Faraday to exercise his own judgment more than if the subject had been presented calmly, without controversy, as Truth. Tytler’s defensive posture also forced him to attack the more orthodox theories and underline their very real weaknesses. If nothing else, these criticisms must have made Faraday skeptical of the accepted theories and forced him to keep an open mind on controversial points. When he later challenged both the one-fluid and the two-fluid theories, he was able to do so in precisely those areas where Tytler had first sown doubts. His challenge to orthodox electrical theories in 1838 was couched in Tytlerian terms. Current electricity, for Faraday as for Tytler, was a vibration, not a material flow. How much Faraday owed to Tytler is impossible to assess, but the influence was strong enough to lead Faraday to refer to Tytler’s article a number of times in the laboratory diary that he kept from 1820 on.

With the reading of Tytler’s article, Faraday began the pursuit of science in earnest. In the London of the early nineteenth century, however, it was difficult for an apprentice bookbinder to find many sources of scientific enlightenment. He could and did attend public lectures, but there were no night schools, no correspondence courses, no public libraries from which he could gain scientific enlightenment. He was, therefore, doubly fortunate to fall in with a group of young men with a common passion for science. They had come together as the City Philosophical Society in 1808 and were led by John Tatum, at whose house they met every Wednesday night. Tatum would deliver a lecture on a scientific subject and then throw open his library to the members of the society.

Faraday was introduced into this company in February 1810, when he attended his first lecture. At the City Philosophical Society, he received a basic education in the sciences, attending and taking careful notes on lectures on electricity, galvanism, hydrostatics, optics, geology, theoretical mechanics, experimental mechanics, chemistry, aerology (pneumatic chemistry), astronomy, and meteorology. These lectures should not be overestimated, for they were often mere catalogs of facts (mineralogy is an example) but, when possible, Tatum illustrated them with experiments and introduced his avid listeners to interesting pieces of scientific apparatus. It was at the City Philosophical Society, for example, that Faraday first saw a voltaic pile in operation.

Faraday’s interest was increasingly focused on science. It was this interest that led him to the discovery of a work which he lauded throughout his life, Jane Marcet’s Conversations on Chemistry. Mrs. Marcet’s treatment of chemistry differed considerably from other contemporary, more technical accounts. She had written it for those people, like herself, who had been entranced by the lectures of Humphry Davy at the Royal Institution of Great Britain. Davy approached chemistry as if it were the key to the ultimate mysteries of nature, and Mrs. Marcet did likewise. Here was no dry catalog of chemical facts, or recipes, but a grand scheme which tied together chemical reactions, electrical relations, and thermal and optical phenomena. The impact on Faraday was considerable. The simplicity of his views on electricity was forever destroyed, his thoughts were directed specifically to chemistry, and, most important of all, he was introduced to the thoughts of Humphry Davy, who became, for him, the example of what he would like to be.

Faraday and Humphry Davy. There was, seemingly, little chance that Michael Faraday, bookbinder’s apprentice, would ever become anything other than Michael Faraday, bookbinder. But one of Riebau’s customers offered him tickets to Davy’s lectures at the Royal Institution. He went, took careful notes, and copied them out in a clear hand. Each scientific point made by Davy was grasped eagerly and recounted to his friends at the City Philosophical Society. But this was mere playing at science, and it was with a heavy heart that Faraday, in October 1812, accepted the end of his apprenticeship and prepared to devote himself to bookbinding instead of his beloved chemistry. An accident changed his life and the life of science. In late October, while examining chloride of nitrogen, a very unstable substance, Davy was temporarily blinded by an explosion. Faraday was recommended to Davy as an amanuensis, and Davy was pleased to have him. In December, Faraday sent Davy the carefully bound notes he had taken at Davy’s lectures. Davy was flattered but could do nothing at that time to help his young admirer. In February 1813, however, an assistant in the laboratory of the Royal Institution was fired for brawling. Davy immediately sent for Faraday and on 1 March 1813, Faraday took up his new position at the Royal Institution.

Davy exerted the most important influence on Faraday’s intellectual development. Davy’s mind was both penetrating and wide-ranging. He seems to have been an omnivorous reader interested in metaphysics as well as chemistry, poetry as well as physics. His science was characterized by brilliant flashes of insight soundly supported by experimental evidence. Although he never committed himself to a specific theoretical or metaphysical viewpoint, he was aware of and often used those that offered clues to the nature of matter and its forces. In the early nineteenth century, there were a number of points of view which could provide the chemist with guidelines worth following. There was, first of all, an English tradition in chemistry which could be traced back to the patron saint of English science, Sir Isaac Newton. It took Newton’s work on force and raised it to the level of a universal science. The classic example in the eighteenth century is Gowin Knight’s An Attempt to Demonstrate That All the Phenomena in Nature May Be Explained by Two Simple Active Principles, Attraction and Repulsion (1748), whose message can be seen from the title. There seems little reason to doubt that both Faraday and Davy had read Knight’s work. It was a part of the English scientific tradition and, more important, was easily available in the library of the Royal Institution.

But Knight’s work was relatively crude. Although he reduced matter to the forces of attraction and repulsion, he separated the two, hypothesizing one kind of matter with attractive force only and another consisting solely of repulsive force. The association of these two forms of matter gave rise to the phenomena of the sensible world. A more subtle solution to the problem of complexity and of the nature of matter was provided by the Jesuit Rudjer Bošković in his Philosophiae naturalis theoria redacta ad unicam legem virium in natura existentium, which first appeared in 1758. Like Knight, Bošković dismissed the reality of matter and substituted forces but, unlike Knight, was able to combine the forces of attraction and repulsion in one “atom.” In Figure 1, the pattern of forces of a Boscovichean atom is represented graphically. The point at O is a mathematical point which serves merely as the center of the forces of which the atom consists. Beyond H, the atomic force is attractive, decreasing inversely as the square of the distance, thus satisfying the Newtonian principle of universal attraction. From H to A, the force varies, according to the distance from O, in a continuous fashion from attractive to repulsive and back to attractive. The number of such variations can be multiplied at will to account for phenomena. From A to O, the force becomes increasingly repulsive, reaching infinite repulsion at O and thereby preserving impenetrability as a characteristic of “matter.” These pointatoms were likened by Bošković to the points that make up the lines of the letters of the alphabet. A combination of the pointatoms gave the chemical elements, just as a combination of points made up the letters. Combinations of elements yielded the chemical compounds, and so on. Ultimately, then, all “matter” is one; observable complexities were the result of successive levels of complexity of particulate arrangements.

This system was particularly appealing to chemists

of philosophical disposition. It reconciled simplicity and complexity, providing a fundamental order in place of the taxonomic confusion engendered by the myriad chemical compounds and the ever-growing number of chemical elements. It also offered some insight into such specifically chemical problems as elective affinity by referring to the patterns of forces which could interact to create stable compounds. Davy remarked in his last years that he had found Bošković’s theory of some importance in the development of his ideas and, in 1844, Faraday publicly declared his preference for Boscovichean atoms over those suggested by Dalton. Just how important Bošković’s theory was for Faraday is currently a matter of scholarly dispute. I shall here insist that it was fundamental, but the reader is warned that my discussion of Faraday’ use of it is controversial.

Knight and Bošković provided the justification for the unity of matter in which both Faraday and Davy believed. They did not, however, provide the concept of the unity of force. Both Knight and Bošsković’, after having composed their primary matter(s) from attractive and repulsive forces, gave material explanations for such phenomena as light and electricity. It may, of course, be argued that since all phenomena are ultimately the results of attractive and repulsive forces, then all phenomena are convertible into one another. But no such argument was ever made, to my knowledge, by those within the English tradition or by those who were partial to Bošsković. Yet Faraday wrote in 1845: “I have long believed in the unity of force,” and his work from 1831 on was devoted to the conversion of one force into another. Whence came this conviction of the unity and convertibility of forces? Again, what follows is controversial, but it seems to make sense of what otherwise appears inexplicable and is, therefore, worth putting forward, albeit with considerable caution.

The doctrine of the unity and convertibility of forces is the product of German philosophy at the end of the eighteenth century. It was first suggested by Immanuel Kant in his Metaphysische Anfangsgrunde der Naturwissenschaft (1786) and then developed by F. J. Schelling— the Naturphilosophen, among whom may be counted Hans Christian Oersted, the discoverer of the first force conversion (electromagnetism)—used this idea as the basic guiding thread in their researches. What is extremely difficult is to connect this movement in Germany and Scandinavia to Davy and Faraday. The one possible link, since neither Davy nor Faraday read German and translations were unavailable, is the poet and metaphysician Samuel Taylor Coleridge. He visited Germany in 1798–1799 and came back to England with his head overflowing with Naturphilosophie. He and Davy were close friends in the early 1800’ and it seems likely, indeed inevitable, given Coleridge’s enthusiasm and love of conversation, that he and Davy discussed Naturphilosophie in some detail. The unity and convertibility of forces was the kind of idea Davy always liked to keep in the back of his mind without committing himself to it. It might suggest some experiments and was, therefore, a potentially useful way of looking at the world. If he passed it on to Faraday, it fell on eager ears, for there can be no doubt of Faraday’s commitment to it. The difference in their reaction may have lain in their different attitudes toward religion rather than toward science. Both men were religious, but Faraday was by far the more intense in his religious feelings and more determined in his devotion. One of the reasons Coleridge had been so enthusiastic in his acceptance of Naturphilo-sophie was that it appeared to contradict materialism and offer a place to spirit in the world. Faraday may have felt the same. Certainly the unity and convertibility of force offered a more appealing view of God’s creation than the chaotic interplay of material atoms in which most scientists believed.

If we accept this admittedly hypothetical reconstruction, we can suggest the course of Faraday’s development under Davy’s tutelage. The unity and convertibility of force would first appeal to the apprentice chemist, for it bound the universe together in an aesthetically and theologically satisfying way. From here, it was a short step to the acceptance of, or at least the willingness to think in terms of, Boscovichean atoms. The English tradition of dynamic atomism made such a step intellectually respectable, for this tradition had based its insistence on the ultimate reality of force on sound empirical arguments which Faraday was to repeat in 1844 and 1846. It is within this intellectual and philosophic framework that his work should be viewed.

There was ample opportunity for Davy and Faraday to discuss these fundamental aspects of the nature and structure of physical reality. Soon after Faraday’s employment at the Royal Institution, Davy decided to visit the Continent, and he asked Faraday to accompany him and Lady Davy. The party set out on 13 October 1813 and during 1813 and 1814 visited France and Italy, where Faraday met many of the leading scientists of the day. During this tour, Davy discoursed on every scientific subject under the sun, and Faraday eagerly drank it all in. Faraday became fully conscious, during this period, of the philosophical complexities underlying the apparent simplicity of chemical science and even more aware of the dangers of both methodological and metaphysical complacency.

Journeyman Chemist. Upon his return to London in April 1815, Faraday threw himself into chemistry with the enthusiasm that marked his whole scientific life. He assiduously searched all the scientific journals available to him, keeping a detailed bibliographical record of everything he read and carefully noting everything of interest to him. In 1816 he published his first paper, “Analysis of Caustic Lime of Tuscany,” which was followed by a series of short (and inconsequential) articles on subjects suggested to him by the researches of Davy and William T. Brande, Davy’s successor as professor of chemistry at the Royal Institution. By 1820 Faraday had established a modest but solid reputation as an analytical chemist, so much so that he was involved in court cases requiring expert testimony. One such case involved the question of the ignition point of heated oil vapor. This, together with his brother’s involvement in the new gas lighting of London, led Faraday to investigate the general properties of the various oils used for heating and lighting. From these researches came the discovery of benzene in 1825.

But Faraday’s mind ranged far wider than the composition of lime or illuminating gas. One of his earliest chemical enthusiasms had been Davy’s work on chlorine, in which Davy had exploded Lavoisier’s theory of acids by showing that not all acids contain oxygen, as the name of that element implied. Hydrochloric acid consisted solely of hydrogen and chlorine. Davy’s demonstration that chlorine supported combustion also destroyed the unique place among the elements allotted to oxygen as the sole supporter of combustion, and thereby tended to weaken Lavoisier’s magistral chemical synthesis. But this demonstration raised an important problem, and it was to this problem that Faraday turned. If chlorine were a supporter of combustion, as the almost explosive nature of the combination of iron with chlorine clearly demonstrated, then why did chlorine not combine with carbon, the combustible substance par excellence? All attempts at “burning” carbon in chlorine were unsuccessful, but Faraday was convinced that compounds of chlorine and carbon must exist. In 1820 he produced the first known compounds of chlorine and carbon, C2Cl6and C2Cl4. These compounds had been produced by the substitution of chlorine for hydrogen in “olefiant gas,” our modern ethylene. This was the first substitution reaction; such reactions, in the hands of Charles Gerhardt and Augustin Laurent in the 1840’s, were to be used as a serious challenge to the dualistic electrochemical theories of J. J. Berzelius.

Beyond his work in analytical and pure chemistry, Faraday showed himself to be a pioneer in the application of chemistry to problems of technology. In 1818, together with James Stodart, a cutler, he began a series of experiments on the alloys of steel. Although he was able to produce alloys of superior quality, they were not capable of commercial production because they required the use of such rare metals as platinum, rhodium, and silver. Nevertheless, Faraday demonstrated that the increasingly urgent problem of producing higher-grade steels could be attacked by science. The later work on steel of Henry Sorby, Henry Bessemer, and Robert A. Hadfield was based directly on Faraday’s work in the early part of the century.

In 1824 Faraday was asked by the Royal Society to conduct experiments on optical glass. Again his researches were inconclusive, but he paved the way for later improvements in glass manufacture. It was in these experiments that he produced a glass containing borosilicate of lead and with a very high refractive index. This was the glass he used in 1845 when he discovered the rotation of the plane of polarization of a light ray in an intense magnetic field.

The 1820’s were busy years for Faraday beyond his chemical researches. In 1821 he married Sarah Barnard, the sister of one of the friends he had made at the City Philosophical Society. Their marriage was an extremely happy one and sustained Faraday throughout the extraordinary mental exertions of the next forty years. Sarah Barnard was not an intellectual. Once, when she was asked why she did not study chemistry, she replied, “Already it is so absorbing, and exciting to him that it often deprives him of his sleep and I am quite content to be the pillow of his mind.” Faraday needed no one to whom to talk about his research. His dialogue was with nature. “I do not think I could work in company, or think aloud, or explain my thoughts...,” he remarked near the end of his life. He founded no school and left no disciple who had been formed in his laboratory.

In the 1820’s the precarious financial position of the Royal Institution also demanded Faraday’s attention. He helped support the institution by performing chemical analyses, and he contributed to its fiscal stability by instituting the Friday evening discourses in 1825. He gave more than a hundred of these lectures before his retirement in 1862. They served to educate the English upper class in science, and part of the growing support for science in Victorian England may legitimately be attributed to the efforts of Faraday and his fellow lecturers to popularize science among those with influence in government and the educational establishment.

Early Researches on Electricity. During these busy years, Faraday was forced to push his love for electricity into the background. Yet it was never far from his thoughts, as the events of 1821 and 1831 reveal. In 1821 a series of brilliant researches culminated in the discovery of electromagnetic rotation; in 1831, seemingly out of nowhere, came the discovery of electromagnetic induction and the beginning of the experimental researches in electricity which were to lead Faraday to the discovery of the laws of electrochemistry, specific inductive capacity, the Faraday effect, and the foundations of classical field theory. These researches, in both 1821 and 1831, are all of a piece; and it would be well here to make explicit what I think is the theoretical thread that holds them together.

By 1821 we know that Faraday was aware of and even toying with the concept of Boscovichean pointatoms. This is not to say that Faraday was a disciple of Bošsković, for he certainly did not follow the Boscovichean system in his work. But the notion of atoms as centers of force had a strong appeal for him, and it is this notion that, I should like to suggest, provided the conceptual framework for his work on electricity. In particular, there were two specific consequences of the theory of pointatoms which were to be fundamental to Faraday’s discoveries. The first was the emphasis upon complex patterns of force that followed logically from the consideration of the interaction of numbers of Boscovichean particles. It should be remembered that Boscovichean atoms were not the atoms of early nineteenth-century chemistry. Rather, the chemical elements were agglomerates of Boscovichean atoms whose specific chemical properties were the direct result of the patterns of force produced by the intimate association of point-atoms. When Faraday thought of material particles, therefore, he did not envision them as submicroscopic billiard balls with which certain rather simple forces were associated, but rather as centers of a complex web of forces.

Put another way, the orthodox scientist of the 1820’s tended to think in terms of central forces emanating from particles, and central forces always act in straight lines between particles. Faraday’s vision was far more intricate, and it permitted him to contemplate forces in manifold ways. An example may be useful here. Oersted’s discovery of a circular magnetic “force” around a current-carrying wire was explained by André-Marie Ampère as the resultant of central forces emanating from current elements in the wire. To Faraday, the circular “force” was simple and could be used to explain the apparent polarity (or central forces) of magnetic poles. No one but Faraday could or did take a circular “force” seriously, but this was the germ of the idea of the Line of force which was to be central to the development of Faraday’s theories.

The second consequence involved a subtle shift in point of view away from the orthodox physics of the day. Boscovichean atoms, as force, were infinite in extent because the forces associated with atoms extended to infinity. Thus all material associations on the molecular level were really interpenetrations of fields of force, if I may be excused the anachronism. All particles, then, were associated with one another; the only differences were in the degrees of approximation of molecular or atomic centers of force. A displacement of a particle, anywhere in the universe, ought to affect every other particle. The same conclusion, of course, may be drawn from orthodox action-at-a-distance physics, but it is neither obvious nor obtrusive. In the theory of point-atoms it is both.

Furthermore, it suggests a mode of action which Faraday seized upon in his researches on the nature of electricity. Orthodox theory assumed the existence of one or two “imponderable” electrical fluids with whose particles specific electrical forces were associated. Electrical energy was transferred from place to place by the translation of these particles. The interlocking of force particles permitted energy to be transferred without the permanent displacement of the particles by means of the vibration of the particles. If a line of particles could be put under a strain, this line could then transmit energy either by the rapid breakdown and buildup of the strain or by vibrating transversally to the direction along which the strain was exerted. The first kind of “vibration” was that suggested by Faraday in 1838 to explain spark discharge, electrochemical decomposition, and ordinary electrical conduction. The second sort of vibration was tentatively put forward by Faraday in 1846 in his “Thoughts on Ray Vibrations” to account for the transmission of light through a vacuum without having recourse to a vibrating medium such as the luminiferous ether.

All this was far in the future in 1821, when Faraday was persuaded to take up the subject of electromagnetism by his friend Richard Phillips, an editor of Philosophical Magazine. Ever since Hans Christian Oersted’s announcement of the discovery of electromagnetism in the summer of 1820, editors of scientific journals had been inundated with articles on the phenomenon. Theories to explain it had multiplied, and the net effect was confusion. Were all the effects reported real? Did the theories fit the facts? It was to answer these questions that Phillips turned to Faraday and asked him to review the experiments and theories of the past months and separate truth from fiction, groundless speculation from legitimate hypothesis. Faraday agreed to undertake a short historical survey but he did so reluctantly, since his attention was focused on problems of chemistry rather remote from electromagnetism.

His enthusiasm was aroused in September 1821, when he turned to the investigation of the peculiar nature of the magnetic force created by an electrical current. Oersted had spoken of the “electrical conflict” surrounding the wire and had noted that “this conflict performs circles,” but this imprecise description had had little impact upon Faraday. Yet as he experimented he saw precisely what was happening. Using a small magnetic needle to map the pattern of magnetic force, he noted that one of the poles of the needle turned in a circle as it was carried around the wire. He immediately realized that a single magnetic pole would rotate unceasingly around a current-carrying wire so long as the current flowed. He then set about devising an instrument to illustrate this effect. (See Figure 2.) His paper “On Some New Electro-Magnetical Motions, and on the Theory of Magnetism” appeared in the 21 October 1821 issue of the Quarterly Journal of Science. It records the first conversion of electrical into mechanical energy. It also contained the first notion of the line of force. Faraday, it must be remembered, was a mathematical illiterate. His experiments revealed a circular “line” of magnetic force around a current-carrying wire and he found no difficulty in accepting this as a simple fact. To his mathematically trained contemporaries, such a force could not be simple but must be resolved into central forces. This is what Ampere had done so ingeniously in his early papers on electromagnetism. Ampère;’s sophisticated mathematical reasoning could have no

effect on Faraday and he refused to move from what he considered the bedrock of experiment. Stubbornness, however, is no virtue in science and he was forced to face the problem of deriving central forces from his circular force in order to explain the “simple” attractions and repulsions of magnetic poles. His solution was both simple and elegant. If a straight current-carrying wire were bent into a loop, then the circular lines of magnetic force would be arranged in such a way as to concentrate them within the loop and the magnetic “polarity” of the loop would reflect this concentration. That there were no “poles” or termini of the magnetic force, Faraday showed by another simple demonstration. He wound a glass tube with insulated wire and then placed it half-submerged in water. A long magnetic needle was affixed to a cork so that it could float freely on the water. When a current was passed through the wire surrounding the glass tube, “poles” were formed at opposite ends of the tube and the north pole of the needle was attracted to the south pole of the helix. If an ordinary magnet had been used, the needle would have approached the electromagnet and clung to it, giving the illusion that the south pole attracted the north pole.

But in Faraday’s setup the result was surprising. The needle moved toward the helix, entered the glass tube and continued through it until the north pole of the needle was situated at the north pole of the helix. The result was as Faraday had expected; it was merely another example of his electromagnetic rotations. A single magnetic “pole” would continue to move around and through the helix and never come to rest. The line of force along which it moved was the resultant of the circular magnetic forces surrounding the wires of the helix and did not emanate in straight lines from the “poles” of the magnet.

Thus Faraday’s work on electromagnetic rotations led him to take a view of electromagnetism different from that of most of his contemporaries. Where they focused on the electrical fluids and the peculiar forces engendered by their motion (Ampère’s position), he was forced to consider the line of force. He did not know what it was in 1821, but he suspected that it was a state of strain in the molecules of the currentcarrying wire and the surrounding medium produced by the passage of an electrical “current” (whatever that was) through the wire. Such a state of strain, he knew, was transmitted some distance from the source of the strain, the current-carrying wire. Might it not be legitimate to speculate that if the strain could be intensified and concentrated, it might induce a similar state in a neighboring wire?

In the years between 1821 and 1831, Faraday returned sporadically to this question. He attempted to detect the strain by passing plane polarized light through an electrolyte through which a current was passing; he queried the best form of magnet to produce the maximum strain, concluding that it might be “a very thick ring”; he attempted to induce an electrical current by means of static electricity; but all to no avail. Yet in these years his ideas gradually developed and clarified. The wave theory of light revealed how strains could transmit energy; the work of his friend Charles Wheatstone on sound, particularly on Chladni figures, which Faraday illustrated to audiences at the Royal Institution, showed how vibrations could produce symmetrical arrangements of particles; the discovery of “magnetism by rotation” by François Arago in 1825 (Arago’s wheel) revealed to him the insufficiency of Ampere’s electrodynamic theory.

In 1831 Faraday learned of Joseph Henry’s experiments in Albany, New York, with powerful electromagnets in which the polarity could be reversed almost instantaneously by a simple reversal of “current” direction. The stage was set. An electromagnet, in the shape of a thick iron ring, wound on one side with insulated wire should set up the powerful strain; the strain should be conducted through the particles of the ring, which would then be thrown into a peculiar arrangement, much as the particles of dust were affected on a neighboring iron plate when one close by was set into vibration by a violin bow; the resultant arrangement would distort the intermolecular forces by which the iron molecules of the ring cohered, and this strain should then be detected by a secondary winding on the other side of the iron ring. On 29 August 1831, Faraday tried the experiment. When the primary circuit was closed, the galvanometer in the secondary circuit moved. An electrical “current” had been induced by another “current” through the medium of an iron ring. This discovery is always called the discovery of electromagnetic induction, but it should be noted that it is no such thing.

It was not until some weeks later that Faraday discovered the conditions under which a permanent magnet could generate a current of electricity (17 October 1831). It was at this date that he could declare that he had demonstrated the reverse of Oersted’s effect, namely, the conversion of magnetic force into electrical force. Further investigation led him to the invention of the first dynamo, whereby the reverse of his 1821 discovery of electromagnetic rotations could be accomplished. Mechanical force could be converted into electrical force by a simple machine. A copper disk, rotated between the poles of a magnet, produced a steady electrical current in a circuit running

from the center of the disk through a wire to the edge of the disk. (See Figure 3.)

The concept of the line of force now moved to the very center of Faraday’s thought, where it was to remain for the rest of his life. It was the line of force which tied all his researches on electricity and magnetism together. It was therefore with some embarrassment that he confessed, in his second series of Experimental Researches in Electricity, that he did not know what the line of force was. In the first series, he had described it as a strain imposed upon the molecules of the conducting wire and the surrounding medium by the passage of the electric “current.“This state of strain he christened “the electrotonic state,” but it defied every attempt at detection. His abandonment of the electrotonic state in the second series was only temporary, for without it Faraday was deprived of his basic concept. The electrotonic state had to exist, for there could be no doubt of the reality of the line of force. It was his attempts to relate the two which led him onward through the brilliant series of researches which culminated in his general theory of electricity in 1838.

Electrochemistry. The first and second series of Experimental Researches had been concerned with the relations between electricity and magnetism. In the summer of 1832 Faraday appeared to go off on a tangent, with an investigation into the identity of the electricities produced by the various means then known. His commitment to the unity of force led him to believe that the electricities produced by electrostatic generators, voltaic cells, thermocouples, dynamos, and electric fishes were identical, but belief was no substitute for proof. Furthermore, this identity had been challenged by Sir Humphry Davy’s brother John, who insisted that electrical effects were not produced by a single agent but were the complex results of a combination of powers. There was little sense in continuing to work on electricity until this question was settled. It seemed like a routine investigation involving mere manipulative skill to demonstrate that electricity, no matter how produced, had the same effects. But in the course of this investigation Faraday was to be led to the laws of electrolysis and, more important, to challenge the concept of action at a distance.

Faraday’s attack was straightforward. Searching the literature, he found reports of the similar effects of the various forms of electricity. The only real difficulties arose with static electricity. There were published reports that electrostatic discharges had both magnetic and electrochemical effects but, upon repeating the experiments, Faraday found them equivocal. Electrostatic discharge, for example, could magnetize needles, but Faraday found it impossible to produce a magnet in an electrostatic field. Similarly, William Hyde Wollaston had reported the decomposition of water by an underwater spark in 1801, but it was possible to view this decomposition as the result of the mechanical shock, the heat generated by the discharge, or both. To remove all possible doubts, Faraday turned his experimental skill to the examination of these two effects.

The magnetic effect of an electrostatic discharge was examined by means of a simple galvanometer. The discharge was “slowed down” by passing it through wet string. The galvanometer was deflected, thus settling the question once and for all. Here Faraday might have stopped, but he saw the opportunity to compare static and voltaic electricity quantitatively and was quick to seize it. An electrometer gave him a relative reading of static charge; the deflection of the galvanometer permitted him to correlate the charge with the discharge. Fortunately (and unbeknown to Faraday), his galvanometer here acted like a ballistic galvanometer, and he was able to conclude that “if the same absolute quantity of electricity pass through the galvanometer, whatever may be its intensity, the deflecting force upon the magnetic needle is the same.” Faraday immediately proceeded to devise an apparatus by which he could compare, quantitatively, the currents produced by electrostatic and voltaic discharge. Insofar as electricity affected a galvanometer needle, then, Faraday had given conclusive proof of the identity of static and voltaic electricity. He had, furthermore, devised an instrument for the measurement of relative quantities of electricity.

The remaining problem was that of electrochemical decomposition by electrostatic discharge. Once again, the desired effect was produced without the ambiguity of Wollaston’s experiment. Faraday might have rested here, since the identity of electricities was what he had set out to prove, but the opportunity for further discoveries was clear and he set out to exploit it. The course was obvious. Both electrostatic and current electricity decomposed water; the “throw” of the galvanometer permitted the accurate measure of electrical quantity. Could not the quantity of electricity be correlated with the products of electrochemical decomposition? In answering this question, Faraday enunciated his two laws of electrochemistry: (1) Chemical action or decomposing power is exactly proportional to the quantity of electricity which passes in solution; (2) The amounts of different substances deposited or dissolved by the same quantity of electricity are proportional to their chemical equivalent weights. Thus, Faraday had not only proved the identity of electricities; he had added another link in the chain of the convertibility of forces. Electricity was not only involved in chemical affinity, as the invention of the voltaic cell had shown, but it was the force of chemical affinity. In 1881 Hermann von Helmholtz was to use Faraday’s 1834 papers on electrochemistry as the experimental basis for his suggestion that electricity must be particulate, or Faraday’s laws of electrochemistry would make no sense.

In the course of his electrochemical researches, Faraday made a discovery with revolutionary implications. As he varied the conditions under which electrostatic discharge produced electrochemical decomposition, he found to his surprise that no “poles” were required. Ever since the invention of the voltaic cell, electrochemists had assumed that the + and - terminals of the circuit acted as centers of force, which force, acting at a distance upon the molecules in solution, literally tore them apart. Hence the term “poles.” But when Faraday passed an electrostatic discharge through some blotting paper soaked with a solution of potassium iodide into the air, the potassium iodide decomposed. Where, now, were the centers of force of orthodox theory? More important, what was “acting at a distance” upon the potassium iodide molecules? The mere passage of the “current” was sufficient to decompose the potassium iodide. The experiment with electrostatic discharge suggested to Faraday that decomposition was not effected by action at a distance.

In a series of ingenious experiments, Faraday went on to show that the molecules were not “torn apart” at all. Instead, the two components of a binary salt seemed to migrate in opposite directions through the solution, without ever becoming free chemical agents, until they reached the terminals upon which they were deposited. Faraday accounted for this strange behavior by claiming that the electric “current” exalted the affinities of the components of a salt on opposite sides of the compound molecules, thus permitting each component to leave its original partner and join with another close by. The electrical force determined the direction of this recombination, one component moving toward the “positive” terminal, the other toward the “negative.” The “exaltation” was passed along from one molecule to the next, beginning from the terminals and moving out into the solution. There was no action at a distance, but only intermolecular forces created by the strain imposed by the electrical force. It is difficult to visualize this process without having recourse to point-atoms and the patterns of force which produced their chemical identity.

Such patterns of force could be distorted by the imposition of other forces, and this appears to be what Faraday meant by his use of the term “exaltation.” Under the strain of electrical force, the affinities of the molecular components were both “exalted” and aligned, permitting their transfer through the solution. As in an American square dance “grand right and left,” where each partner passes around the square by taking the hands of people passing in the opposite direction, the chemical elements in solution passed through the solution, ever bound to a partner, until they were freed at the termini. The process involved three steps: the creation of the initial strain by the imposition of the electrical force; the exaltation of the affinities along the direction of the electrical force, which exaltation caused the component atoms of the decomposing substances to shift in opposite directions and to be bound by partners moving the other way; and the “shift” in which the strain was momentarily relieved, only to be reimposed immediately by the constant application of the electric force at the termini. The electric force was transmitted by this rapid series of buildups and breakdowns of strain, and electrical energy could be transmitted in this fashion without the transfer of a material agent. It was even possible to deduce the second law of electrochemistry from this scheme. Each shift required the breaking of a chemical bond of specific strength, so it was to be expected that the total force employed (quantity of electricity) should bear some specific and simple relation to the total quantity of matter decomposed by this force.

In his published accounts, Faraday only hinted at what has been presented here as his theory of electrochemical decomposition. The conceptual framework was too conjectural for Faraday to present it to his co-workers in electrochemistry. But what he could and did do was to publish his factual results and also prepare the way for a successful challenge to the prevalent theory by introducing a new nomenclature which was theoretically neutral. Instead of poles, which implied centers of force, Faraday used the term “electrode,” which had no such implication. Similarly “cathode,” “anode,” “electrolysis,” “electrolyte,” “anion,” and “cation” were merely descriptive terms. William Whewell of Trinity College, Cambridge, was the source of most of these neologisms.

Faraday’s Theory of Electricity. Faraday’s electrochemical researches suggested to him a new perspective on electrostatics. If electrochemical forces did not act at a distance, was it preposterous to think that electrostatic forces also were intermolecular? The researches of Charles Coulomb in the 1780’s had appeared to settle that question once and for all in favor of action at a distance, but Faraday drew courage from his electrochemical work and sought to find experimental confirmation for his new point of view. Two consequences flowed logically from the substitution of intermolecular forces for action at a distance. First, the electrostatic force ought to vary if it depended upon the ability of the molecules of a medium to transmit it and, second, this force ought to be transmitted in curved lines, since the transmitting molecules occupied a volume of space, rather than in the straight lines assumed by action-at-a-distance physics. Experimental confirmation of both these conclusions was quick in coming. The inductive force did vary when different substances were used to transmit it. The discovery of specific inductive capacity was an important structural element in the construction of Faraday’s novel electrical theory. The inductive force did vary when different substances were used to transmit it. The discovery of specific inductive capacity was an important structural element in the construction of Faraday’s novel electrical theory. The inductive force was also shown to be transmitted in curved, not straight, lines, thus confirming once again Faraday’s belief in intermolecular forces.

By 1838 Faraday was in a position to put all the pieces together into a coherent theory of electricity. The particles of matter were composed of forces arranged in complex patterns which gave them their individuality. These patterns could be distorted by placing the particles under strain. Electrical force set up such a strain. In electrostatics, the strain was imposed on molecules capable of sustaining large forces; when the line of particulate strain gave way, it did so with the snap of the electric spark. Lightning was the result of the same process on a larger scale. In electrochemistry, the force of the “breaking” strain was that of the chemical affinities of the elements of the chemical compound undergoing electrochemical decomposition. The shift of the particles of the elements toward the two electrodes momentarily relaxed the strain, but it was immediately re-created by the constant application of electric force at the electrodes upon the nearest particles of the electrolyte. This buildup and breakdown of interparticulate strain, passing through the electrolyte, constituted the electrical “current.” It was a transfer of energy which did not entail a transfer of matter; Faraday’s caution in adopting the term “current” appeared justified. The same situation obtained in ordinary conduction through a wire. The molecules of good conductors could not sustain much of a strain at all, so here the buildup and breakdown of the strain was exceptionally rapid and the “conduction” was therefore correspondingly good.

The theory was elegant, firmly based on experiment, and complete. It was also heretical, challenging almost all the fundamental concepts of orthodox electrical science. Faraday knew this and put it forward with appropriate caution. The experimental results were clearly and firmly reported; the theoretical aspect was hedged with fuzzy and tentative language, hesitantly and sometimes confusedly presented. It is, I think, fair to say that no one in the 1830’s took the theory seriously. Even Faraday was unable to advocate it with the necessary vigor. The strain of eight years of unremitting intellectual effort at the farthest frontier of electrical theory ultimately broke his powerful mind. In 1839 he suffered a nervous breakdown, from which he never really recovered. For five years he was unable to concentrate his mental faculties on the problems of electricity and magnetism. He passed this time by devoting himself to the affairs of the Royal Institution and such other researches as did not require his total intellectual commitment. It was in these years, for example, that he extended his earlier work on the condensation of gases. He was able here to use his experimental talents to the full without being forced to focus his mind on the consequences.

Even during these years, Faraday kept returning to his electrical theory. In 1844 he published a small paper entitled “Speculation Touching Electrical Conduction and the Nature of Matter,” in which he “proved” to his own satisfaction that only Boscovichean atoms were compatible with the observed conduction and nonconduction of electricity through material bodies. Again, it seems unlikely that Faraday convinced anyone, but this exercise did serve to stimulate him to return to his old preoccupation with the nature of electricity and magnetism. In 1846 he was led, in his “Thoughts on Ray Vibrations,” to an embryonic form of the electromagnetic theory of light, later developed by James Clerk Maxwell. In both these essays Faraday was, as it were, conducting a dialogue with himself, attempting to clarify his own ideas and to grasp the full implications of his own speculative hypotheses. These works therefore are of importance more because they reveal Faraday’s mind to us than because they are important steps in the progress of electrical and magnetic science.

Last Researches: The Origins of Field Theory. The last, and in many ways the most brilliant, of Faraday’s series of researches was stimulated by the quite specific comments of one of the few people who thought his theory of electricity worthy of serious attention. On 6 August 1845, William Thomson, the future Lord Kelvin, addressed a lengthy letter to Faraday, describing his success with the mathematical treatment of the concept of the line of force. At the end of the letter Thomson listed some experiments to test the results of his reasonings on Faraday’s theory, and it was this that pushed Faraday once more into active scientific research. One of Thomson’s suggestions was that Faraday test the effect of electrical action through a dielectric on plane-polarized light. As Thomson wrote:

It is known that a very well defined action, analogous to that of a transparent crystal, is produced upon polarized light when transmitted through glass in any ordinary state of violent constraint. If the constraint, which may be elevated to be on the point of breaking the glass, be produced by electricity, it seems probable that a similar action might be observed.

The effect predicted by Thomson was one which Faraday had been seeking to detect since the 1820’s but with no success. Thomson’s belief that it should exist reinforced Faraday’s and he returned to the laboratory to find it. As in the 1820’s his search was fruitless, but this time, instead of abandoning his search, he altered the question he put to nature. His own work in the 1830’s had illustrated the convertibility of electrical and magnetic force. The failure to detect an effect of electrical force of polarized light might only reflect the fact that electrical force produced a very small effect which he could not detect. The force of an electromagnet was far stronger and might, therefore, be substituted in order to make the expected effect manifest.

On 13 September 1845 his efforts finally bore fruit. The plane of polarization of a ray of plane-polarized light was rotated when the ray was passed through a glass rhomboid of high refractive index in a strong magnetic field. The angle of rotation was directly proportional to the strength of the magnetic force and, for Faraday, this indicated the direct effect of magnetism upon light. “That which is magnetic in the forces of matter” he wrote “has been affected, and in turn has affected that which is truly magnetic in the force of light” The fact that the magnetic force acted through the mediation of the glass suggested to Faraday that magnetic force could not be confined to iron, nickel, and cobalt but must be present in all matter. No body should be indifferent to a magnet, and this was confirmed by experiment. Not all bodies reacted in the same way to the magnetic force. Some, like iron, aligned themselves along the lines of magnetic force and were drawn into the more intense parts of the magnetic field. Others, like bismuth, set themselves across the lines of force and moved toward the less intense areas of magnetic force. The first group Faraday christened “paramagnetic” the second, “diamagnetic.”

The discovery of diamagnetism stimulated the production of theories to account for this new phenomenon. Ever since the work of Coulomb in the 1780’s most physicists had assumed (with Coulomb) the existence of polar molecules to account for magnetism. The simple thing to do, when faced with the apparent repulsion of diamagnetic substances by magnetic poles, was simply to assume some kind of “reverse” polarity leading to repulsion rather than attraction. Since such explanations necessarily involved the existence of magnetic or electrical “fluids,” Faraday was skeptical. Furthermore, Faraday’s attention was increasingly focused on the line of force, rather than on the particles of matter affected by the line of force. In his experiment on the rotation of the plane of polarization of a light ray, Faraday had noted that the “polarity” involved was in the line of magnetic force, not in the interposed glass. Experiments with diamagnetics further convinced him that there were no poles in diamagnetics but only reactions to the line of magnetic force.

He therefore rejected the polar theories of his contemporaries and substituted one of his own. Paramagnetics were substances that conducted the magnetic force well, thereby concentrating lines of force through them; diamagnetic substances were poor conductors of magnetism, thus diverging the lines of magnetic force passing through them. (See Figure 4.) A glance at the patterns of the lines of force was sufficient to disprove the polar theory: the lower figure is not the opposite of the top one. There are, in fact, no poles in diamagnetics. The top figure also indicates that there are no “poleas” in Paramagnetics either, if poles be defined as the termini of the magnetic force. As Faraday went on to show, the lines of magnetic force, unlike their electrostatic cousins, are continuous curves having no termini. They cannot be accounted for in terms of force-atoms under strain, and Faraday ignored his earlier model of interparticulate strain for the transmission of magnetic force.

Instead, he spoke of a “flood of power” marked out by the lines of force or compared a magnet to a galvanic circuit in which the magnet was the source of power; but the surrounding medium played the part of the connecting wires to transmit the magnetic “current”. A magnet was described as the “habitation of lines of force”.

Such explanations were manifestly unsatisfactory, for they provided no mechanism whatsoever for magnetic phenomena. They expressed metaphorically what Faraday felt the phenomena to be, but they gave little insight into their underlying causes. Only one point emerged clearly, and this point was of fundamental importance. Whatever the cause of magnetism, the manifestation of magnetic force took place in the medium surrounding the magnet. This manifestation was the magnetic field and the energy of the magnetic system was in the field, not in the magnet. By extension, the same could be said (and was so said by Faraday) of electrical and gravitational systems. This is the fundamental axiom of classic field theory.

By the mid-1850’s Faraday had gone as far as he could go. He had provided a new perspective for those who would look on all manifestations of force in the phenomenal world. His description of this perspective was fuzzy and imprecise but capable of clarification and precision if taken up by someone who could share Faraday’s vision. Such a man was James Clerk Maxwell, who, in the 1850’s and 1860’s built field theory on the foundations Faraday had laid.

Faraday was unable to appreciate what his young disciple was doing. His mind deteriorated rapidly after the mid-1850’s, and even if he had been able to understand Maxwell’s mathematics, it is doubtful that he would have been able to follow Maxwell’s chain of reasoning. As his mental faculties declined, Faraday gracefully retreated from the world. He resigned from all social clubs in the 1850’s concentrating what remained of his energies on his teaching functions at the Royal Institution. His Christmas lectures for a juvenile audience for 1859–1860, on the various forces of matter, and for 1860–1861, on the chemical history of a candle, were edited by William Crookes and have become classics. But even his lecturing abilities began to fade, and he was forced to abandon the lectern in 1861. In 1862 he resigned his position at the Royal Institution, retiring to a house provided for him by Queen Victoria at Hampton Court. On 25 August 1867 he died.

BIBLIOGRAPHY

I. Original Works. Faraday collected his papers in four vols.: Experimental Researches in Electricity, 3 vols. (London, 1839–1855), and Experimental Researches in Chemistry and Physics (London, 1859). The course of his thought may be followed in Thomas Martin, ed., Faraday’s Diary, Being the Various Philosophical Notes of Experimental Investigation Made by Michael Faraday, 7 vols. and index (London, 1932–1936). For a complete list of Faraday’s lectures and writings, see Alan Jeffreys, Michael Faraday, A List of His Lectures and Published Writings (London, 1960). Henry Bence Jones was Faraday’s close friend and, after his death, collected a large number of letters to and from Faraday, which, together with excerpts from diaries, etc., were published as Life and Letters of Faraday, 2 vols. (London, 1870). This volume must be used with great caution, since the editor was not averse to correcting and amending Faraday’s language. See also The Selected Correspondence of Michael Faraday, L. Pearce Williams, ed., 2 vols. (Cambridge, 1971). There are important MS collections at the Royal Institution of Great Britain, the Royal Society of London, the Institution of Electrical Engineers, London, and the Wellcome Medical Historical Library.

II. Secondary Literature. The most recent and detailed biography is L. Pearce Williams, Michael Faraday, A Biography (London-New York, 1965). A complete list of books on Faraday is to be found in the bibliography compiled by M. Lukomskaya as an appendix to the Russian trans. of Faraday’s Experimental Researches in Electricity(Moscow, 1951). John Tyndall, Faraday as a Discoverer (London, 1869, and many subsequent eds.) reveals what Faraday’s orthodox friends thought of his physical heresies. Silvanus P. Thompson, Michael Faraday. His Life and Work (London, 1898) depicts Faraday as seen by a famous electrical engineer to whom Faraday’s electrical discoveries far outweighed his work on field theory.

There are portraits of Faraday in the Royal Institution of Great Britain and the National Portrait Gallery.

L. Pearce Williams

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Faraday, Michael

FARADAY, MICHAEL

(b. Newington Butts, Surrey [now London], England, 22 September 1791, d. Hampton Green Court, Middlesex, England, 25 August 1867),

electricity and magnetism, chemistry.

For the original article on Faraday see DSB, vol. 4.

Faraday’s contributions to electricity and magnetism shaped nineteenth-century physics fundamentally, opened the possibility of a wider use of electric power, and laid the origin of field theory. Both for his contemporaries and for modern science studies, his experimental approach and unorthodox concepts have been challenging. At his time, his fame rested as much on his lecturing and counseling in public service as on his research.

Since the 1980s, Faraday studies have shifted their focus from Faraday’s ideas, experimental discoveries, and intellectual influences toward the practice of his life, research, and religion. As a result, a new picture has emerged, and it has become clear that the degree to which Faraday’s research was preshaped by philosophical ideas about the nature of matter and force had been considerably overestimated. This update article focuses on how his generation of knowledge—experimental, practical, conceptual, theoretical—was connected to, and shaped by, the other aspects of his life.

Working in the Royal Institution. Faraday’s lifelong working site, the Royal Institution of Great Britain, had been founded in 1799 as a philanthropic initiative for improving the scientific education of craftsmen and practitioners, but quickly developed into a meeting point for the middle and upper class. Its finances depended largely on the income of the public lectures it offered, and hence on finding lecturers that attracted a substantial audience. In that respect, Faraday was as great a success as Humphry Davy had been before him. The Friday evening and the Christmas juvenile lecture series (founded in 1826 and 1827,respectively) were essentially his creation and much shaped by him.

Pushed by Davy, and well beyond the needs of lecturing, the Royal Institution had installed a well-equipped laboratory and a library, in a period when the very idea of such laboratories was new and just starting to be realized. The Royal Institution’s facility, well apt for cutting-edge research, developed into one of the best-equipped laboratories of the period, competing with places such as the Paris École Polytechnique. Faraday thus had unrestricted access to a unique resource of experimental research, a situation that he himself strongly endorsed and of which he took significant advantage. Both the lecture hall (where he spent much time) and the apartment he shared with his wife Sarah were in the Royal Institution’s building, hence he could easily switch between work and home, research and lecturing, at least as long he was not interrupted by one of the many visitors calling for information. Of course, this was not a situation without tensions. Faraday’s income at the Royal Institution was certainly not adequate, given the benefits he provided for the institution. However, he lived a modest life, even at the height of his fame, and gave the surplus mostly to charity. Nevertheless, his continued (and well-paid) teaching at the Royal Mili tary Academy at Woolwich for more than two decades was, among others, a deliberate step to lessen his financial dependence on one single institution with insecure financial standing. Moreover, combining living and work in one and the same house for a whole life was not necessarily a favorable arrangement. That Faraday was able to turn it into great success had also to do with the fact that his life had, besides work, also a second focus: his being part of the Sandemanian community—a life that took place outside the Royal Institution and in which, contrasted to his research and lecturing, Sarah took part equally.

To a far larger extent than hitherto realized, Faraday was active in public service. More than 10 percent of all of his correspondence deals with lighthouses alone, stemming from his work for Trinity House (from 1836 on). He was scientific adviser to the Admiralty, the Home Office, the Board of Trade, the Office of Woods and Forests, and the Board of Ordnance. These projects ranged from a gunpowder factory explosion to conservation issues of works of art. His inquiry into the devastating explosion at Haswell Colliery (1844) was a key event in the relationship of science and politics and in labor history—it is cited by Friedrich Engels for example.

The situation at the Royal Institution (which he himself had considerably shaped and stabilized), his enormous success as a public lecturer and scientific advisor, and his religious life combined to form a peculiar and very specific constellation—a constellation that gave him much inner and outer stability and relieved him to a considerable degree from the compulsion of scientific competition. This was an important element of his capacity to pursue his own ideas and conceptualizations, even through long periods of nonresponse or rejection from the academic environment.

Experimenting . Faraday is most known as an experimenter. Indeed, those achievements that made him famous in his time rely on experiments, be it electromagnetic rotation (1821), the liquefaction of gases (1823), the discovery of benzene (1825), electromagnetic induction (1831), the identity of various electricities (1833), the laws of electrolysis (1834), the magneto-optical effect (1845), or diamagnetism (1845–1846). Contrasting to the older picture of Faraday’s experiments being guided by speculative views on matter and force, new studies of his experimental practice by David Gooding, Friedrich Steinle, and Ryan D. Tweney have drawn quite a different picture. The core of his experimental approach was never individual, single experiments but always extended experimental series—a point that is easily eclipsed when focusing on his prominent discoveries. But these discoveries are only understandable as outcomes of those experimental series. The main experimental procedure was a systematic

variation of experimental parameters, with the goal of finding constant correlations and establishing laws. Explaining a specific effect meant to him, first of all, placing it in a wider surrounding of related effects, then “deducing” one from another by building a chain of experimental phenomena, or, as he said, “putting facts closely together.” Sometimes this required framing new concepts, or transferring existing ones into a totally new context, as in the case of magnetic curves.

Faraday had a laboratory assistant, the former Sergeant Charles Anderson, but it seems that in his considerations about the meaning and ordering of experimental results, and the planning of further experiments, he worked essentially alone. When other scientists visited him in the laboratory, he would show them his ready results, but not discuss ongoing research—the same holds for his well-documented and extensive correspondence.

Faraday’s experimental approach was intimately linked to his practice of record keeping. He probably put down notes right in the laboratory, but edited them in clear writing afterward (typically on a daily basis), numbered each entry for later reference, and eventually bound these notes into books. In composing his papers for publication, he would often take directly the wording and the figures of his notebook. As the number of experiments increased greatly over the years, he started to work on indices and superindices to enable later retrieval. And even in later years he would still come back to experiments made more than a decade earlier. Such a conscious dealing with enormous amounts of experimental records was extraordinary at his time; see, for example, the contrasting case of Ampère.

Theorizing. Faraday’s success as an experimentalist has long overshadowed his efforts and achievements in theorizing and conceptualizing. But his work was at least as strongly focused on understanding and ordering experimental outcomes as on obtaining new experimental effects. His approach focused more on formulating laws and on fundamental concepts than on searching for hidden entities that would provide causal explanations. More than others, he was ready to question fundamental concepts, such as electric current, electric attraction, and magnetic polarity, and to propose new concepts, such as electromagnetic rotation as an elementary effect, magnetic and electric curves (later to be renamed lines of force), specific capacity, dia- and paramagnetism, and of course electric and magnetic fields. In some cases he consulted other scholars (most notably William Whewell) for appropriate words in order to keep the new concepts as neutral as possible with respect to explanatory theories. Only when a firm experimental and conceptual foundation was achieved, was he ready to put real effort into the question of hidden causes, such as the theory of electrolysis or of polarization.

The concepts thus created were “empirically saturated,” in the sense that Faraday formed and developed them with an ever-growing body of experimental results in mind, for which they should enable a formulation of regularities and laws. In face of new experimental evidence, he was ready to a very high degree to revise and refine those concepts again and again, with the result that in the end they found a very precise formulation, though not in mathematical language. That he was able to form such unconventional concepts at all had to do with his noncommitment to any established school of physical thinking, and with his deep feeling of the responsibility to fit his concepts to nature. At the same time, it was exactly this character of the concepts that made them appear weird for most of his contemporaries, because they did not resonate with the established body of knowledge of the period.

Ever since his first use of “magnetic curves” in 1831 for the induction law, he emphasized he was not claiming physical reality of these curves, but rather was using them

as a convenient tool to express the spatial distribution of magnetic force. Rather than being an “embarrassment” for Faraday, as Leslie Pearce Williams suggests in the original DSB article, this peculiar status of lines of force lay at the core of his approach. Faraday kept that cautious attitude for decades, even when conceiving the curves as movable (1832), introducing electric lines of force (1838), formulating diamagnetic behavior in terms of lines of force (1848), or finally developing a general theory of magnetism in terms of lines of force (1850). Only in 1851, at a stage when he oversaw a huge domain of electromagnetic effects, did he drop his reluctance and state that there probably was more to lines of force than just being descriptive tools: their successful application comprised much wider realms than any other concept of electrodynamics.

Religion . Throughout his life, and while living in the Royal Institution’s building, Faraday kept apart his professional and private life. The latter was most intensely shaped by his adherence to the Sandemanian sect, a strict religious group that comprised not more than four hundred members in England and Scotland in his time. Faraday’s confession of faith in 1821 was certainly one of the most important moments of his life. Like all members of that community, Faraday spent much time and effort with services, gatherings, and duties such as caring for the sick or preaching, often outside London. His important social connections were more or less completely located within the community and formed strong ties. It is indicative, for example, that while he generally refused to write support letters for anyone for positions, he deviated from this rule in the case of Sandemanian brethren. His funeral, on his own wish, and despite his wide fame, took place only within a small circle of Sandemanians.

Both his personal faith and the Sandemanian community life gave Faraday a considerable degree of personal stability. Correspondingly, however, instabilities within the Sandemanian community (such as his temporary exclusion in 1844) affected him profoundly and made him existentially suffer, in sharp contrast to problems and lack of resonance in his scientific surroundings. Moreover, his religion provided him with a specific attitude toward researching nature. In his 1854 lecture “Mental Education,” he emphasized the importance of humility in the face of God’s creation. The extraordinary degree to which he kept his concepts and theoretical ideas open for revision by further experience (dubbed “Negative capability” by Elspeth Crawford), and also his persistence in keeping his unconventional ideas, can well be understood as his own way of realizing that virtue.

Impact . Faraday’s impact on research in electrodynamics (and physics in general) was immense. From 1830 on, he was the one to put challenges and create the “hot topics” in electrodynamics for two and a half decades: rotation, induction, specific capacity, magneto-optical effect, diamagnetism, and lines of force. The continuing series of Faraday’s papers was translated into various languages on a regular basis. However, the reception was split in a characteristic way: While his experimental results were highly praised, his conceptual approach met with silence or criticism. This had partly to do with his total lack of mathematical education in a period when physics became strongly mathematized and partly with his uneasy way of presenting his results, switching between meticulous experimental descriptions and general considerations. The largest obstacle, however, was the unconventional character of some of his new concepts. Wilhelm Weber, for example, in his 1845 Maassbestimmungen, mentioned Faraday as a gifted experimentalist and discoverer of the induction effect, but found there was no law of induction. Obviously he did not regard Faraday’s induction law of 1832 as something to be considered seriously—it was formulated in terms of magnetic curves and hence probably too far from anything a physicist of the time could deal with.

The second half of the century saw the development of field-theory in mathematical form. It is important to note that what James Clerk Maxwell set out to mathematize was not specific effects, domains, or laws, but the concept of lines of force, as he took it from Faraday. The striking historical observation that Maxwell’s success in mathematizing the concept provided a comprehensive theory of a vast range of electrodynamic effects, without having discussed that variety of effects in detail, can be understood just by highlighting the “empirically saturated” and highly precise character of Faraday’s concepts.

A third aspect of Faraday’s impact has received less attention. While Faraday never formulated anything like a methodology, his peculiar approach was quite visible and would eventually become subject of methodological considerations. The growing insight into the inadequacy of the search for the “hidden levers and screws” of nature during the last decades of the nineteenth century was in part stimulated by the complex dispute of Weberian, Neumannian, and Faraday-Maxwellian electrodynamics. A major exponent of that changing ideal of knowledge, Hermann von Helmholtz, explicitly attributed his own turn away from the search for hidden mechanisms to his reading of Faraday. Even in recent attempts to widen the understanding of experimental practice in general, Faraday figures as a prominent example and unique resource because of his peculiar productivity, the unique availability of sources that enable insight into his everyday practice, and the specific experimental approach that does not fit the standard view of experiment.

SUPPLEMENTARY BIBLIOGRAPHY

The Royal Institution of Great Britain, the Royal Society, the Guildhall Library, and the Institution of Engineering and Technology keep much archival material (manuscripts, lecture notes, and so forth), all of which has been microfilmed and stored on compact disc, available from Microform Academic, Wakefield, United Kingdom.

WORKS BY FARADAY

Faraday’s Diary: Being the Various Philosophical Notes of Experimental Investigation Made by Michael Faraday during the Years 1820–1862 and Bequeathed by Him to the Royal Institution of Great Britain. Edited by Thomas Martin. London: G. Bell, 1932–1936.

Experimental Researches in Electricity. New York: Dover, 1965. Originally published 1839–1855.

Experimental Researches in Chemistry and Physics. London: Taylor & Francis, 1991. Originally published in 1859.

The Correspondence of Michael Faraday. 4 vols. Edited by Frank A. J. L. James. London: Institution of Electrical Engineers, 1991–. Complete edition, with excellent comments and introduction.

Curiosity Perfectly Satisfyed: Faraday’s Travels in Europe 1813–1815. Edited by Brian Bowers and Lenore Symons. IEE History of Technology Series, 16. London: Peter Peregrinus, 1991. Faraday’s notebook of the “Continental Tour.”

Michael Faraday’s “Chemical Notes, Hints, Suggestions and Objects of Pursuit” of 1822. Edited by Ryan D. Tweney and David Gooding. IEE History of Technology Series, 17. London: Peter Peregrinus, 1991.

OTHER SOURCES

Berman, Morris. Social Change and Scientific Organization: The Royal Institution, 1799–1844. Ithaca, NY: Cornell University Press, 1978.

Cantor, Geoffrey N. Michael Faraday: Sandemanian and Scientist; A Study of Science and Religion in the Nineteenth Century. Basingstoke, U.K.: Macmillan, 1991.

——. “The Scientist as Hero: Public Images of Michael Faraday.” In Telling Lives in Science: Essays on Scientific Biography, edited by Michael Shortland and Richard Yeo. Cambridge, U.K.: Cambridge University Press, 1996.

Cantor, Geoffrey N., David Gooding, and Frank A. J. L. James. Faraday. London: Macmillan, 1991.

Caroe, Gwendy M. The Royal Institution: An Informal History. London: John Murray, 1985.

Cavicchi, Elizabeth. “Experimenting with Magnetism: Ways of Learning of Joann and Faraday.” American Journal of Physics65, no. 9 (1997): 867–882.

Crawford, Elspeth. “Learning from Experience.” In Faraday Rediscovered: Essays on the Life and Work of Michael Faraday, 1791–1867, edited by David Gooding and Frank A. J. L. James. Basingstoke, U.K.: Macmillan; New York: Stockton, 1985.

Forgan, Sophie. “Faraday—From Servant to Savant: The Institutional Context.” In Faraday Rediscovered: Essays on the Life and Work of Michael Faraday, 1791–1867, edited by David Gooding and Frank A. J. L. James. Basingstoke, U.K.: Macmillan; New York: Stockton, 1985.

Gooding, David. Experiment and the Making of Meaning: Human Agency in Scientific Observation and Experiment. Dordrecht: Kluwer, 1990.

—— and Frank A. J. L. James, eds. Faraday Rediscovered: Essays on the Life and Work of Michael Faraday, 1791–1867. Basingstoke, U.K.: Macmillan; New York: Stockton, 1985.

James, Frank A. J. L. “Michael Faraday and Lighthouses.” In The Golden Age: Essays in British Social and Economic History, 1850–1870, edited by Ian Inkster with Colin Griffin, Jeff Hill, and Judith Rowbotham. Aldershot, U.K.: Ashgate, 2000.

——. “Running the Royal Institution: Faraday as an Administrator.” In The Common Purposes of Life: Science and Society at the Royal Institution of Great Britain, edited by Frank A. J. L. James. Aldershot, U.K.: Ashgate, 2002.

—— and Margaret Ray. “Science in the Pits: Michael Faraday, Charles Lyell, and the Home Office Enquiry into the Explosion at Haswell Colliery, County Durham, in 1844.” History and Technology 15 (1999): 213–231.

Nersessian, Nancy J. Faraday to Einstein: Constructing Meaning in Scientific Theories. Science and Philosophy. Dordrecht: Nijhoff, 1984.

Steinle, Friedrich. “Entering New Fields: Exploratory Uses of Experimentation.” Philosophy of Science 64, Supplement (1997): S65–S74.

——. “The Practice of Studying Practice: Analyzing Research Records of Ampère and Faraday.” In Reworking the Bench: Research Notebooks in the History of Science, edited by Frederic Lawrence Holmes, Jürgen Renn, and Hans-Jörg Rheinberger. Archimedes 7. Dordrecht: Kluwer, 2003.

——. Explorative Experimente: Ampère, Faraday und die Ursprünge der Elektrodynamik. Boethius 50. Stuttgart: Steiner, 2005.

Tweney, Ryan D. “Faraday’s Notebooks: The Active Organization of Creative Science.” Physics Education 26 (1991): 301–306.

——. “Discovering Discovery: How Faraday Found the First Metallic Colloid.” Perspectives on Science 14, no. 1 (2006): 97–121.

Friedrich Steinle

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Faraday, Michael (1791-1867)

Faraday, Michael (1791-1867)

English physicist and chemist

Michael Faraday's early life had a remarkable resemblance to that of Benjamin Franklin . Faraday was born in Newington, Surrey, England. Like Franklin, Michael Faraday was part of a large family. His father was a blacksmith who lacked the resources to obtain a formal education for his son.

Franklin had been apprenticed to a printer; young Faraday went a similar route, becoming apprenticed to a bookbinder. In each case, this led to a voracious love of books. Michael was especially interested in chemistry and electricity . He studied the articles about electricity in the Encyclopaedia Britannica. His employer not only allowed him to read all that he wanted, he encouraged the boy to attend scientific lectures.

A turning point occurred in 1812. In that year, Faraday obtained tickets to hear the lectures of Humphry Davy at the Royal Institution. Faraday took careful notes extending to 386 pages, which he had bound in leather. He sent a copy to Sir Joseph Banks (17431820), president of the Royal Society of London, who wielded great influence over European scientific investigation. Faraday hoped to make a favorable impression, but if Banks ever looked through the book with its carefully drawn and colored diagrams, Faraday never knew it.

Determined not to be ignored, Faraday sent a copy of his notes to Davy and included an application for a job as Davy's assistant. Davy was impressed, but did not offer Faraday work as he already had an assistant. Later, however, after firing the assistant in 1813, Davy contacted Faraday. The job description was not quite what Faraday had in mind. A trustee of the Royal Institution had said, "Let him wash bottles. If he is any good, he will accept the work; if he refuses, he is not good for anything." Faraday accepted, even though it meant he would be paid less than what he was making as a bookbinder.

Shortly thereafter, Davy resigned his post at the Royal Institution, married a wealthy widow, and decided to travel through Europe . Faraday accompanied the couple and met such illustrious men as Italian physicist Alessandro Volta and French chemist Louis-Nicholas Vauquelin.

In 1820, Danish Physicist Hans Christian Oersted amazed scientists with the discovery that electric current produced a magnetic field . Faraday had a greater goal in sight: Oersted had converted electric current into a magnetic force; Faraday intended to reverse the process and create electricity from magnetism . Within a year Faraday, now back in England, constructed a device that essentially consisted of a hinged wire, a magnet and a chemical battery. When the current was turned on, a magnetic field was set up in the wire, and it began to spin around the magnet. Faraday had just invented the electric motor. Faraday's motor was certainly an interesting device, but it was treated as a toy.

At this point, Davy, realizing that Faraday had the potential to eclipse him, jealously claimed that Faraday had taken his own idea for the experiment.

Faraday's first major contribution to chemistry came a few years later. In 1823 he unknowingly became the "father" of cryogenics by producing laboratory temperatures that were below freezing . He discovered how to liquefy carbon dioxide , chlorine, hydrogen sulfide, and hydrogen bromide gases by placing them under pressure, but again Davy took the credit. Two years later Faraday discovered the compound benzene, which became his greatest contribution in chemistry. In 1865 German chemist Friedrich Kekulé was able to determine the structure of benzene, leading to the understanding of molecular structure in general.

The studies of magnetism and electricity were still main interests of Faraday, so he elaborated on Davy's pioneering work in electrochemistry. Davy had passed an electric current through a variety of molten metals and created new metals in the process. Faraday named this process electrolysis. He also bestowed names that were suggested by the British scholar Whewell and are still in use today: electrolyte, for the compound or solution that conducts electricity; electrode, for the metal rod inserted in the object; and anode and cathode for the positively and negatively charged electrodes, respectively.

In 1832, Faraday devised what became known as Faraday's laws of electrolysis, which hold that the mass of the substance liberated at an electrode during electrolysis is proportional to the amount of electricity going through the solution; and the mass liberated by a given amount of electricity is proportional to the atomic weight of the element liberated and inversely proportional to the "combining power" of the element liberated. The two laws showed there was a connection between electricity and chemistry. They also supported the suggestion that Franklin had made nearly 100 years earlier when he claimed electricity was composed of particles, a theory that would be another 50 years in the making.

In another experiment, Faraday sprinkled iron filings on a paper which was held over a magnet and noticed the filings had arranged themselves along what he called "lines of force." The connections along the lines showed where the strength of the field was equal. With the magnetic field now "visible," scientists began to wonder if space itself was filled with inter-acting fields of various types and this helped establish a new way of thinking about the universe. Up to this point most scientists had believed in the mechanical nature of the universe as established by Galileo and Isaac Newton.

Taking the concept of his lines of force one step farther, Faraday realized that when an electric current began to flow it caused lines of force to expand outward. When the current stopped, the lines collapsed. If the lines expanded and collapsed across an intervening wire, an electric current would be induced to flow through it, first forward then in reverse.

By now Faraday was giving public lectures, which were very popular, at the Royal Institute, just as Davy had. Faraday reasoned that if electricity could induce a magnetic field, then it should be possible for the reverse to be true. Taking an iron ring during one demonstration, Faraday wrapped half of it with a coil of wire that was attached to a battery and switch. André Ampère (17751836) had shown that electricity would set up a magnetic field in the coil. The other half of the ring was wrapped with a wire that led to a galvanometer. In theory, the first coil would set up a magnetic field that the second coil would intercept and convert back to electric current, which the galvanometer would register. Faraday threw the switch: the experiment worked. He had just invented the transformer. However, the result was not exactly what he expected. Instead of registering a continuous current, the galvanometer moved only when the circuit was opened or closed. Ampère had observed the same effect a decade earlier but ignored it because it did not fit his theories. Deciding to make the theory fit the observation, instead of the other way around, Faraday concluded that when the current was turned on or off, it caused magnetic "lines of force" from the first coil to expand or contract across the second coil, inducing a momentary flow of current in the second coil. Faraday had now discovered electrical induction. Meanwhile, in the United States, physicist Joseph Henry had independently made the same discovery.

In 1839, at the age of 48, Faraday had a nervous breakdown. Faraday never completely recovered. It is also possible that he was afflicted with a low-grade chemical poisoning. This was a common ailment that affected chemists at the time; Davy had suffered from it as well. In any event, Faraday's failing memory forced him to leave the laboratory.

Faraday published a book describing his lines of force in 1844, but because he lacked a formal education it was written without mathematical equations. Consequently the book was not taken seriously. When James Clerk Maxwell investigated the subject, he essentially came to the same conclusion as Faraday had, but used mathematics to prove his theory.

Although out of the laboratory, Faraday was by no means inactive. He investigated the effect of weak magnetic fields on nonmetallic substances and coined the words paramagnetic and diamagnetic to differentiate between the force of attraction and repulsion. Development of a theory to explain the two opposing forces, however, had to wait more than 50 years for the work of Paul Langevin. In the 1850s, during the Crimean War, the British government sought his opinion on the feasibility of using poisonous chemical weapons, and asked him to oversee their development. Faraday immediately said the project was very feasible, but he refused to have anything to do with its initiation.

Faraday died at Hampton Court, Middlesex, England. The word "farad," which is a unit of capacitance, was named in his honor.

See also Electricity and magnetism; Electromagnetic spectrum

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Faraday, Michael

Faraday, Michael


ENGLISH CHEMIST AND PHYSICIST
17911867

Michael Faraday, the leading chemist and natural philosopher in England during the middle third of the nineteenth century, discovered the principle behind the electric motor (1821), benzene (1825), the electric transformer

and generator (1831), the laws of electrolysis (early 1830s), and the magneto-optical effect and diamagnetism (1845), which enabled him to develop the field theory of electromagnetism, one of the cornerstones of modern physics.

Faraday was born on September 22, 1791, in Newington Butts, south of London. His father, a blacksmith, belonged to the Sandemanians, a small literalist sect (in which the members believe in the literal truth of the Bible) of Christianity. Faraday was fully committed to this sect, becoming a deacon in 1832 and an elder in the 1840s and again in the 1860s. He married a fellow Sandemanian, Sarah Barnard, in 1821 and died on August 25, 1867, in his "grace and favour" house (a house given by a monarch to a subject in recognition of worth and of need) at Hampton Court. In his scientific research, Faraday sought to determine the laws of nature that he believed God had written at the creation of the universe. Although it was only toward the end of his life that problems began to emerge between some types of Christianity and science, mostly in response to Charles Darwin's theory of natural selection, published in 1859, Faraday did not see any conflict between them.

Faraday attended a day school and in 1805 he began an apprenticeship as a bookbinder, which was to last for seven years. During this time he developed a strong interest in science, particularly chemistry, and in 1812, the final year of his apprenticeship, he attended four lectures delivered by Humphry Davy at the recently founded (1799) Royal Institution in London's West End. Faraday sent his notes on Davy's lectures to Davy asking for a job in the field of science; he was eventually appointed as an assistant in the Royal Institution's laboratory. Between the fall of 1813 and spring of 1815 he toured Europe with Davy and helped him establish the fact that iodine was a chemical element. Returning to England, Faraday was reappointed to the Royal Institution and promoted through the ranks, becoming the director of its laboratory in 1825 and first Fullerian Professor of Chemistry in 1833. In these roles, Faraday established Christmas lectures for children and Friday evening discourses, both of which series still continue.

During the 1820s much of Faraday's work centered on chemistry. He aided Davy in his disastrous efforts to protect electrochemically the copper bottoms of ships and with the equally unsuccessful project to improve optical glass. In 1823 Faraday liquefied the gas chlorine for the first time and in the 1840s he liquefied several more gases. His liquefaction of chlorine resulted in a bitter break with Davy, by now president of the Royal Society , who believed that Faraday had not given him sufficient credit for his part in the work. Davy thus tried, albeit unsuccessfully, to block Faraday's election to the Royal Society. Two years later Faraday discovered, but did not investigate fully, a new chemical that he named "bi-carburet of hydrogen." Nearly ten years later Eilhardt Mitscherlich, a chemistry professor in Berlin, first undertook a detailed study of the substance that he renamed benzene. Faraday, nevertheless, is credited with benzene's discovery, and in 1925 there were major celebrations throughout England marking the 100-year anniversary of Faraday's discovery.

Following his 1831 electromagnetic work, Faraday turned his attention to electrochemistry. The decomposition of chemical compounds was a standard test for the presence of electricity. In his extensive use of this test, he observed phenomena contradicting Davy's theory that electrochemical decomposition occurred at the metal pole. Faraday found that decomposition occurred in the substance itself and the poles did not need to be metal. All this led Faraday to develop a new language of electrochemistry. With a number of classical scholars, notably William Whewell, Faraday introduced terms such as electrolysis, electrolyte, electrode, anode, cathode, and ion (although he said there would be little need for this last term).

Faraday was thus able to enunciate his two laws of electrolysis. His second law implied that both matter and electricity were atomic in nature. Faraday was deeply opposed to atomism, especially the theory proposed by John Dalton, and indeed held a very antimaterialist view. It was clear to Faraday, however, that the law of definite proportions also required some sort of atomic theory . What Faraday proposed in the 1840s was that matter was perceived where lines of force met at a particular point in space. A direct experimental outcome of this radical theory was Faraday's discovery in 1845 of the magneto-optical effect and diamagnetism. The field theory that Faraday developed from this was able to solve a number of problems in physics that were not amenable to conventional approaches. This was one reason why field theory was taken up quite quickly by elite natural philosophers such as William Thomson (later Lord Kelvin) and James Clerk Maxwell. Nevertheless, the theory was not generally accepted for some time because it was seen by many physicists as opaque and, in origin, nonmathematical. However, as the German organic chemist Justus von Liebig pointed out, this occurred because physicists did not recognize Faraday's background as a chemist, a factor Liebig thought crucial in the development of Faraday's theory: "To physicists, who have approached physics by the road of chemistry, Faraday's memoirs sound like admirably beautiful music" (Hofmann, p. 1100).

see also Dalton, John; Davy, Humphry; Electrochemistry; Iodine; Liebig, Justus von; Maxwell, James Clerk.

Frank A. J. L. James

Bibliography

Cantor, Geoffrey (1991). Michael Faraday, Sandemanian and Scientist: A Study of Science and Religion in the Nineteenth Century. London: Macmillan.

Cantor, Geoffrey; Gooding, David; and James, Frank A. J. L. (1996). Michael Faraday. Atlantic Highlands, NJ: Humanities Press.

Gooding, David (1990). Experiment and the Making of Meaning: Human Agency in Scientific Observation and Experiment. Dordrecht and Boston: Kluwer Academic.

Gooding, David, and James, Frank A. J. L., eds. (1985). Faraday Rediscovered: Essays on the Life and Work of Michael Faraday, 17911867. London: Macmillan.

Hofmann, August (1875). "Faraday Lecture." Journal of the Chemical Society 13:1100.

James, Frank A. J. L. (1991). The Correspondence of Michael Faraday. 4 vols. and others in preparation. London: Institution of Electrical Engineers.

Thompson, Sylvanus P. (1898). Michael Faraday: His Life and Work. London: Cassell.

Internet Resources

The Royal Institution of Great Britain. Available from <http://www.rigb.org/heritage/index.html>.

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Faraday, Michael (1791-1867)

Faraday, Michael (1791-1867)

Famous British physicist, born in London on September 22, 1791. He became an assistant to Sir Humphry Davy and later became celebrated for his brilliant discoveries relating to electricity and chemistry. Faraday's well-known saying, "Nothing is too amazing to be true," apparently was not meant to cover table turning. It was, for him, too amazing to be true. His noted theory that table movements were caused by unconscious muscular pressure was first advanced in a letter to the Times of June 30, 1853. To prove it, he prepared two small flat boards a few inches square, placed several glass rollers between them and fastened the whole together with a couple of rubber bands so that the upper board would slide under lateral pressure to a limited extent over the lower one. A light index fastened to the upper board would betray the least amount of sliding.

During experiments this is just what happened. The upper board always moved first, which demonstrated that the fingers moved the table and not the table the fingers. Faraday also found that when the sitters learned the meaning of the index and kept their attention fixed on it, no movement took place. When it was hidden from their sight it kept on wavering, although the sitters believed that they always pressed directly downward. However, the pressure of the hands was trifling and was practically neutralized by the absence of unanimity in the direction. The sitters never made the same movement at the same moment.

For this reason, and for the weightier one that tables moved without contact as well, his theory was soon found inadequate. According to Charles Richet, it was Michel Chevreul, the famous French chemist, who originally evolved the theory of un-conscious muscular pressure. Chevreul's book, however, did not appear until 1854, a year after Faraday's explanation was published.

In later years many attempts were made to prove to Faraday the reality of psychic phenomena, but he was too obstinate. "They who say these things are not competent witnesses of facts," he wrote in 1865. To an invitation to attend the first séance of the Davenport brothers he returned the answer, "If spirit communications, not utterly worthless, should happen to start into activity, I will trust the spirits to find out for themselves how they can move my attention. I am tired of them."

Faraday was a member of the Sandemanians, an obscure religious sect holding rigid biblical views. When Sir William Crookes inquired of Faraday how he reconciled science with religion, he received the reply that he kept his science and religion strictly apart.

At the time of the Home-Lyon trial (see D. D. Home ), a Professor Tyndall, in a letter in Pall Mall Gazette (May 5, 1868), wrote that, years before, Faraday had accepted an invitation to examine Home's phenomena, but his conditions were not met and the investigation fell through. When the original correspondence on the subject between Faraday and Sir Emerson Tennant was published, it appeared that one of Faraday's conditions was, "If the effects are miracles, or the work of spirits, does he (Home) admit the utterly contemptible character, both of them and their results, up to the present time, in respect either of yielding information or instruction or supplying any force or action of the least value to mankind?" Robert Bell, the intermediary for the proposed séance, found Faraday's letter so preposterous that, without consulting Home, he declined his intervention. Home, when he learned about it, was duly indignant.

Professor Tyndallas an arch skepticcommended Faraday's attitude, but those interested in psychical research assumed the contrary position. "The letter," writes Frank Pod-more in Modern Spiritualism (1902), "was, of course, altogether unworthy of Faraday's high character and scientific eminence, and was no doubt the outcome of a moment of transient irritation. The position taken was quite indefensible. To enter upon a judicial inquiry by treating the subject-matter as a chose jugée was surely a parody of scientific methods."

Faraday died August 25, 1867. In a series of séances between 1888 and 1910 in Spring Hall, Kansas, the presiding spirit claimed to be Faraday, and his communications were published in four books by A. Aber: Rending of the Veil, Beyond the Veil, The Guiding Star, and The Dawn of Another Life. A second set of communications reportedly from Faraday were received by an anonymous medium who called herself (or himself) the "Mystic Helper." The messages were received sporadically beginning in 1874 and were finally published in 1924.

Sources:

Berger, Arthur S., and Joyce Berger. The Encyclopedia of Parapsychology and Psychical Research. New York: Paragon House, 1991.

Mystic Helper, The. The Evolution of the Universe, or, Creation According to Science. Los Angeles: Cosmos Publishing, 1924.

Podmore, Frank. Modern Spiritualism. London: Methuen, 1902. Reprinted as Mediums of the Nineteenth Century. New Hyde Park, N.Y.: University Books, 1963.

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Michael Faraday

Michael Faraday

The English physicist and chemist Michael Faraday (1791-1867) discovered benzene and the principles of current induction.

One of a blacksmith's 10 children, Michael Faraday was born on Sept. 22, 1791, in Newington, Surrey. The family soon moved to London, where young Michael picked up the rudiments of reading, writing, and arithmetic. At the age of 14 he was apprenticed to a bookbinder and bookseller. He read ravenously and attended public lectures, including some by Sir Humphry Davy.

Faraday's career began when Davy, temporarily blinded in a laboratory accident, appointed Faraday as his assistant at the Royal Institution. With Davy as a teacher in analytical chemistry, Faraday advanced in his scientific apprenticeship and began independent chemical studies. By 1825 he discovered benzene and had become the first to describe compounds of chlorine and carbon. He adopted the atomic theory to explain that chemical qualities were the result of attraction and repulsion between united atoms. This proved to be the theoretical foundation for much of his future work.

Faraday had already done some work in magnetism and electricity, and it was in this field that he made his most outstanding contributions. His first triumph came when he found a solution to the problem of producing continuous rotation by use of electric current, thus making electric motors possible. Hans Oersted had discovered the magnetic effect of a current, but Faraday grasped the fact that a conductor at rest and a steady magnetic field do not interact and that to get an induced current either the conductor or the field has to move. On Aug. 29, 1831, he discovered electromagnetic induction.

During the next 10 years Faraday explored and expanded the field of electricity. In 1834 he announced his famous two laws of electrolysis. Briefly, they state that for any given amount of electrical force in an electrochemical cell, chemical substances are released at the electrodes in the ratio of their chemical equivalents. He also invented the voltameter, a device for measuring electrical charges, which was the first step toward the later standardization of electrical quantities.

Faraday continued to work in his laboratory, but his health began to deteriorate and he had to stop work entirely in 1841. Almost miraculously, however, his health improved and he resumed work in 1844. He began a search for an interaction between magnetism and light and in 1845 turned his attention from electrostatics to electromagnetism. He discovered that an intense magnetic field can rotate the plane of polarized light, a phenomenon known today as the Faraday effect. In conjunction with these experiments he showed that the magnetic line of force is conducted by all matter. Those which were good conductors he called paramagnetics, while those which conducted the force poorly he named diamagnetics. Thus, the energy of a magnet is in the space around it, not in the magnet itself. This is the fundamental idea of the field theory.

Faraday was a brilliant lecturer, and through his public lectures he did a great deal to popularize science. Shortly after he became head of the Royal Institution in 1825, he inaugurated the custom of giving a series of lectures for young people during the Christmas season. This tradition has been maintained, and over the years the series have frequently been the basis for fascinating, simply written, and informative books.

On Aug. 25, 1867, Faraday died in London.

The admiration of physicists for Faraday has been demonstrated by naming the unit of capacitance the farad and a unit of charge, the faraday. No other man has been doubly honored in this way. His name also appears frequently in connection with effects, laws, and apparatus. These honors are proper tribute to the man who was possibly the greatest experimentalist who ever lived.

Further Reading

Much has been written about Faraday, but the student should first read the account by his successor at the Royal Institution, John Tyndall, Faraday as a Discoverer (1961). The sketch of Faraday in James Gerald Crowther, Men of Science (1936), is also recommended. Leslie Pearce Williams, Michael Faraday: A Biography (1965), appraises Faraday's work in relation to modern science and contains many previously unpublished manuscripts. □

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Faraday, Michael

Michael Faraday (fâr´ədē, –dā´), 1791–1867, English scientist. The son of a blacksmith, he was apprenticed to a bookbinder at the age of 14. He had little formal education, but acquired a store of scientific knowledge through reading and by attending educational lectures including, in 1812, one by Sir Humphry Davy. The following year he became Davy's assistant at the Royal Institution in London. Faraday was made a member of the institution in 1823 and a fellow of the Royal Society in 1824. In 1825 he became director of the laboratory, and from 1833 he was Fullerian professor of chemistry at the Royal Institution. He subsequently declined knighthood and the presidency of the Royal Society.

Faraday's experiments yielded some of the most significant principles and inventions in scientific history. He developed the first dynamo (in the form of a copper disk rotated between the poles of a permanent magnet), the precursor of modern dynamos and generators. From his discovery of electromagnetic induction (1831; also independently discovered by the American Joseph Henry) stemmed a vast development of electrical machinery for industry. In 1825 he discovered the compound benzene. In addition to other contributions he did research on electrolysis, formulating Faraday's law. He also laid the foundations of the classical electromagnetic field theory, later fully developed by J. C. Maxwell. Some of his works were collected as Experimental Researches in Electricity (3 vol., 1839–55) and Experimental Researches in Chemistry and Physics (1859).

See his diary (ed. by T. Martin, 7 vol., 1932–36); his correspondence (ed. by L. P. Williams, 2 vol., 1971); biographies by T. Martin (1934), L. P. Williams (1965), G. Cantor (1991), and J. Hamilton (2005); studies by D. Gooding and F. A. James, ed. (1986) and N. Forbes and B. Mahon (2014).

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Faraday, Michael

Faraday, Michael (1791–1867). Chemist and pioneer of electromagnetism. As a bookbinder's apprentice, he went to Humphry Davy's lectures at the Royal Institution and asked to be taken on as his assistant. Accompanying Davy to Paris and Rome in 1813–15, by 1820 he was himself a prominent chemist, famous for his experimental skill, thinking with his fingers. He isolated benzene in 1825, and when Davy died in 1829 he could escape from his shadow and work on the nature of electricity, magnetism, and light. After his death, this led to the electrical industry; and by the 1860s with J. C. Maxwell's work, it had transformed physics with field theory. Faraday was a keen member of the fundamentalist Sandemanian sect. He remained a very private man, refusing titles or (like Robert Boyle) public offices—a kind of scientific saint.

David Knight

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Faraday, Michael

Faraday, Michael (1791–1867) English physicist and chemist. Faraday worked as Sir Humphry Davy's assistant at the Royal Institution in London, where, in 1825 he became director of the laboratories. Faraday liquefied chlorine, discovered benzene (1825), and enunciated the laws of electrolysis (Faraday's laws). He also discovered electromagnetic induction, made the first dynamo, built a primitive electric motor, and studied nonconducting materials (dielectrics). The unit of capacitance (the farad) is named after him.

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