ruthenium

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ruthenium

The Columbia Encyclopedia, Sixth Edition | 2008 | The Columbia Encyclopedia, Sixth Edition. Copyright 2008 Columbia University Press. (Hide copyright information) Copyright

ruthenium , metallic chemical element; symbol Ru; at. no. 44; at. wt. 101.07; m.p. about 2,310°C; b.p. about 3,900°C; sp. gr. 12.41 at 20°C; valence commonly +2, +3, +4, +6, or +8. Ruthenium is a hard, lustrous, silver-gray metal with a close-packed hexagonal crystalline structure. It is found directly above osmium in Group 8 of the periodic table . Below about 100°C ruthenium is insoluble in acids, including aqua regia, but reacts violently if potassium chlorate is added. It reacts with the halogens and with fused alkali hydroxides. When heated above 800°C it oxidizes, but it does not react with air at room temperature. It forms compounds with silicon and sulfur. Its compounds resemble those of osmium. Ruthenium is found in nature with other metals of the so-called platinum group in river sands, in minerals such as laurite (the sulfide) and osmiridium, and in association with certain ores containing platinum, copper, and nickel. It is obtained commercially as a byproduct of the refining of nickel sulfide ores mined near Sudbury, Ont., Canada. Ruthenium metal powder is obtained as the final product of a complex chemical process. It is used as a catalyst in hydrogenation, isomerization, nitrogenation, oxidation, and reforming reactions. The metal is used as a hardener in electrical contact alloys and filaments, in jewelry, in pen nibs, and in instrument pivots. It is usually alloyed with other metals. It is a very good hardener for palladium and platinum, and vastly improves the corrosion resistance of titanium when added in small amounts. It is also used in alloys with cobalt, molybdenum, nickel, tungsten, and other metals. Ruthenium compounds are used to color ceramics and glass. Ruthenium was discovered in 1827 in an impure form by G. W. Osann in residues of crude platinum ores from the Ural Mts. of Russia. Pure ruthenium was first prepared by K. K. Klaus in 1845; he showed that Osann's sample contained at least one other metal.

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ruthenium

World Encyclopedia | 2005 | © World Encyclopedia 2005, originally published by Oxford University Press 2005. (Hide copyright information) Copyright

ruthenium (symbol Ru) Silver-white metallic element, one of the transition elements. It was discovered in 1844 by Russian chemist Karl Klaus (1796–1864). Ruthenium is found in platinum ores. It is used as a catalyst to harden other metals, and its alloys are used in electrical contacts and to colour glass and ceramics. Properties: at.no. 44; r.a.m. 101.07; r.d. 12.41; m.p. 2310°C (4190°F); b.p. 3900°C (7052°F); most common isotope Ru102 (31.61%).

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ruthenium

The Oxford Pocket Dictionary of Current English | 2009 | © The Oxford Pocket Dictionary of Current English 2009, originally published by Oxford University Press 2009. (Hide copyright information) Copyright

ru·the·ni·um / roōˈ[unvoicedth]ēnēəm/ • n. the chemical element of atomic number 44, a hard silvery-white metal of the transition series. (Symbol: Ru)

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Ruthenium catalysts for selective nucleophilic allylic substitution *.(Report)
Magazine article from: Pure and Applied Chemistry; 5/1/2008; ; 700+ words ; ...oxidative addition of allylic substrates to a ruthenium(II) center. Subsequent reaction with...substitution reaction. We focus here on ruthenium-catalyzed substitution of allylic substrates...enantioselective reactions possible. Keywords: ruthenium catalysis; allylic substitution; regioselectivity...
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Kinetic isotope effect evidence for the concerted transfer of hydride and proton from hydroxycyclopentadienyl ruthenium hydride in solvents of different polarities and hydrogen bonding ability (1).
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Ruthenium-Containing Bond Coats for Thermal Barrier Coating Systems
Magazine article from: JOM; 1/1/2006; ; 700+ words ; ...but a melting point 400C higher than NiAl, ruthenium-modified aluminide bond coats could provide...improved creep properties with increasing ruthenium content. Processing paths for ruthenium-modified NiAl-based bond coatings have...

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