mass spectrograph

mass spectrograph device used to separate electrically charged particles according to their masses; a form of the instrument known as a mass spectrometer is often used to measure the masses of isotopes of elements. J. J. Thomson and F. W. Aston showed (c.1900) that magnetic and electric fields can be used to deflect streams of charged particles traveling in a vacuum, and that the degree of bending depends on the masses and electric charges of the particles. In the mass spectrograph the particles, in the form of ions, pass through deflecting fields (produced by carefully designed magnetic pole pieces and electrodes) and are detected by photographic plates. The beam of ions first passes through a velocity selector, consisting of a combination of electric and magnetic fields that eliminates all particles except those of a given velocity. The remaining ion beam then enters an evacuated chamber where a magnetic field bends it into a semicircular path ending at the photographic plate. The radius of this path depends upon the mass of the particles (all other factors, such as velocity and charge, being equal). Thus, if in the original stream isotopes of various masses are present, the position of the blackened spots on the plate makes possible a calculation of the isotope masses. The mass spectrograph is widely used in chemical analysis and in the detection of impurities.

mass spectrograph (mass spectrometer) Instrument for separating ions according to their masses (or more precisely, according to their charge-to-mass ratio), used in chemical analysis. In the simplest types, an electric field accelerates ions, which a magnetic field then deflectes; the lighter the ions the greater the deflection. By varying the field, ions of different masses can be focused in sequence onto a photographic plate or detector and a record of charge-to-mass ratios obtained.