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Thallium (revised)

THALLIUM (REVISED)

Note: This article, originally published in 1998, was updated in 2006 for the eBook edition.

Overview

Thallium is a member of the aluminum family, Group 13 (IIIA) on the periodic table. The periodic table is a chart that shows how chemical elements are related to one another. Thallium is also a member of the heavy metals, along with gold, platinum, and lead.

Thallium was first discovered by means of a spectroscope. A spectroscope is a device for analyzing the light produced when an element is heated. The spectrum (plural: spectra) of an element consists of a series of colored lines that are different for every element. The brightest lines in the spectrum of thallium are green, which accounts for its name. In Greek, the word thallos means "green twig." The green lines in thallium's spectrum look like green twigs.

SYMBOL
Tl

ATOMIC NUMBER
81

ATOMIC MASS
204.37

FAMILY
Group 13 (IIIA)
Aluminum

PRONUNCIATION
THA-lee-um

Thallium is a rather uncommon element. Still, some of its compounds have important applications. For example, thallium sulfate (Tl2SO4) has long been used as a rodenticide (rat and mouse poison). One form of thallium is sometimes used to study the flow of blood in the body. It shows how well the heart is working.

Discovery and naming

The spectroscope was invented in 1814 by German physicist Joseph von Fraunhofer (1787-1826). Forty years later, German chemists Robert Bunsen (1811-99) and Gustav Robert Kirchhoff (1824-87) improved on the instrument and showed how it could be used to study chemical elements. (See sidebar on Bunsen in the cesium entry in Volume 1.)

Scientists were fascinated by the instrument. They could detect the presence of elements without actually seeing them. A mineral is made of many elements, each of which gives off its own series of colored (spectral) lines. The spectroscope is able to detect all the elements present in the mineral.

Within a period of four years after the work of Bunsen and Kirchhoff, four new elements were discovered: cesium, rubidium , thallium, and indium . All four elements are named after the color of their spectral lines. The discoverer of thallium was British physicist Sir William Crookes (1832-1919).

Interestingly, thallium was discovered at almost the same time by French chemist Claude-Auguste Lamy (1820-78). Lamy discovered thallium the "old fashioned way," by separating one of its minerals in the laboratory. For a short time, there was a difference of opinion as to whether Lamy or Crookes was the "real" discoverer of thallium. Eventually, the decision was made in favor of Crookes.

Physical properties

Thallium is a heavy, bluish-white metal that resembles lead, element 82. Thallium is very soft and melts easily. It is soft enough to cut with an ordinary knife and will leave a mark on paper if rubbed across it.

Thallium has a melting point of 302°C (576°F) and a boiling point of 1,457°C (2,655°F). Its density is 11.85 grams per cubic centimeter.

Chemical properties

Thallium is a fairly active element. It reacts with acids and with oxygen in the air. When exposed to air, it forms a thin coating of thallium oxide (Tl2O) that peels off easily. As the coating drops off, a new layer forms in its place.

Occurrence in nature

Thallium is quite uncommon in the Earth's crust. Its abundance is estimated to be about 0.7 parts per million. That puts it in the bottom half among the elements in terms of abundance. It is about as common as iodine or tungsten.

The most common minerals containing thallium are crookesite, lorandite, and hutchinsonite.

Isotopes

Two naturally occurring isotopes of thallium exist, thallium-203 and thallium-205. Isotopes are two or more forms of an element. Isotopes differ from each other according to their mass number. The number written to the right of the element's name is the mass number. The mass number represents the number of protons plus neutrons in the nucleus of an atom of the element. The number of protons determines the element, but the number of neutrons in the atom of any one element can vary. Each variation is an isotope.

Two dozen radioactive isotopes of thallium have also been made. A radioactive isotope is one that breaks apart and gives off some form of radiation. Radioactive isotopes are produced when very small particles are fired at atoms. These particles stick in the atoms and make them radioactive.

Thallium-201 is used by doctors to determine how well a person's heart is working. In many cases, the isotope is used as a stress test. Thallium-201 is injected into the patient's blood-stream as he or she exercises on a treadmill or bicycle. As soon as the exercise ends, the patient lies down. A large camera is passed over the body. The camera records the radiation given off by the isotope. This record shows whether the patient's heart is working properly or not.

Extraction

Thallium is obtained as a by-product of the recovery of lead and zinc. Gases from the recovery process are captured. They are then treated to obtain the pure metal.

Uses and compounds

For many years, thallium sulfate (Tl2SO4) was used as a rodenticide. It worked well with rats and mice because it passes through their skin easily. Once inside their bodies, it causes death. Thallium sulfate is also colorless and odorless, so rats and mice were not aware the compound was present.

Unfortunately, thallium sulfate has the same effects on humans. Accidental poisoning, especially of young children, led to the banning of thallium sulfate as a rodenticide in the United States in 1975. Today, safer compounds (for humans, not rats) are available for rodenticides.

Thallium is too expensive to have many practical applications. There are a few exceptions, however, that make use of special properties of the elements and its compounds. For example, thallium sulfide (Tl2S) is sometimes used in photocells. Photocells are devices that convert light into electrical energy. In some kinds of light, thallium sulfide does not conduct electricity very well. But in other kinds of light, it conducts very well. Special photocells can be built to take advantage of this property.

An alloy of thallium and mercury can be used to make low-temperature thermometers. An alloy is made by melting and mixing two or more metals. The mixture has properties different from those of the individual metals. The thallium-mercury alloy remains liquid at -60°C (-76°F). At that temperature, a mercury-only thermometer would freeze solid.

An interesting new application of thallium is in superconducting materials. Superconductors have no resistance to the flow of electricity. Once an electrical current begins flowing in the material, it continues to flow forever. Superconducting materials may have some very important practical applications in the future.

Accidental poisoning, especially of young children, led to the banning of thallium sulfate as a rodenticide in the United States in 1975.

Health effects

Both thallium and its compounds are very toxic. A person exposed to the element or its compounds over long periods of time develops weakness, pain in the arms and legs, and loss of hair. A high dosage in a short time leads to different symptoms. These symptoms include nausea, vomiting, diarrhea, pain in the arms and legs, coma, convulsions, and even death. People who work with thallium use extreme caution to avoid coming into contact with the material.

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Thallium

Thallium


melting point: 302°C
boiling point: 1,457°C
density: 11.8 g/cm
3
most common ions: Tl+, Tl 3+

Thallium was discovered in 1861 by the British chemist Sir William Crookes. While attempting a spectroscopic analysis of materials that contained tellurium, Crookes observed a previously unknown bright green line

on his spectroscope (a machine that identifies the kinds of light emitted by elements at high temperatures). The name thallium comes from the Greek word Thallos, meaning "green twig," and was chosen by Crookes because the spectral line he had observed reminded him of a fresh green shoot.

The abundance of thallium in Earth's crust is estimated to be between 0.1 and 1 mg/kg (ppm). It is widely dispersed and is often associated with potassium minerals. Small deposits of the thallium-bearing minerals such as lorandite and the aptly named crookesite exist in Greece and Sweden, respectively.

Thallium metal is so soft that it can easily be cut with a knife. It has a metallic luster that slowly tarnishes upon exposure to air to give the metal a bluish-gray appearance (caused by the formation of Tl2O3). The thin layers of surface oxide prevent further oxidation . However, in moist air or water, the soluble hydroxide TlOH is formed. Thallium can exist in two oxidation states, (I) and (III). When heated in air, the metal oxidizes to Tl2O. Thallium reacts vigorously with the halogens , forming dihalides of composition 2TlX 3 where X = fluorine, chlorine, or bromine. Thallium is rapidly dissolved in nitric acid but rendered passive in sulfuric and hydrochloric acids due to the formation of insoluble Tl(I) salts.

In biological systems, thallium is nonessential, (i.e., not required for organisms to complete their life cycles) and toxic at high concentrations. Thallium(I) mimics potassium. In humans it affects potassium-activated enzymes in the brain, muscles, and skin. Symptoms of thallium poisoning can easily be attributed to other causes, which in the past has made this element popular for homicides!

Currently, thallium is used in some electronic devices, in low melting point glass, and in the creation of low melting point alloys .

see also Halogens; Potassium.

Brett Robinson

Bibliography

Cotton, F. Albert; Wilkinson, Geoffrey; Mruillo, Carlos A.; et al. (1999). Advanced Inorganic Chemistry, 6th edition. New York: Wiley.

Emsley, John (2001). Nature's Building Blocks: An A-Z Guide to the Elements. New York: Oxford University Press.

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thallium

thallium (thăl´ēəm), metallic chemical element; symbol Tl; at. no. 81; interval in which at. wt. ranges 204.382–204.385; m.p. 303.5°C; b.p. about 1,457°C; sp. gr. 11.85 at 20°C; valence +1 or +3. Thallium is a soft, malleable, lustrous silver-gray metal with a hexagonal close-packed crystalline structure. A member of Group 13 of the periodic table, it resembles aluminum in its chemical properties. In its physical properties it resembles lead. It forms univalent compounds similar to those of the alkali metals. It tarnishes rapidly in dry air, forming a heavy oxide coating; in moist air or water the hydroxide is formed. It dissolves in nitric or sulfuric acid. Thallium is widely distributed in nature, but the only minerals rich in the element are crooksite and lorandite. It is also found in copper pyrites and lead and zinc ores; it is recovered during the processing of these ores, the method of recovery depending on the source. Thallium is used in low-melting alloys with other metals and in compounds. Both the metal and its compounds are very poisonous. The sulfide is used as a rat poison and the sulfate as an insecticide. The oxide is used in special highly refractive optical glass. Several compounds are used in photoelectric cells and infrared detectors. Discovered spectroscopically in 1861 by Sir William Crookes, it was isolated independently by Crookes and C. A. Lamy in 1862.

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thallium

thallium (symbol Tl) Shiny, metallic element of group III of the periodic table. Soft and malleable, it is obtained as a by-product of processing zinc or lead sulphide ores. It is used in electronic components, infrared detectors and optical and infrared glasses. Thallium is a toxic compound, and thallium sulphide is used as a rodent and ant poison. It was discovered in 1861 by English chemist and physicist Sir William Crookes. Properties: at.no. 81; r.a.m. 204.37; r.d. 11.85; m.p. 303.5°C (578.3°F); b.p. 1457°C (2655°F); most common isotope Tl205 (70.5%).

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thallium

thal·li·um / ˈ[unvoicedth]alēəm/ • n. the chemical element of atomic number 81, a soft silvery-white metal that occurs naturally in small amounts in pyrite, sphalerite, and other ores. Its compounds are very poisonous. (Symbol: Tl)

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thallium

thallium (chem.) metallic element. XIX. f. L. thallus green shoot — Gr. thallós; see -IUM.
So named from the green line distingiushing its spectrum.

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thallium

thallium •columbium •erbium, terbium, ytterbium •scandium • compendium •palladium, radium, stadium, vanadium •medium, tedium •cryptosporidium, cymbidium, idiom, iridium, rubidium •indium •exordium, Gordium, rutherfordium •odeum, odium, plasmodium, podium, sodium •allium, gallium, pallium, thallium, valium •berkelium, epithelium, helium, nobelium, Sealyham •beryllium, cilium, psyllium, trillium •linoleum, petroleum •thulium • cadmium •epithalamium, prothalamium •gelsemium, premium •chromium, encomium •holmium • fermium •biennium, millennium •cranium, geranium, germanium, Herculaneum, titanium, uranium •helenium, proscenium, rhenium, ruthenium, selenium •actinium, aluminium, condominium, delphinium •ammonium, euphonium, harmonium, pandemonium, pelargonium, plutonium, polonium, zirconium •neptunium •europium, opium •aquarium, armamentarium, barium, caldarium, cinerarium, columbarium, dolphinarium, frigidarium, herbarium, honorarium, planetarium, rosarium, sanitarium, solarium, sudarium, tepidarium, terrarium, vivarium •atrium •delirium, Miriam •equilibrium, Librium •yttrium •auditorium, ciborium, conservatorium, crematorium, emporium, moratorium, sanatorium, scriptorium, sudatorium, vomitorium •opprobrium •cerium, imperium, magisterium •curium, tellurium •potassium • axiom • calcium •francium • lawrencium • americium •Latium, solatium •lutetium, technetium •Byzantium • strontium • consortium •protium • promethium • lithium •alluvium, effluvium •requiem • colloquium • gymnasium •caesium (US cesium), magnesium, trapezium •Elysium • symposium

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