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Ruthenium (revised)

RUTHENIUM (REVISED)

Note: This article, originally published in 1998, was updated in 2006 for the eBook edition.

Overview

Ruthenium belongs in the platinum group of metals. The elements in this group are named after the best known member of the group, platinum. The group is found in the middle of the periodic table, in Groups 8, 9, and 10, and Rows 5 and 6. The periodic table is a chart that shows how chemical elements are related to one another. The platinum metals tend to be somewhat rare and valuable. They are also called precious metals. The platinum metals also tend to have bright, shiny surfaces and high melting points, boiling points, and densities.

Credit for the discovery of ruthenium is often given to Polish chemist Jedrzej Sniadecki (1768-1838). Sniadecki announced the discovery of the element in 1808. He suggested the name vestium for the element, after the asteroid Vesta. Other chemists were not able to confirm Sniadecki's work, however. As a result, the element was rediscovered twice more in later years.

The primary uses of ruthenium are in alloys and as catalysts for industrial processes.

SYMBOL
Ru

ATOMIC NUMBER
44

ATOMIC MASS
101.07

FAMILY
Group 8 (VIIIB)
Transition metal;
platinum group

PRONUNCIATION
roo-THEE-nee-um

Discovery and naming

Sniadecki discovered element 44 in 1808 while working with platinum ores from South America. After he published his results, other chemists tried to find the element as well. They were unsuccessful. Sniadecki became discouraged, dropped his claims of discovery, and did no further research on the element.

About twenty years later, the discovery of element 44 was announced again. This time, the discoverer was Russian chemist Gottfried W. Osann. Once more, other chemists could not repeat Osann's results. There was disagreement as to whether the element had been found.

Finally, in 1844, Russian chemist Carl Ernst Claus (also known in Russian as Karl Karlovich Klaus; 1796-1864) gave positive proof of a new element in platinum ores. Many authorities now call Claus the discoverer of the element. Claus suggested calling the element ruthenium, after the ancient name of Russia, Ruthenia. Osann had suggested that name as well.

Physical properties

Ruthenium is a hard, silvery-white metal with a shiny surface. Its melting point is about 2,300 to 2,450°C (4,200 to 4,400°F) and its boiling point is about 3,900 to 4,150°C (7,100 to 7,500°F). Its density is 12.41 grams per cubic centimeter.

Chemical properties

Ruthenium metal is relatively unreactive. It does not dissolve in most acids or in aqua regia. Aqua regia is a mixture of hydrochloric and nitric acids. It often reacts with materials that do not react with either acid separately. Ruthenium does not react with oxygen at room temperatures either. At higher temperatures, however, it does combine with oxygen.

Occurrence in nature

Ruthenium is one of the rarest elements in the Earth's crust. Its abundance is estimated at about 0.0004 parts per million. This makes it one of six least abundant elements on Earth.

Like other members of the platinum family, ruthenium occurs in platinum ores. It is obtained from those ores and from the mineral osmiridium by purification of the natural material.

Isotopes

Seven isotopes of ruthenium are known. Isotopes are two or more forms of an element. Isotopes differ from each other according to their mass number. The number written to the right of the element's name is the mass number. The mass number represents the number of protons plus neutrons in the nucleus of an atom of the element. The number of protons determines the element, but the number of neutrons in the atom of any one element can vary. Each variation is an isotope.

At least nine radioactive isotopes of ruthenium are also known. A radioactive isotope is one that breaks apart and gives off some form of radiation. Radioactive isotopes are produced when very small particles are fired at atoms. These particles stick in the atoms and make them radioactive.

Ruthenium-106 is used for medical purposes. When ruthenium-106 breaks down, it gives off a form of radiation called beta rays. These beta rays act somewhat like X rays. They attack and kill cancer cells. As an example, ruthenium-106 has been used to treat certain forms of eye cancer.

Extraction

Ruthenium is obtained by separating it from other platinum metals, such as platinum, palladium, and osmium, with which it occurs. These metals are usually obtained as by-products during the refining of nickel metal. They are then separated from each other by a series of chemical reactions.

Uses

One important use of ruthenium is in the manufacture of alloys. An alloy is made by melting and mixing two or more metals. The mixture has properties different from those of the individual metals. Ruthenium adds two properties to an alloy. First, it makes the alloy hard. Second, it makes the alloy resistant to attack by oxygen and other materials.

Ruthenium is most often combined with platinum or palladium in alloys. Electrical contacts, devices for measuring very high and very low temperatures, and medical instruments are often made from ruthenium alloys. Some types of jewelry are also made from ruthenium, though it is very expensive.

"Ruthenium" comes from the ancient name of Russia, Ruthenia.

Ruthenium can also be alloyed with other metals. It is sometimes added to titanium to make that metal more resistant to corrosion (rusting). Only 0.1 percent of ruthenium in titanium makes titanium a hundred times more corrosion resistant.

A second important use of ruthenium is in catalysts. A catalyst is a substance used to speed up or slow down a chemical reaction without undergoing any change itself. Ruthenium catalysts may provide a way of changing light energy into electrical energy. The process is similar to photosynthesis, in which green plants change sunlight into stored chemical energy.

Compounds

No compounds of ruthenium have any important commercial application.

Health effects

Ruthenium tetroxide (RuO4) is very dangerous. Its fumes are irritating to the skin, eyes, and respiratory tract (mouth, throat, and lungs).

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Ruthenium

Ruthenium


melting point: 2,310°C
boiling point: 3,900°C
density: 12.2 g/cm3
most common ions: Ru2+, Ru3+, RuO42, RuO4

Ruthenium was discovered in 1844 in ores extracted from the Ural Mountains in Russia by Karl Klaus, who named it after Ruthenia, the Latin name for Russia. Its abundance in Earth's crust is about 0.0001 ppm. Ruthenium crystallizes in the hexagonal close-packed arrangement, is lustrous, and is silvery in color. It is used primarily to harden platinum and palladium in alloys . It is extracted from platinum metal ore concentrates and isolated as a gray powder or a sponge using chemical techniques. Ruthenium will dissolve in fused KOH to give K2[RuO4]. It will react with F2 to give RuF5, and with Cl2, Br2, or I2 to yield RuX3, where X = Cl, Br, or I. It also combines with the elements As, P, Si, and B at high temperatures to form binary compounds of various stoichiometries, and with air upon heating to yield RuO2. RuO4 (mp 25.5°C, or 77.9°F), a powerful oxidizing agent, is obtained by reaction of ruthenium in acidic solution with oxidizing agents such as MnO4 and has found use as a catalyst in the oxidation of various substrates. In the +2 and +3 oxidation states, ruthenium forms numerous coordination complexes with ligands containing carbon, nitrogen, phosphorus, oxygen, and sulfur donors. It also forms oxo- and ligand-bridged binuclear and trinuclear metal complexes, such as [(NH3)5RuNNRu(NH3)5]4+ and [(NH3)5RuORu(NH3)4ORu(NH3)5]6+ , and dioxo-compounds such as cis- or trans- [Ru(bpy)2(O)2], where bpy is 2,2-bipyridine. In the lower oxidation states, ruthenium together with carbonyl, phosphine, and/or hydrido ligands form alkene, diene, alkyne, and allyl complexes.

see also Palladium; Platinum.

D. Paul Rillema

Bibliography

Cotton, F. Albert, and Wilkinson, Geoffrey (1988). Advanced Inorganic Chemistry, 5th edition. New York: Wiley.

Greenwood, N. N., and Earnshaw, A. (1984). Chemistry of the Elements. New York: Pergamon Press.

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ruthenium

ruthenium (rōōthē´nēəm), metallic chemical element; symbol Ru; at. no. 44; at. wt. 101.07; m.p. about 2,310°C; b.p. about 3,900°C; sp. gr. 12.41 at 20°C; valence commonly +2, +3, +4, +6, or +8. Ruthenium is a hard, lustrous, silver-gray metal with a close-packed hexagonal crystalline structure. It is found directly above osmium in Group 8 of the periodic table. Below about 100°C ruthenium is insoluble in acids, including aqua regia, but reacts violently if potassium chlorate is added. It reacts with the halogens and with fused alkali hydroxides. When heated above 800°C it oxidizes, but it does not react with air at room temperature. It forms compounds with silicon and sulfur. Its compounds resemble those of osmium. Ruthenium is found in nature with other metals of the so-called platinum group in river sands, in minerals such as laurite (the sulfide) and osmiridium, and in association with certain ores containing platinum, copper, and nickel. It is obtained commercially as a byproduct of the refining of nickel sulfide ores mined near Sudbury, Ont., Canada. Ruthenium metal powder is obtained as the final product of a complex chemical process. It is used as a catalyst in hydrogenation, isomerization, nitrogenation, oxidation, and reforming reactions. The metal is used as a hardener in electrical contact alloys and filaments, in jewelry, in pen nibs, and in instrument pivots. It is usually alloyed with other metals. It is a very good hardener for palladium and platinum, and vastly improves the corrosion resistance of titanium when added in small amounts. It is also used in alloys with cobalt, molybdenum, nickel, tungsten, and other metals. Ruthenium compounds are used to color ceramics and glass. Ruthenium was discovered in 1827 in an impure form by G. W. Osann in residues of crude platinum ores from the Ural Mts. of Russia. Pure ruthenium was first prepared by K. K. Klaus in 1845; he showed that Osann's sample contained at least one other metal.

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ruthenium

ruthenium (symbol Ru) Silver-white metallic element, one of the transition elements. It was discovered in 1844 by Russian chemist Karl Klaus (1796–1864). Ruthenium is found in platinum ores. It is used as a catalyst to harden other metals, and its alloys are used in electrical contacts and to colour glass and ceramics. Properties: at.no. 44; r.a.m. 101.07; r.d. 12.41; m.p. 2310°C (4190°F); b.p. 3900°C (7052°F); most common isotope Ru102 (31.61%).

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ruthenium

ru·the·ni·um / roōˈ[unvoicedth]ēnēəm/ • n. the chemical element of atomic number 44, a hard silvery-white metal of the transition series. (Symbol: Ru)

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ruthenium

ruthenium (chem.) metal of the platinum group, discovered 1828, being first observed in platinum ores in the Ural mountains XIX. f. medL. Ruthenia Russia; see -IUM.

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ruthenium

ruthenium •columbium •erbium, terbium, ytterbium •scandium • compendium •palladium, radium, stadium, vanadium •medium, tedium •cryptosporidium, cymbidium, idiom, iridium, rubidium •indium •exordium, Gordium, rutherfordium •odeum, odium, plasmodium, podium, sodium •allium, gallium, pallium, thallium, valium •berkelium, epithelium, helium, nobelium, Sealyham •beryllium, cilium, psyllium, trillium •linoleum, petroleum •thulium • cadmium •epithalamium, prothalamium •gelsemium, premium •chromium, encomium •holmium • fermium •biennium, millennium •cranium, geranium, germanium, Herculaneum, titanium, uranium •helenium, proscenium, rhenium, ruthenium, selenium •actinium, aluminium, condominium, delphinium •ammonium, euphonium, harmonium, pandemonium, pelargonium, plutonium, polonium, zirconium •neptunium •europium, opium •aquarium, armamentarium, barium, caldarium, cinerarium, columbarium, dolphinarium, frigidarium, herbarium, honorarium, planetarium, rosarium, sanitarium, solarium, sudarium, tepidarium, terrarium, vivarium •atrium •delirium, Miriam •equilibrium, Librium •yttrium •auditorium, ciborium, conservatorium, crematorium, emporium, moratorium, sanatorium, scriptorium, sudatorium, vomitorium •opprobrium •cerium, imperium, magisterium •curium, tellurium •potassium • axiom • calcium •francium • lawrencium • americium •Latium, solatium •lutetium, technetium •Byzantium • strontium • consortium •protium • promethium • lithium •alluvium, effluvium •requiem • colloquium • gymnasium •caesium (US cesium), magnesium, trapezium •Elysium • symposium

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