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Niobium (revised)

NIOBIUM (REVISED)

Note: This article, originally published in 1998, was updated in 2006 for the eBook edition.

Overview

Niobium is a transition metal in Group 5 (VB) of the periodic table. The periodic table is a chart that shows how chemical elements relate to one another.

Niobium has a very interesting history. It was discovered by English chemist Charles Hatchett (1765-1847) in 1801. Hatchett found the element in a stone sent from North America. He named the element columbium. For years, scientists argued about the correct name for the element. Some still call the element columbium, although the official name is now niobium.

Niobium is used in many alloys. An alloy is made by melting and mixing two or more metals. The mixture has properties different from those of the individual metals. Niobium alloys are used in items that come into contact with the human body, such as rings for pierced ears, nose, and other body parts. Niobium is used in this kind of jewelry because it does not cause allergies or other problems.

SYMBOL
Nb

ATOMIC NUMBER
41

ATOMIC MASS
92.9064

FAMILY
Group 5 (VB)
Transition metal

PRONUNCIATION
nye-OH-bee-um

Discovery and naming

Historians today give credit for the discovery of niobium to Hatchett. The English chemist found the element in a "very heavy black stone, with golden streaks" that he found in the British Museum. The stone had been sent to England from the United States by John Winthrop (1681-1747). Winthrop was a member of the British Royal Society, one of the most important scientific societies in the world. (He was also the grandson of the first governor of Connecticut and the great-grandson of the first governor of Massachusetts.) The rock had sat in the British Museum for nearly 70 years before anyone decided to analyze it. When Hatchett did so in 1801, he discovered a new element. He named it columbiun, after the mineral columbite in which it is often found.

Not everyone agreed with Hatchett's discovery at first. Some chemists were convinced that columbium was identical to the element tantalum, which had been discovered earlier. The confusion is easy to understand. The two elements have very similar properties and are difficult to separate. Finally, in 1844, German chemist Heinrich Rose (1795-1864) showed that tantalum and columbium really were different from each other. Rose then suggested the name niobium for the new element. The name comes from Greek mythology. Niobe is the daughter of the god Tantalus, from whom the name tantalum comes.

Scientists debated for nearly a century over which name to use. In 1949, niobium was officially adopted. However, many metallurgists (scientists who work with metals) still use the name columbium for the element.

Physical properties

Niobium is a shiny gray metal with a melting point of 2,468°C (4,474°F) and a boiling point of 4,927°C (8,901°F). Its density is 8.57 grams per cubic centimeter.

Chemical properties

Niobium metal is resistant to attack by most common chemicals. It does not combine with oxygen or most other active elements except at high temperatures. It does not react with most strong acids unless they are hot and concentrated.

Occurrence in nature

Niobium occurs primarily in two minerals, columbite and pyrochlore. The original name columbium was taken from the first of these minerals. Niobium always occurs with tantalum in these minerals. Separating the two elements is always the most difficult step in their preparation.

Columbite and pyrochlore are not mined in the United States. These two minerals are imported primarily from Brazil and Canada.

Scientists believe that niobium's abundance in the Earth's crust is about 20 parts per million. That makes it about as abundant as nitrogen and lithium, and slightly more abundant than lead.

Isotopes

Only one naturally occurring isotope of niobium exists, niobium-93. Isotopes are two or more forms of an element. Isotopes differ from each other according to their mass number. The number written to the right of the element's name is the mass number. The mass number represents the number of protons plus neutrons in the nucleus of an atom of the element. The number of protons determines the element, but the number of neutrons in the atom of any one element can vary. Each variation is an isotope.

At least a dozen radioactive isotopes of niobium are known also. A radioactive isotope is one that breaks apart and gives off some form of radiation. Radioactive isotopes are produced when very small particles are fired at atoms. These particles stick in the atoms and make them radioactive.

None of the radioactive isotopes of niobium have any practical application.

Extraction

The first step in preparing niobium metal is to separate its compounds from tantalum in an ore. The niobium compounds are then heated in air to change them to niobium oxide (Nb2O5). This is then heated with charcoal (carbon) to produce free metal:

Uses

Niobium is used primarily in making alloys. For example, the addition of niobium to steel greatly increases its strength. One use of such steel is in the construction of nuclear reactors.

Nuclear reactors are devices in which the energy of nuclear reactions is converted to electricity. Niobium steel is used because it keeps its strength at the very high temperatures produced there.

The demand for niobium steel has increased. One reason is its increased use in airplanes and space vehicles. Some skateboards also include niobium steel components.

Another popular use of niobium alloys is in the making of jewelry. These alloys are lightweight and hypoallergenic. The term hypoallergenic means that they do not cause skin reactions. People who wear pierced earrings or similar forms of jewelry will not develop skin problems from niobium alloy jewelry.

Niobium alloys are also used in the construction of superconducting magnets. A superconducting material is one that has no resistance to an electric current. Once an electric current begins to flow in such a material, it continues to flow practically forever.

The most powerful magnets in the world are those made with superconducting materials. In 1997, a new record was set for superconducting magnets at the Lawrence Berkeley Laboratory in Berkeley, California. A magnet made with an alloy of niobium and tin proved to be three times as strong as the best magnet previously known.

Compounds

Niobium diselenide (NbSe2) is sometimes used as a lubricant at high temperatures. It does not break down at temperatures up to about 1300°C. Niobium silicide (NbSi2) is used as a refractory material. A refractory material is one that can withstand very high temperatures.

Niobium alloys are used in jewelry because they are lightweight and hypoallergenic (won't cause skin reactions).

Health effects

Neither niobium nor its compounds are known to pose serious health effects for humans and animals.

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Niobium

Niobium


melting point: 2,475°C ±10°C
boiling point: 4,740°C
density: 8.57g/cm
3 at room temperature
most common ions: Nb
3+

Niobium metal is typically gray or dull silver in color. It is one of the refractory metals along with tantalum, tungsten, molybdenum, and rhenium, due to its very high melting point. It is estimated that niobium has a natural occurrence in Earth's crust of approximately 20 parts per million (ppm). The largest niobium-containing mineral reserves are located in Brazil and Canada.

English chemist Charles Hatchett originally discovered niobium in 1801 while examining an ore sample obtained in Connecticut. Since the ore sample came from the United States, he named the unknown material columbium (at the time, Columbia was another name for America). In the 1840s German chemist Heinrich Rose rediscovered the element and named it niobium. Chemically, niobium and the element tantalum are very similar, so niobium was named for Niobe, a daughter of Tantulus (root name for the element tantalum) in ancient mythology. It was not until 1950, at a meeting of the International Union of Pure and Applied Chemistry, that it was finally settled that the element would be called niobium. Many metallurgists and engineers, especially in the United States, still refer to the element as columbium.

Pure niobium has relatively poor mechanical properties and readily oxidizes in air to niobium pentoxide (Nb2O5) at elevated temperatures. Various niobium-containing alloys such as Nb-1Zr and C-103 have been successfully used in specific liquid-metal based nuclear applications and in the fabrication of various rocket components.

see also Inorganic Chemistry.

Daniel P. Kramer

Bibliography

American Society for Metals (1998). Metals Handbook, Vol. 2: Properties and Selection: Nonferrous Alloys and Pure Metals. Metals Park, OH: American Society for Metals.

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niobium

niobium (nīō´bēəm), metallic chemical element; symbol Nb; at. no. 41; at. wt. 92.90638; m.p. about 2,468°C; b.p. 4,742°C; sp. gr. 8.57 at 20°C; valence +2, +3, +4, or +5. Niobium is a rare, soft, malleable, ductile, gray-white metal with a body-centered cubic crystalline structure. In its physical and chemical properties it resembles tantalum, the element below it in Group 5 of the periodic table. At normal temperatures it is insoluble in solutions of most acids or alkalies. It reacts readily at high temperatures with oxygen, carbon, the halogens, nitrogen, and sulfur; it must be placed in a protective atmosphere when processed. It forms four oxides; the pentoxide, Nb2O5, is the basis of a series of salts called niobates. Niobium is important in the production of high-temperature-resistant alloys and special stainless steels; large amounts of niobium have been used in the U.S. space program. Niobium carbide is used in cutting tools. The name niobium was officially adopted by the International Union of Pure and Applied Chemistry (IUPAC) in 1949; the name columbium (symbol Cb) was used for the element in some countries prior to that and continued to be used by many metallurgists and commercial producers of the metal. Niobium is widely distributed in nature; it is about one and a half times as abundant as lead. It occurs in the minerals columbite and tantalite, together with tantalum. Separating niobium and tantalum is difficult. The element was discovered in 1801 by Charles Hatchett and first isolated in 1864 by C. W. Blomstrand.

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niobium

niobium (symbol Nb) Shiny grey-white metallic element of the second transition series. Its chief ore is pyrochlore. Soft and ductile, niobium is used in special stainless steels and in alloys for rockets and jet engines. It was discovered in 1801 by the English chemist Charles Hatchett (1765–1847) who named it columbium; the name was changed to niobium in 1844. Properties: at.no. 41; r.a.m. 92.9064; r.d. 8.57; m.p. 2468°C (4474°F); b.p. 4742°C (8568°F); most common isotope Nb93 (100%).

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niobium

ni·o·bi·um / nīˈōbēəm/ • n. the chemical element of atomic number 41, a silver-gray metal of the transition series, used in superconducting alloys. (Symbol: Nb)

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