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Lawrencium

Lawrencium


melting point: Unknown
boiling point: Unknown
density: Unknown
most common ions: Lw
3+

Lawrencium is a synthetic radioactive element and the last member of the actinide series. It was discovered in 1961 by Albert Ghiorso and his coworkers, who bombarded a target of isotopes of californium (249Cf252Cf) with boron projectiles (either 10B or 11B) using the Heavy Ion Linear Accelerator (HILAC) at the University of California, Berkeley, producing isotopes of unknown element 103 of masses 257 and 258. The atoms recoiling after the nuclear reaction were caught on metalized Mylar tape, which was then moved past a series of α -detectors, and the decays of a few new atoms of element 103 (257103 and 258103), having half-lives of seconds or less, were recorded. The element is named after Ernest O. Lawrence, the inventor of the cyclotron and the founder of the Berkeley Radiation Laboratory. "Lawrencium" was suggested and accepted by the International Union of Pure and Applied Chemistry, but the originally suggested symbol of Lw was changed to Lr. In 1965 Evgeni D. Donets at the Joint Institutes of Nuclear Research in Dubna, Russia, using a double-recoil technique, confirmed the atomic number of element 103 by linking its decay, via either electron capture followed by α -decay, or α -decay followed by electron capture, to its known granddaughter, an isotope of fermium (252Fm).

All Lr isotopes are radioactive, decaying by α -particle emission, electron capture, and/or spontaneous fission , and have half-lives ranging from a few tenths of a second for the isotope of mass 252, the lightest isotope, to 3.6 hours for the isotope of mass 262, the heaviest. The ground state electronic configuration of the gaseous Lr atom is believed to be [Rn]5f146d7s2, by analogy to its lanthanide homologue, lutetium (element 71). Its most stable ion in aqueous solution is Lr3+, and attempts to reduce it to Lr2+ or Lr1+ in aqueous solution have been unsuccessful.

see also Actinium; Berkelium; Einsteinium; Fermium; Lawrence, Ernest; Mendelevium; Neptunium; Nobelium; Plutonium; Protactinium; Radioactivity; Rutherfordium; Thorium; Transmutation; Uranium.

Darleane C. Hoffman

Bibliography

Ghiorso, A.; Sikkeland, A.; Larsh, A. E.; and Latimer, R. M. (1961). "New Element, Lawrencium, Atomic Number 103." Physical Review Letters 6:473475.

Hoffman, Darleane C.; Ghiorso, Albert; and Seaborg, Glenn T. (2000). The Transuranium People: The Inside Story. Singapore: World Scientific Publishing.

Hoffman, Darleane C., and Lee, Diana M. (1999). "Chemistry of the Heaviest ElementsOne Atom at a Time." Journal of Chemical Education 76(3):331347.

Seaborg, Glenn T., and Loveland, Walter D. (1990). The Elements Beyond Uranium. New York: Wiley.

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lawrencium

lawrencium, artificially produced radioactive chemical element; symbol Lr; at. no. 103; mass number of most stable isotope 262; m.p. about 1,627°C; b.p. and sp. gr. unknown; valence +3. Lawrencium is the last member of the actinide series of elements found in Group 3 of the periodic table. Lawrencium was the 11th transuranium element to be discovered. It was first prepared in 1961 (after three years of preliminary work) by Albert Ghiorso, Torbjørn Sikkeland, Almon E. Larsh, and Robert M. Latimer at the Univ. of California at Berkeley; a sample of californium isotopes was bombarded with a beam of boron nuclei from the heavy-ion linear accelerator. The resulting isotope, lawrencium-258, had a half-life of 4.2 sec. The element was named for Ernest O. Lawrence, the inventor of the cyclotron. The symbol Lw was used at first, but it was changed to Lr in 1963. Ten isotopes, all of which are radioactive, are known; the most stable, lawrencium-262, has a half-life of 3.6 hours.

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lawrencium

lawrencium (symbol Lr) Radioactive metallic element, one of the actinide series. It was first made in 1961 at the University of California at Berkeley by bombarding californium with boron nuclei. It is named after the US physicist Ernest Lawrence who established the laboratory where it was produced. Properties: at.no. 103; r.a.m. 262; most stable isotope Lr256 (half-life 27 seconds).

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lawrencium

law·ren·ci·um / lôˈrensēəm/ • n. the chemical element of atomic number 103, a radioactive metal of the actinide series. Lawrencium does not occur naturally and was first made by bombarding californium with boron nuclei. (Symbol: Lr)

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lawrencium

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