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Erbium (revised)

ERBIUM (REVISED)

Note: This article, originally published in 1998, was updated in 2006 for the eBook edition.

Overview

Erbium is one of 14 rare earth elements with atomic numbers 58 through 71 in Row 6 of the periodic table. The periodic table is a chart that shows how chemical elements are related to each other. Rare earth is a misleading category because these elements are not especially rare in the Earth's crust. Rare earth metals were rarely used because the 15 elements were difficult to separate from each other.

Today, the rare earth elements can be separated easily, and they can be bought at a reasonable cost. Two common uses of erbium today are in lasers and special kinds of optical fibers. Optical fibers are glass-like materials used to carry telephone messages.

The correct chemical name for the rare earth elements is the lanthanides, which comes from the first element in the sixth row of the periodic table, lanthanum.

SYMBOL
Er

ATOMIC NUMBER
68

ATOMIC MASS
167.26

FAMILY
Lanthanide
rare earth metal)

PRONUNCIATION
ER-bee-um

Discovery and naming

The discovery of the lanthanides began outside the small town of Ytterby, Sweden, in 1787. A Swedish army officer named Carl Axel Arrhenius (1757-1824) found an unusual kind of black mineral in a rock quarry. That mineral was later given the name gadolinite.

Gadolinite was full of surprises. As chemists analyzed the new mineral, they found nine new elements! No mineral had ever produced such a wealth of new information.

One of the first scientists to work on gadolinite was Swedish chemist Carl Gustav Mosander (1797-1858). Mosander was able to separate gadolinite into three parts: yttria, terbia, and erbia. Later, the parts he called erbia and terbia had their names switched.

In 1843, Mosander found that erbia was an entirely new substance. It consisted of a new element combined with oxygen. He called the new element erbium. The name came from the town near which it had been found, Ytterby. Interestingly, three other elements were also named after this small town: terbium, yttrium, and ytterbium.

Although Mosander is given credit for discovering erbium, he saw only erbia, the compound of erbium and oxygen. The erbia he saw was not even pure, but was mixed with other rare earth element oxides.

The first pure samples of erbium oxide (erbia) were produced in 1905 by French chemist George Urbain (1872-1938) and American chemist Charles James (1880-1928). It was not until 1934 that the first pure erbium metal was produced.

Physical properties

Erbium metal has a bright, shiny surface, much like metallic silver. It is soft and malleable. Malleable means capable of being hammered into thin sheets. It has a melting point of 1,522°C (2,772°F) and a boiling point of about C (4,500°F). Its density is 9.16 grams per cubic centimeter.

Chemical properties

Erbium is fairly stable in air. It does not react with oxygen as quickly as most other lanthanides. Erbium compounds tend to be pink or red. They are sometimes used to color glass and ceramics.

Occurrence in nature

Erbium ranks about number 42 in abundance in the Earth's crust. It is more common than bromine, uranium, tin, silver and mercury. It occurs in many different rare earth minerals, naturally occurring lanthanide mixtures. Some common sources of erbium are xenotime, fergusonite, gadolinite, and euxenite.

Isotopes

Six naturally occurring isotopes of erbium are known. Isotopes are two or more forms of an element. Isotopes differ from each other according to their mass number. The number written to the right of the element's name is the mass number. The mass number represents the number of protons plus neutrons in the nucleus of an atom of the element. The number of protons determines the element, but the number of neutrons in the atom of any one element can vary. Each variation is an isotope. The isotopes of erbium are erbium-162, erbium-164, erbium-166, erbium-167, erbium-168, and erbium-170.

Four elements are named after the small town of Ytterby, Sweden: erbium, terbium, yttrium, and ytterbium.

At least thirteen radioactive isotopes of erbium are known also. A radioactive isotope is one that breaks apart and gives off some form of radiation. Radioactive isotopes are produced when very small particles, such as protons or neutrons, are fired at atoms. These particles stick in the atoms and make them radioactive. None of the radioactive isotopes of erbium has any important uses.

Extraction

Erbium in a mineral is first converted into erbium fluoride (ErF3). Pure erbium is then obtained by passing an electric current through erbium fluoride:

Uses

Erbium metal has few uses. It is sometimes alloyed with vanadium metal. An alloy is made by melting and mixing two or more metals. The mixture has properties different than those of the individual metals. A vanadium-erbium alloy is easier to work with than pure vanadium metal.

The most important uses of erbium are in lasers and optical fibers. A laser is a device for making very intense light of one specific color. The light is intensified and focused into a narrow beam that can cut through metal. Lasers now have many practical applications.

Erbium Lasers are used to treat skin problems. The lasers have been used to remove wrinkles and scars. They work better than other kinds of lasers because they do not penetrate the skin very deeply. They also produce little heat and cause few side effects.

An optical fiber is a thin thread-like piece of glass or plastic through which light travels easily. Light carries messages along the fiber, much as electricity carries messages along copper telephone wires. Erbium optical fibers carry messages in long distance communication systems and in military applications. Telephone providers are converting copper phone lines to optical fibers for improved clarity. Optical fibers carry far more information than the old bundles of copper.

Compounds

There are no commercially important erbium compounds.

Optical fibers and high-definition television

O ptical fibers have proven to be an ideal method of transmitting high-definition television (HDTV) signals. Many people predict HDTV will be the next popular technology item for consumers. The signals in HDTVs contain twice as much "information" as conventional TVs do. These signals result in a much clearer picture. However, the picture on an HDTV looks just like a regular TV unless optical fibers are used. With optical fibers, the HDTV signal can transmit a nearly perfect image.

Erbium optical fibers carry messages in long distance communication systems and in military applications.

Health effects

Almost nothing is known about the health effects of erbium on plants, humans, or animals. In such cases, it is usually safest to assume that the element is toxic.

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Erbium

Erbium


melting point: 1,529°C
boiling point: 2,510°C
density: 9.07 g cm 3
most common ion: Er 3+

Erbium is a chemical element. Its ground state electronic configuration is [Xe]4f12 6s2. Natural erbium is a mixture of six stable isotopes . Monazite and xenotime are the principal erbium ores, in which erbium occurs together with other members of the rare earth elements , or the lanthanides . It can be separated from the other rare earths by ion exchange or solvent extraction techniques. The discovery of erbium is attributed to Carl G. Mosander(1842). Its name is derived from Ytterby, a small town in Sweden, where the first rare earth mineral (gadolinite) had been found. The elements ytterbium, yttrium, and terbium have also been named after the town of Ytterby.

Pure erbium metal was first prepared in 1934. It is a silver-white, malleable, and ductile metal. The metal is not oxidized as rapidly as other rare earth metals when exposed to air. Erbium chemistry is dominated by the trivalent erbium (III) ion, Er3+. Its chemical behavior resembles that of yttrium and the heavy rare earth elements. The ground state electronic configuration of Er3+ is [Xe]4f13. Because of erbium's narrow absorption band in the green region of visible light (at wavelengths of ca. 530 nanometers, or 2.09 × 105 inches), erbium (III) salts are pink. Due to the high chemical stability of trivalent erbium, erbium (III) oxide is used to color glassware pink. Erbium is of importance to the technology of optical amplification in glass fibers. Erbium-doped crystals can be used to generate laser beams having wavelengths in the vicinity of 2,900 nanometers (1.14 ×104 inches). Such lasers are being used in laser surgery. The laser beam is strongly absorbed by water, so that the energy in hitting its target is confined to the surface layer of tissue. Phosphors based on erbium can convert infrared light to visible light (upconversion).

see also Cerium; Dysprosium; Europium; Gadolinium; Holmium; Lanthanides; Lanthanum; Lutetium; Neodymium; Praseodymium; Promethium; Samarium; Terbium; Ytterbium.

Koen Binnemans

Bibliography

Cotton, Simon (1991). Lanthanides and Actinides. New York: Oxford University Press.

Kaltsoyannis, Nikolas, and Scott, Peter (1999). The f Elements. New York: Oxford University Press.

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erbium

erbium (ûr´bēəm) [from Ytterby, a town in Sweden], metallic chemical element; symbol Er; at. no. 68; at. wt. 167.259; m.p. 1,529°C; b.p. 2,863°C; sp. gr. 9.05 at 25°C; valence +3. Erbium is a soft, malleable, lustrous, silvery metal. It is a member of the lanthanide series in Group 3 of the periodic table. With other rare earths its oxide occurs in the mineral gadolinite, found in Sweden. Natural erbium is a mixture of 6 stable isotopes; in addition, 10 radioactive isotopes are known. Erbium does not oxidize in air as rapidly as some of the other rare-earth metals. Erbia is a rose-colored oxide of erbium; it has been used to a very limited extent in glazes and glass as a coloring agent. The discovery of erbium is generally credited to Carl G. Mosander, although he did not succeed in isolating the element. In 1843 he separated from gadolinite three oxide fractions that he called yttria, erbia, and terbia. Later, what he had called terbia became known as erbia and was shown to contain five distinct rare earths, now called erbia, scandia, holmia, thulia, and ytterbia. Fairly pure erbium oxide was first isolated in 1905; fairly pure erbium was isolated in 1934.

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erbium

erbium (symbol Er) Silvery, metallic element of the lanthanide series. There are six isotopes naturally occurring, and the chief ores are monazite and bastnaesite. Nine radioactive isotopes have been identified. Soft and malleable, erbium is used in some specialized alloys, and erbium oxide is used as a pink colourant for glass. Properties: at.no. 68; r.a.m. 167.26; m.p. 1522°C (2772°F); r.d. 9.045; b.p. 2863°C (5185°F); most common isotope Er166 (33.41%).

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erbium

er·bi·um / ˈərbēəm/ • n. the chemical element of atomic number 68, a soft, silvery-white metal of the lanthanide series. (Symbol: Er)

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erbium

erbium •columbium •erbium, terbium, ytterbium •scandium • compendium •palladium, radium, stadium, vanadium •medium, tedium •cryptosporidium, cymbidium, idiom, iridium, rubidium •indium •exordium, Gordium, rutherfordium •odeum, odium, plasmodium, podium, sodium •allium, gallium, pallium, thallium, valium •berkelium, epithelium, helium, nobelium, Sealyham •beryllium, cilium, psyllium, trillium •linoleum, petroleum •thulium • cadmium •epithalamium, prothalamium •gelsemium, premium •chromium, encomium •holmium • fermium •biennium, millennium •cranium, geranium, germanium, Herculaneum, titanium, uranium •helenium, proscenium, rhenium, ruthenium, selenium •actinium, aluminium, condominium, delphinium •ammonium, euphonium, harmonium, pandemonium, pelargonium, plutonium, polonium, zirconium •neptunium •europium, opium •aquarium, armamentarium, barium, caldarium, cinerarium, columbarium, dolphinarium, frigidarium, herbarium, honorarium, planetarium, rosarium, sanitarium, solarium, sudarium, tepidarium, terrarium, vivarium •atrium •delirium, Miriam •equilibrium, Librium •yttrium •auditorium, ciborium, conservatorium, crematorium, emporium, moratorium, sanatorium, scriptorium, sudatorium, vomitorium •opprobrium •cerium, imperium, magisterium •curium, tellurium •potassium • axiom • calcium •francium • lawrencium • americium •Latium, solatium •lutetium, technetium •Byzantium • strontium • consortium •protium • promethium • lithium •alluvium, effluvium •requiem • colloquium • gymnasium •caesium (US cesium), magnesium, trapezium •Elysium • symposium

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