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Cesium (revised)

CESIUM (REVISED)

Note: This article, originally published in 1998, was updated in 2006 for the eBook edition.

Overview

Cesium is a member of the alkali family, which consists of elements in Group 1 (IA) of the periodic table. The periodic table is a chart that shows how chemical elements are related to each other. The alkalis include lithium, sodium, potassium, rubidium, and francium. Cesium is considered the most active metal. Although in theory francium is more active than cesium, francium is too rare to have any commercial uses.

Cesium was discovered in 1861 by German chemists Robert Bunsen (1811-99) and Gustav Kirchhoff (1824-87). They found the element using a method of analysis they had just invented: spectroscopy. Spectroscopy is the process of analyzing light produced when an element is heated. The light produced is different for every element. The spectrum (plural: spectra) of an element consists of a series of colored lines.

SYMBOL
Cs

ATOMIC NUMBER
55

ATOMIC MASS
132.9054

FAMILY
Group 1 (IA)
Alkali metal

>

PRONUNCIATION
SEE-zee-um

Cesium is not a common element, and it has few commercial uses. One of its radioactive isotopes, cesium-137, is widely used in a variety of medical and industrial applications.

Discovery and naming

The invention of spectroscopy gave chemists a powerful new tool. In many cases, the amount of an element present in a sample is too small to see. But the element is much easier to detect by spectroscopy. When the substance is heated, the hidden elements give off characteristic spectral lines. Using spectroscopy, a chemist can identify the elements by these distinctive lines.

Such was the case with the discovery of cesium. In 1859, Bunsen and Kirchhoff were studying a sample of mineral water taken from a spring. They saw spectral lines for sodium, potassium, lithium, calcium, and strontium. These elements were already well known.

After Bunsen and Kirchhoff removed all these elements from their sample, they were surprised to find two beautiful blue lines in the spectrum of the "empty" spring water. The water contained an unknown element. Bunsen suggested calling the element cesium, from the Latin word caesius for "sky blue." For many years, the name was also spelled caesium.

Physical properties

Cesium is a silvery-white, shiny metal that is very soft and ductile. Ductile means capable of being drawn into thin wires. Its melting point is 28.5°C (83.3°F). It melts easily in the heat of one's hand, but should never be handled that way! Cesium's boiling point is 705°C (1,300°F), and its density is 1.90 grams per cubic centimeter.

Chemical properties

Cesium is a very reactive metal. It combines quickly with oxygen in the air and reacts violently with water. In the reaction with water, hydrogen gas is released. Hydrogen gas ignites immediately as a result of the heat given off by the reaction. Cesium must be stored under kerosene or a mineral oil to protect it from reacting with oxygen and water vapor in the air.

Cesium also reacts vigorously with acids, the halogens, sulfur, and phosphorus.

Occurrence in nature

The abundance of cesium in the Earth's crust has been estimated at about 1 to 3 parts per million. It ranks in the middle of the chemical elements in terms of their abundance in the earth.

Cesium occurs in small quantities in a number of minerals. It is often found in an ore of lithium called lepidolite. The mineral containing the largest fraction of cesium is pollucite (Cs4Al4Si9O26). This ore is mined in large quantities at Bernic Lake, in the Canadian province of Manitoba. Cesium is also found in small amounts in a mineral of boron called rhodizite.

Isotopes

Only one naturally occurring isotope of cesium is known, cesium-133. Isotopes are two or more forms of an element. Isotopes differ from each other according to their mass number. The number written to the right of the element's name is the mass number. The mass number represents the number of protons plus neutrons in the nucleus of an atom of the element. The number of protons determines the element, but the number of neutrons in the atom of any one element can vary. Each variation is an isotope.

A number of artificial radioactive isotopes of cesium are known also. A radioactive isotope is one that breaks apart and gives off some form of radiation. Radioactive isotopes are produced when very small particles are fired at atoms. These particles stick in the atoms and make them radioactive.

One radioactive isotope of cesium is of special importance, cesium-137. It is produced in nuclear fission reactions. Nuclear fission is the process in which large atoms break apart. Large amounts of energy and smaller atoms are produced during fission. The smaller atoms are called fission products. Cesium-137 is a very common fission product.

Nuclear fission is used in nuclear power plants. The heat produced by nuclear fission can be converted into electricity. While this process is going on, cesium-137 is being produced as a by-product. That cesium-137 can be collected and used for a number of applications.

As an example, cesium-137 can be used to monitor the flow of oil in a pipeline. In many cases, more than one oil company may use the same pipeline. How does a receiving station know whose oil is coming through the pipeline? One way to solve that problem is to add a little cesium-137 when a new batch of oil is being sent. The cesium-137 gives off radiation. That radiation can be detected easily by holding a detector at the end of the pipeline. When the detector shows the presence of radiation, a new batch of oil has arrived.

This isotope of cesium can also be used to treat some kinds of cancer. One procedure is to fill a hollow steel needle with cesium-137. The needle can then be implanted into a person's body. The cesium-137 gives off radiation inside the body. That radiation kills cancer cells and may help cure the disease.

When a hollow steel needle filled with cesium-137 is implanted into a person's body, the isotopes's radiation can kill cancer cells.

Cesium-137 is often used in scientific research also. For example, cesium tends to stick to particles of sand and gravel. This fact can be used to measure the speed of erosion in an area. Cesium-137 is injected into the ground at some point. Some time later, a detector is used to see how far the isotope has moved. The distance moved tells a scientist how fast soil is being carried away. In other words, it tells how fast erosion is taking place.

Cesium-137 has also been approved for the irradiation of certain foods. The radiation given off by the isotope kills bacteria and other organisms that cause disease. Foods irradiated by this method last longer before beginning to spoil. Wheat, flour, and potatoes are some of the foods that can be preserved by cesium-137 irradiation.

Extraction

Cesium can be obtained in pure form by two methods. In one, calcium metal is combined with fused (melted) cesium chloride:

In the other, an electric current passes through a molten (melted) cesium compound:

Uses

Cesium has a limited number of uses. One is as a getter in bulbs and evacuated tubes. The bulb must be as free from gases as possible to work properly. Small amounts of cesium react with any air left in the bulb. It converts the gas into a solid cesium compound. Cesium is called a getter because it gets gases out of the bulb.

Cesium is also used in photoelectric cells, devices for changing sunlight into electrical energy. When sunlight shines on cesium, it excites or energizes the electrons in cesium atoms. The excited electrons easily flow away, producing an electric current.

An important use of cesium today is in an atomic clock. An atomic clock is the most precise method now available for measuring time. Here is how an atomic clock works:

Cesium-137 is used in atomic clocks, the most precise method for measuring time.

A beam of energy is shined on a very pure sample of cesium-133. The atoms in the cesium are excited by the energy and give off radiation. That radiation vibrates back and forth, the way a violin string vibrates when plucked. Scientists measure the speed of that vibration. The second is officially defined as that speed of vibration multiplied by 9,192,635,770.

Atomic clocks keep very good time. The best of them lose no more than one second in a million years.

Compounds

Cesium compounds have relatively few commercial uses. Cesium bromide is used to make radiation detectors and other measuring devices. Cesium carbonate and cesium fluoride are used to make specialty glasses. Cesium carbonate and cesium chloride are used in the brewing of beers. Cesium compounds are also used in chemical research.

Health effects

Cesium is not regarded as essential to the health of plants or animals, nor does it present a hazard to them.

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cesium

cesium (sē´zēəm) [Lat.,=bluish gray], a metallic chemical element; symbol Cs; at. no. 55; at. wt. 132.90545; m.p. 28.4°C; b.p. 669.3°C; sp. gr. 1.873 at 20°C; valence +1. Cesium is a ductile, soft-as-wax, silver-white metallic element. It is in Group 1 of the periodic table. An alkali metal, it is the most alkaline of all elements. Cesium liquefies in a warm room; mercury and gallium are the only other metals with this property. Chemically cesium resembles rubidium and potassium. It is the most reactive metal and is never found uncombined in nature. Pure cesium can be prepared by electrolysis of fused cesium cyanide in an inert atmosphere; the pure metal must be kept under an inert liquid or gas or in a vacuum to protect it from air and water. Cesium reacts readily with oxygen; it is sometimes used to remove traces of the gas from vacuum tubes and from light bulbs. It reacts with ice; it reacts explosively with water to form cesium hydroxide, the strongest base known. Cesium reacts with the halogens to form a fluoride, chloride, bromide, and iodide. It also forms a sulfate, carbonate, nitrate, and cyanide. The chloride is used in photoelectric cells, in optical instruments, and in increasing the sensitivity of electron tubes. Cesium compounds are used in the production of glass and ceramics and as antishock agents in conjunction with drugs containing arsenic. Cesium-137, a waste product of nuclear reactors, is a radioactive isotope used in the treatment of cancer. Cesium is found in the mineral pollux, or pollucite, which occurs on the island of Elba, in SW Africa, in the United States in Maine and South Dakota, and in Manitoba, Canada. Commercially useful quantities of inexpensive cesium are now available as a byproduct of the production of lithium metal. Minute quantities of cesium chloride are found in mineral springs and in seawater. In 1860, R. W. Bunsen and G. R. Kirchoff discovered the element (the first to be discovered by the use of the spectroscope) and named it for the two bright blue lines characteristic of its spectrum. It was first isolated by Carl Sefferburg in 1881 by electrolysis of its salts.

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Cesium

Cesium


melting point: 28.5°C
boiling point: 671°C
density: 1.873 g/cm3
most common ions: Cs+

Cesium is an alkali metal that reacts explosively with water and melts just above room temperature. The word "cesium" is derived from caesium (Latin for "sky blue"). The name was chosen because of the blue lines observed by Robert Bunsen and Gustav Kirchhoff during their analysis of springwater with a spectroscope in 1860. Currently, cesium metal is generated via thermal decomposition of the azide, electrolysis of molten CsCN, or reduction of molten CsCl with calcium vapor followed by fractional distillation .

Like the other alkali metals, cesium is a soft, silvery metal, but it appears golden if it has been exposed to small amounts of oxygen. It is not found in its metallic state in nature; it is obtained as a byproduct of lithium processing of the mineral lepidolite. Its most significant ore is pollucite, and the world's largest pollucite deposit is found in Bernic Lake, Manitoba, Canada. Cesium's average crustal abundance is about 3 parts per million. Cesium is the most electropositive stable element and will ignite if exposed to air. Cesium burns blue in the flame test.

Both cesium and its compounds find practical uses. Cesium metal can be used as a getter to remove oxygen in phototubes. It is used in atomic clocks that are accurate to within five seconds per every three hundred years. (A second is defined as 9,192,631,770 oscillations of a Cs-133 atom.) CsI and CsF are used in scintillation counters to monitor ionizing radiation. CsCl is used to create density gradients for the separation and purification of DNA via ultracentrifugation.

see also Alkali Metals; Bunsen, Robert.

Nathan J. Barrows

Bibliography

Emsley, John (2001). Nature's Building Blocks: An A-Z Guide to the Elements. New York: Oxford University Press.

Greenwood, Norman N., and Earnshaw, A. (1997). Chemistry of the Elements, 2nd edition. Boston: Butterworth-Heinemann.

Lide, David R., ed. (2000). CRC Handbook of Chemistry & Physics, 81st edition. New York: CRC Press.

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caesium

caesium (symbol Cs) Rare silvery-white metallic element in group I of the periodic table; the most alkaline and electropositive element. Discovered in 1860 by German chemist Robert Bunsen and German physicist Gustav Kirchhoff, caesium is ductile and used commercially in photoelectric cells. The isotope Cs137 is used in cancer treatments. The decay rate of its most common isotope Cs133 is the standard for measuring time. Properties: at.no. 55; r.a.m. 132.9055; r.d. 1.87; m.p. 28.4°C (83.1°F); b.p. 678°C (1252.4°F). See also alkali metals; atomic clock

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cesium

ce·si·um / ˈsēzēəm/ (Brit. cae·si·um) • n. the chemical element of atomic number 55, a soft, silvery, extremely reactive metal. It belongs to the alkali metal group and occurs as a trace element in some rocks and minerals. (Symbol: Cs)

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caesium

caesium (chem.) metallic element. XIX. — modL., n. of L. cæsius bluish-grey; after names in -IUM.

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caesium

caesium •columbium •erbium, terbium, ytterbium •scandium • compendium •palladium, radium, stadium, vanadium •medium, tedium •cryptosporidium, cymbidium, idiom, iridium, rubidium •indium •exordium, Gordium, rutherfordium •odeum, odium, plasmodium, podium, sodium •allium, gallium, pallium, thallium, valium •berkelium, epithelium, helium, nobelium, Sealyham •beryllium, cilium, psyllium, trillium •linoleum, petroleum •thulium • cadmium •epithalamium, prothalamium •gelsemium, premium •chromium, encomium •holmium • fermium •biennium, millennium •cranium, geranium, germanium, Herculaneum, titanium, uranium •helenium, proscenium, rhenium, ruthenium, selenium •actinium, aluminium, condominium, delphinium •ammonium, euphonium, harmonium, pandemonium, pelargonium, plutonium, polonium, zirconium •neptunium •europium, opium •aquarium, armamentarium, barium, caldarium, cinerarium, columbarium, dolphinarium, frigidarium, herbarium, honorarium, planetarium, rosarium, sanitarium, solarium, sudarium, tepidarium, terrarium, vivarium •atrium •delirium, Miriam •equilibrium, Librium •yttrium •auditorium, ciborium, conservatorium, crematorium, emporium, moratorium, sanatorium, scriptorium, sudatorium, vomitorium •opprobrium •cerium, imperium, magisterium •curium, tellurium •potassium • axiom • calcium •francium • lawrencium • americium •Latium, solatium •lutetium, technetium •Byzantium • strontium • consortium •protium • promethium • lithium •alluvium, effluvium •requiem • colloquium • gymnasium •caesium (US cesium), magnesium, trapezium •Elysium • symposium

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cesium

cesium •columbium •erbium, terbium, ytterbium •scandium • compendium •palladium, radium, stadium, vanadium •medium, tedium •cryptosporidium, cymbidium, idiom, iridium, rubidium •indium •exordium, Gordium, rutherfordium •odeum, odium, plasmodium, podium, sodium •allium, gallium, pallium, thallium, valium •berkelium, epithelium, helium, nobelium, Sealyham •beryllium, cilium, psyllium, trillium •linoleum, petroleum •thulium • cadmium •epithalamium, prothalamium •gelsemium, premium •chromium, encomium •holmium • fermium •biennium, millennium •cranium, geranium, germanium, Herculaneum, titanium, uranium •helenium, proscenium, rhenium, ruthenium, selenium •actinium, aluminium, condominium, delphinium •ammonium, euphonium, harmonium, pandemonium, pelargonium, plutonium, polonium, zirconium •neptunium •europium, opium •aquarium, armamentarium, barium, caldarium, cinerarium, columbarium, dolphinarium, frigidarium, herbarium, honorarium, planetarium, rosarium, sanitarium, solarium, sudarium, tepidarium, terrarium, vivarium •atrium •delirium, Miriam •equilibrium, Librium •yttrium •auditorium, ciborium, conservatorium, crematorium, emporium, moratorium, sanatorium, scriptorium, sudatorium, vomitorium •opprobrium •cerium, imperium, magisterium •curium, tellurium •potassium • axiom • calcium •francium • lawrencium • americium •Latium, solatium •lutetium, technetium •Byzantium • strontium • consortium •protium • promethium • lithium •alluvium, effluvium •requiem • colloquium • gymnasium •caesium (US cesium), magnesium, trapezium •Elysium • symposium

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