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synthetic elements

The Columbia Encyclopedia, Sixth Edition | Date: 2008

synthetic elements in chemistry, radioactive elements that were not discovered occurring in nature but as artificially produced isotopes. They are technetium (at. no. 43), which was the first element to be synthesized, promethium (at. no. 61), astatine (at. no. 85), francium (at. no. 87), and the transuranium elements (at. no. 93 and beyond in the periodic table ). Some of these elements have since been shown to exist in minute amounts in nature, usually as short-lived members of natural radioactive decay series (see radioactivity ).

The synthetic elements through at. no. 100 ( fermium ) are created by bombarding a heavy element, such as uranium or plutonium, with neutrons or alpha particles. The synthesis of the transfermium elements (elements with at. no. 101 or greater) is accomplished by the fusion of the nuclei of two lighter elements. Elements 101 through 106 were first produced by fusing the nuclei of slightly lighter elements, such as californium , with those of light elements, such as carbon . Elements 107 through 112 were first produced by fusing the nuclei of medium-weight elements, such as bismuth or lead , with those of other medium-weight elements, such as iron , nickel , or zinc . Element 114 was first produced by fusing the nuclei of plutonium and calcium and subsequently by fusing the nuclei of lead and krypton , as was element 116. Element 115 was produced by bombarding americium with calcium, and element 113 resulted from the radioactive decay of element 115. The claim by Lawrence Berkeley National Laboratory to have created element 118 has been retracted.)

The transfermium elements are produced in very small quantities (one atom at a time), and identification is therefore very difficult because of half-lives ranging from minutes to milliseconds and the need to identify the products by methods other than known chemical separations. This has led to controversy over reported discoveries and over the naming of the elements. It has been predicted that one isotope of element 114—containing 114 protons and 184 neutrons—would be very stable because its nucleus would have a full complement of protons and neutrons. Termed an "island of stability," its half-life might be measured in years. However, none of the three isotopes of element 114 synthesized as yet have as many as 184 neutrons, and their half-lives are still in the millisecond range.

Author not available, SYNTHETIC ELEMENTS., The Columbia Encyclopedia, Sixth Edition 2008

The Columbia Encyclopedia, Sixth Edition. Copyright 2008 Columbia University Press