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allotropy

The Columbia Encyclopedia, Sixth Edition | Date: 2008

allotropy [Gr.,=other form]. A chemical element is said to exhibit allotropy when it occurs in two or more forms in the same physical state; the forms are called allotropes. Allotropes generally differ in physical properties such as color and hardness; they may also differ in molecular structure or chemical activity, but are usually alike in most chemical properties. Diamond and graphite are two allotropes of the element carbon . Ozone is a chemically active triatomic allotrope of the element oxygen . Phosphorus , sulfur , and tin also exhibit allotropy. Many metals have allotropic crystalline forms that are stable at different temperatures. Polymorphism is an analogous phenomenon observed in chemical compounds.

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The Columbia Encyclopedia, Sixth Edition. Copyright 2008 Columbia University Press

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Related entries from encyclopedias, dictionaries, and thesauruses

allotropy
World Encyclopedia allotropy Property of some chemical elements that enables them to exist in two or more distinct physical forms. Each form (an allotrope ... Read more
ozone
The Columbia Encyclopedia, Sixth Edition , an allotropic form of the chemical element oxygen (see allotropy ). Pure ozone is an unstable, faintly bluish gas with a characteristic fresh, penetrating odor. The gas has a density of 2.144 ... Read more
diamond
The Columbia Encyclopedia, Sixth Edition mineral, one of two crystalline forms of the element carbon (see allotropy ), the hardest natural substance known, used as a gem and in industry. Properties Diamonds crystallize in the isometric system ... Read more
selenium
The Columbia Encyclopedia, Sixth Edition ... of the periodic table . In chemical activity and physical properties it resembles sulfur and tellurium. Selenium exhibits allotropy, appearing in a number of forms, including a red amorphous powder, a red crystalline material, and a gray crystalline metallike ... Read more
phosphorus
World Encyclopedia ... phosphoric acid for detergents and fertilizers. Small amounts are used in insecticides and in matches. Phosphorus exhibits allotropy . Properties: at.no. 15; r.a.m. 30.9738; r.d. 1.82 (white), 2.34 (red); m.p. 44.1°C (111.38°F) (white); b.p. 280 ... Read more

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Allotropy 2008