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Critical Thermodynamic Evaluation and Optimization of the FeO-Fe^sub 2^O^sub 3^-MgO-SiO^sub 2^ System
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A complete literature review, critical evaluation, and thermodynamic modeling of the phase diagrams and thermodynamic properties of all oxide phases in the FeO-Fe^sub 2^O^sub 3^-MgO-SiO^sub 2^ system at 1 bar total pressure are presented. Optimized model equations for the thermodynamic properties of all phases are obtained, which reproduce all available thermodynamic and phase-equilibrium data within experimental error limits from 25 °C to above the liquidus temperatures at all compositions ...
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ELECTROPHILIC HALOGENATION OF nido-5,6-C^sub 2^B^sub 8^H^sub 12^
Collection of Czechoslovak Chemical Communications
; Room-temperature chlorination of the dicarbaborane nido-5,6-C^sub 2^B^sub 8^H^sub 12^ (1) with CCl^sub 4^ in the presence of anhydrous AlCl^sub 3^ yielded a mixture of 7-Cl-5,6-C^sub 2^B^sub 8^H^sub 11^ (7-Cl-1) (yield 34 4-Cl-5,6-C^sub 2^B^sub 8^H^sub 11^ (4-Cl-1) (yield 20 3-Cl-5,6-C^sub 2^B^sub
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Thermodynamic Investigations of Cr^sub 3^C^sub 2^ and Reassessment of the Cr-C System
Metallurgical and Materials Transactions
; The Gibbs energies of formation for Cr^sub 3^C^sub 2^, Δ^sub f^G^sub Cr^sub 3^C^sub 2 have been obtained from electromotive force (EMF) measurements, in the temperature range 950 to 1150 K, using the following galvanic cells with CaF^sub 2^ single crystals as the electrolyte: Cr, CrF^sub 2^
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POLYHEDRAL MONOCARBABORANE CHEMISTRY. FUNCTIONALITY AND ISOMERISM: REACTIONS OF THE [6-Ph-nido-6-CB^sub 9^H^sub 11^]^sup -^ ANION WITH AMINOPYRIDINES NC^sub 5^H^sub 4^NH^sub 2^ TO YIELD NEUTRAL arachno AND closo TEN-VERTEX MONOCARBABORANE DERIVATIVES
Collection of Czechoslovak Chemical Communications
; Reaction of NC^sub 5^H^sub 4^-2-NH^sub 2^ with the [6-Ph-nido-6-CB^sub 9^H^sub 11sup -^ anion (1) in the presence of hydrated FeCl^sub 3^ gives [6-Ph-9-(NC^sub 5^H^sub 4^-2-NH^sub 2arachno-6-CB^sub 9^H^sub 12^] (4) and thence [1-Ph-2-(NC^sub 5^H^sub 4^-2-NH^sub 2closo-1-CB^sub 9^H^sub 8^] (5), in
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Thermodynamic Evaluation and Optimization of the MnO-Al^sub 2^O^sub 3^ and MnO-Al^sub 2^O^sub 3^-SiO^sub 2^ Systems and Applications to Inclusion Engineering
Metallurgical and Materials Transactions
; All available thermodynamic and phase-diagram data have been critically evaluated and optimized for the liquid-slag phase and for all solid phases at 1 bar pressure from 298 K to above the liquidus temperatures for the systems MnO-Al^sub 2^O^sub 3^ and MnO-Al^sub 2^O^sub 3^-SiO^sub 2^, and a
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Modeling of the Solubilities of NiO/NiAl^sub 2^O^sub 4^ and FeO/FeAl^sub 2^O^sub 4^ in Cryolite Melts at 1300 K
Metallurgical and Materials Transactions
; Experiments to measure the solubilities of NiOTNiAl^sub 2^O^sub 4^ and FeO/FeAl^sub 2^O^sub 4^ were performed, and the results confirmed existing literature values. The solubilities of NiAl^sub 2^O^sub 4^ and FeAl^sub 2^O^sub 4^ in Al^sub 2^O^sub 3^-saturated cryolite melts at 1300 K were modeled
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