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Singlet molecular oxygen quenching ability of carotenoids in a reversemicelle membrane mimetic system
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Singlet Molecular Oxygen Quenching Ability of Carotenoids in a Reversemicelle Membrane Mimetic System(para)
ABSTRACT
The influence of the medium heterogeneity upon the bimolecular rate constants for the physical quenching, k^sub q^, and chemical quenching, k^sub r^, of singlet molecular oxygen O^sub 2^(^sup 1^Delta^sub g^) by seven natural and three synthetic carotenoids (CAR) with different substituent patterns was studied in a reverse micelle system of sodium bis(2-ethylhexyl)sulfosuccinate, hexane and water. Because O^sub 2^(^sup 1^Delta^sub g^,) was generated inside the water pools of ...
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ELECTROPHILIC HALOGENATION OF nido-5,6-C^sub 2^B^sub 8^H^sub 12^
; Room-temperature chlorination of the dicarbaborane nido-5,6-C^sub 2^B^sub 8^H^sub 12^ (1) with CCl^sub 4^ in the presence of anhydrous AlCl^sub 3^ yielded a mixture of 7-Cl-5,6-C^sub 2^B^sub 8^H...
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POLYHEDRAL MONOCARBABORANE CHEMISTRY. FUNCTIONALITY AND ISOMERISM: REACTIONS OF THE [6-Ph-nido-6-CB^sub 9^H^sub 11^]^sup -^ ANION WITH AMINOPYRIDINES NC^sub 5^H^sub 4^NH^sub 2^ TO YIELD NEUTRAL arachno AND closo TEN-VERTEX MONOCARBABORANE DERIVATIVES
; Reaction of NC^sub 5^H^sub 4^-2-NH^sub 2^ with the [6-Ph-nido-6-CB^sub 9^H^sub 11^]^sup -^ anion (1) in the presence of hydrated FeCl^sub 3^ gives [6-Ph-9-(NC^sub 5^H^sub 4^-2-NH^sub 2^)-arachno-6-CB^sub 9^H^sub 12^] (4) and thence ...
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Modeling of the Solubilities of NiO/NiAl^sub 2^O^sub 4^ and FeO/FeAl^sub 2^O^sub 4^ in Cryolite Melts at 1300 K
; Experiments to measure the solubilities of NiOTNiAl^sub 2^O^sub 4^ and FeO/FeAl^sub 2^O^sub 4^ were performed, and the results confirmed existing literature values. The solubilities of NiAl^sub...
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Interaction of Singlet Molecular Oxygen with Melatonin and Related Indoles¶
; ABSTRACT Singlet molecular oxygen (^sup 1^O^sub 2^) is one of the major...2^O, deuterium oxide; k^sub obs^, observed rate constant; k^sub q^, quenching rate constant; MeOD, d^sub 1^ deuterated methanol...radicals but not with H^sub 2^O^sub 2^ (9). In addition, MLT...bengal ...
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Porphyrin-fullerene C^sub 60^ Dyads with High Ability to Form Photoinduced Charge-separated State as Novel Sensitizers for Photodynamic Therapy¶
; ...activities of a porphyrin-C^sub 60^ dyad (P-C^sub 60^) and its metal complex with Zn(II) (ZnP-C^sub 60^) were compared with 5...the attached fullerene C^sub 60^ moiety. The singlet molecular oxygen, O2(^sup 1^Δ^sub g^), productions (Φ...type II mechanism, singlet ...
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Molecular Basis for the Dynamic Strength of the Integrin a^sub 4^B^sub 1^/VCAM-1 Interaction
; ABSTRACT Intercellular adhesion mediated by integrin ?^sub 4^?^sub 1^ and vascular cell adhesion molecule-1 (VCAM-1) plays...leukocytes onto the vascular endothelium. Essential to the ?^sub 4^?^sub 1^/VCAM-1 interaction is its mechanical strength...
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Thermodynamics and Kinetics of the Formation of Al^sub 2^O^sub 3^/ MgAl^sub 2^O^sub 4^/MgO in Al-Silica Metal Matrix Composite
; The formation of Al^sub 2^O^sub 3^, MgAl^sub 2^O^sub 4^, and MgO has been widely studied in different Al base metal matrix composites, but the studies on thermodynamic aspects of the Al^sub 2^O^sub 3^/ MgAl^sub 2^O^sub 4^/MgO phase equilibria have...
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Quenching of Singlet Molecular Oxygen, O2(^sup 1^[Delta]^sub g^), by Dipyridamole and Derivatives
; ...the quenching of singlet molecular oxygen, O2(^sup 1^Δ^sub g^), by DIP and RA47 and...than the diffusion limit (k^sub t^ = 3.4-6.8 10^sup 8^ M...Calculation of ΔG^sub et^ associated with O2(^sup 1^Δ^sub g^) quenching corroborates...solutions (pH = 3.0), the ...
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Photoproduction and direct spectral detection of singlet molecular oxygen (O2) in keratinocytes stained with rose bengal
; ...which can be mediated by singlet molecular oxygen (^sup 1^O^sub 2^), a species that is very difficult...cells. We photosensitized ^sup 1^O^sub 2^ in cultured HaCaT keratinocytes...spectrum (1200-1350 nm) from ^sup 1^O^sub 2^ was strongest when the coverslip...
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A Direct Free Thyroxine (T^sub 4^) Immunoassay with the Characteristics of a Total T^sub 4^ Immunoassay
; Background: Direct free thyroxine (T^sub 4^) measurements have been linked to both T^sub 4^-binding serum protein concentrations and protein-bound T^sub 4^ concentrations. Whether this is evidence of a relationship to total T^sub 4^ concentrations...
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