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Kinetics of reduction of ferric iron in Fe(2)O(3)-CaO-SiO(2)-Al(2)O(3) slags under argon, CO-CO(2), or H(2)-H(2)O
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The rates of reduction of ferric iron in Fe^sub 2^O^sub 3^-CaO-SiO^sub 2^-Al^sub 2^O^sub 3^ slags containing 3 to 21 wt pct Fe^sub 2^O^sub 3^ under impinging argon, CO-CO^sub 2^, or H^sub 2^-H^sub 2^O have been studied at 1370 deg C under conditions of enhanced mass transfer in the slag using a rotating alumina disc just in contact with the slag surface. For a 6 wt pct Fe slag at a stirring speed of 900 rpm the observed reduction rates by 50 pct H^sub 2^-H^sub 2^O were a factor of 2 to 3 times higher than those by 50 pct CO-CO^sub 2^ and more than one order of magnitude higher than those ...
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ELECTROPHILIC HALOGENATION OF nido-5,6-C^sub 2^B^sub 8^H^sub 12^
; Room-temperature chlorination of the dicarbaborane nido-5,6-C^sub 2^B^sub 8^H^sub 12^ (1) with CCl^sub 4^ in the presence of anhydrous AlCl^sub 3^ yielded a mixture of 7-Cl-5,6-C^sub 2^B^sub 8^H...
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POLYHEDRAL MONOCARBABORANE CHEMISTRY. FUNCTIONALITY AND ISOMERISM: REACTIONS OF THE [6-Ph-nido-6-CB^sub 9^H^sub 11^]^sup -^ ANION WITH AMINOPYRIDINES NC^sub 5^H^sub 4^NH^sub 2^ TO YIELD NEUTRAL arachno AND closo TEN-VERTEX MONOCARBABORANE DERIVATIVES
; Reaction of NC^sub 5^H^sub 4^-2-NH^sub 2^ with the [6-Ph-nido-6-CB^sub 9^H^sub 11^]^sup -^ anion (1) in the presence of hydrated FeCl^sub 3^ gives [6-Ph-9-(NC^sub 5^H^sub 4^-2-NH^sub 2^)-arachno-6-CB^sub 9^H^sub 12^] (4) and thence ...
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Solid-Solid Reactions in the Ca^sub 3^(AsO^sub 4^)^sub 2^-Ca^sub 2^SiO^sub 4^-CaSO^sub 4^ Ternary System at Elevated Temperatures
; Exploratory laboratory-scale tests were performed in order to identify the solid phases present in the Ca^sub 2^SiO^sub 4^-Ca^sub 3^(AsO^sub 4^)^sub 2^ binary system and in the Ca^sub 2^SiO^sub 4^-Ca^sub 3^(AsO^sub 4^)2-CaSO^sub 4^-CaO system...
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Modeling of the Solubilities of NiO/NiAl^sub 2^O^sub 4^ and FeO/FeAl^sub 2^O^sub 4^ in Cryolite Melts at 1300 K
; Experiments to measure the solubilities of NiOTNiAl^sub 2^O^sub 4^ and FeO/FeAl^sub 2^O^sub 4^ were performed, and the results confirmed existing literature values. The solubilities of NiAl^sub...
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Oxygen evolution in photosynethsis: Simple analytical solution for the Kok model
; ...states and for oxygen evolution is presented here. When only the S^sub 1^ state is present...reaction center to b^sub 6^f complex can...semiquinone, and oxygen evolution provide a basis...observed pattern of oxygen evolution by introducing five discrete ...
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Molecular Basis for the Dynamic Strength of the Integrin a^sub 4^B^sub 1^/VCAM-1 Interaction
; ABSTRACT Intercellular adhesion mediated by integrin ?^sub 4^?^sub 1^ and vascular cell adhesion molecule-1 (VCAM-1) plays...leukocytes onto the vascular endothelium. Essential to the ?^sub 4^?^sub 1^/VCAM-1 interaction is its mechanical strength...
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Thermodynamics and Kinetics of the Formation of Al^sub 2^O^sub 3^/ MgAl^sub 2^O^sub 4^/MgO in Al-Silica Metal Matrix Composite
; The formation of Al^sub 2^O^sub 3^, MgAl^sub 2^O^sub 4^, and MgO has been widely studied in different Al base metal matrix composites, but the studies on thermodynamic aspects of the Al^sub 2^O^sub 3^/ MgAl^sub 2^O^sub 4^/MgO phase equilibria have...
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A Direct Free Thyroxine (T^sub 4^) Immunoassay with the Characteristics of a Total T^sub 4^ Immunoassay
; Background: Direct free thyroxine (T^sub 4^) measurements have been linked to both T^sub 4^-binding serum protein concentrations and protein-bound T^sub 4^ concentrations. Whether this is evidence of a relationship to total T^sub 4^ concentrations...
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Flash-Induced Oxygen Evolution in Photosynthesis: Simple Solution for the Extended S-State Model that includes Misses, Double-Hits, Inactivation, and Backward-Transitions
; ...time. According to oxygen evolution occurs in independent...states of PSII (S^sub 0^, S^sub 1^, S^sub 2^, S^sub 3^, and S^sub 4^) were introduced...oscillations of oxygen evolution. According to the...occurs during the S^sub 4^[arrow right]S...
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Quantitative characterization of the microstructure of two-phase TiB^sub 2^ + Al^sub 2^O^sub 3^ ceramics using mean integral curvature
; Two-phase TiB^sub 2^ + Al^sub 2^O^sub 3^ ceramics with an interconnected or dispersed TiB^sub 2^ (minor)-phase microstructure can be produced by variations in processing parameters. A standard method of quantitative characterization of the microstructural...
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