Mechanistic Studies on the Photochemical Deprotection of 3',5'-Dimethoxybenzoin Esters

Photochemistry and Photobiology | September 1, 2006| | Copyright

ABSTRACT

Several mechanistic alternatives proposed for the photochemical deprotection of dimethoxybenzoin esters are presented. Both experimental and theoretical evidence suggest the mechanism is heterolysis of the singlet excited state to form a carboxylate and the α-ketocation. The α-ketocation has been observed by transient spectroscopy. We propose the α-ketocation undergoes electrocyclization to an intermediate with extended conjugation, whose deprotonation gives the observed benzofuran product. A Brønsted study of the rates of benzofuran formation with dimethoxybenzoin ...

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