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A Dictionary of Biology | 2004 | © A Dictionary of Biology 2004, originally published by Oxford University Press 2004. (Hide copyright information) Copyright

haem (heme) An iron-containing molecule (see formula) that binds with proteins as a cofactor or prosthetic group to form the haemoproteins. These are haemoglobin, myoglobin, and the cytochromes. Essentially, haem comprises a porphyrin with its four nitrogen atoms holding the iron(II) atom as a chelate. This iron can reversibly bind oxygen (as in haemoglobin and myoglobin) or (as in the cytochromes) conduct electrons by conversion between the iron(II) and iron(III) series.

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