phosphorescence
The Oxford Companion to Ships and the Sea
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2006
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© The Oxford Companion to Ships and the Sea 2006, originally published by Oxford University Press 2006. (Hide copyright information)
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phosphorescence, a faint blue-green light emitted from the sea at night, either as a continuous glow or a series of tiny flashes. This light is produced by the bioluminescence of living organisms ranging from bacteria to the many species of
plankton, including phytoplankton, especially dinoflagellates. On moonless nights in late summer, flashes of light in the surf breaking on sandy beaches are often produced by the appropriately named dinoflagellate
Noctiluca. Bioluminescence is produced by a chemical reaction and serves a wide range of functions. Deep in the ocean where there is little or no daylight, almost every species has some light-producing capability. The wavelength of the blue-green light emitted is the same as the residual daylight that penetrates to the greatest depths in the ocean. In a darkened environment signalling by light is an effective way of communicating with other animals of the same species, especially to confirm species identification during mating, or to indicate a readiness to mate. Lights are also used on lures to tempt prey within range. Bright flashes are used as a defence mechanism, startling the attacker. Glowing smoke screens or even phantom decoys are also used to avoid attack. In an environment where the brightest daylight comes from directly overhead, animals are particularly vulnerable to attack from below by predators that pick out their silhouettes. Lights arranged along the underside of
fish and some
Crustacea like prawns break up the silhouette, and act as a form of camouflage.
Some phosphorescent phenomena have a physical origin. During electrical storms structures like a ship's mast can become surrounded by a corona of electrical discharges giving an eerie bluish light called
St Elmo's Fire.
Bibliography
Herring, P. , The Biology of the Deep Ocean (2002).
www.lifesci.ucsb.edu/~biolum/www.islandnet.com/~see/weather/elements/stelmo.htm
M. V. Angel
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Analysis of phosphorescence decay in heterogeneous systems: Consequences of finite excitation flesh duration
Magazine article from: Photochemistry and Photobiology; 6/1/1999; ; 700+ words
; ABSTRACT Analysis of phosphorescence lifetimes using the SternVolmer...the Stern-Volmer ratio of phosphorescence intensities cannot be employed...time-resolved analysis of phosphorescence or fluorescence decays using...
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Room temperature phosphorescence from tryptphan and halogenated tryptophan analogs in amorphous sucrose
Magazine article from: Photochemistry and Photobiology; 8/1/1999; ; 700+ words
; ABSTRACT Tryptophan phosphorescence lifetime and quantum yield are...to the local environment. The phosphorescence from tryptophan analogs, however...data on the room temperature phosphorescence of tryptophan, 4-, 5- and...
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Characterization of F-Actin Tryptophan Phosphorescence in the Presence and Absence of Tryptophan-Free Myosin Motor Domain
Magazine article from: Biophysical Journal; 8/1/2004; ; 700+ words
; ...an analysis of steady-state tryptophan phosphorescence spectra and phosphorescence decay kinetics over a temperature range...discoideum to actin caused red shifts in the phosphorescence spectrum of two internal Trp residues of...
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A Review of Heavy-Atom-Induced Room-Temperature Phosphorescence: a Straightforward Phosphorimetric Method
Magazine article from: Critical Reviews in Analytical Chemistry; 1/1/2005; ; 700+ words
; ...induced, room-temperature phosphorescence (HAI-RTP), a new technique...triplet states and thus emit intense phosphorescence. Keywords heavy-atom-induced, room-temperature phosphorescence INTRODUCTION Luminescence is a...
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Differentiation of the Local Structure Around Tryptophan 51 and 64 in Recombinant Human Erythropoietin by Tryptophan Phosphorescence
Magazine article from: Photochemistry and Photobiology; 9/1/2008; ; 700+ words
; ...positions 51, 64 and 88 whose phosphorescence emission may represent a sensitive...This report characterizes the phosphorescence properties (spectral energy, thermal spectral relaxation and phosphorescence lifetime), from low temperature...
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Erythrosin B Phosphorescence Monitors Molecular Mobility and Dynamic Site Heterogeneity in Amorphous Sucrose
Magazine article from: Biophysical Journal; 5/1/2005; ; 700+ words
; ...steady-state and time-resolved phosphorescence of erythrosin B to monitor mobility...as a function of temperature. The phosphorescence intensity (lifetime), emission...excitation and systematic variations in the phosphorescence lifetime with wavelength indicated...
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Time-resolved Singlet Oxygen Phosphorescence Measurements from Photosensitized Experiments in Single Cells: Effects of Oxygen Diffusion and Oxygen Concentration
Magazine article from: Photochemistry and Photobiology; 9/1/2008; ; 700+ words
; ...sup 1^Δ^sub g^), phosphorescence experiments have been performed in...a^sup 1^Δ^sub g^) phosphorescence data and sensitizer triplet state...931;^sub g^^sup -^) phosphorescence at 1270 nm has proved to be a most...
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Quenching Platinum Octaethylporphine Phosphorescence in Solution by Poly(ferrocenylsilane)[dagger]
Magazine article from: Photochemistry and Photobiology; 1/1/2006; ; 700+ words
; ...platinum octaethylporphine (PtOEP) phosphorescence in toluene solution. The phosphorescence quenching process was interpreted in...backbone is a good quencher for PtOEP phosphorescence. Quenching by the polymer involves...
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Hued afterglow: fingerprinting diamonds via phosphorescence.(This Week)
Magazine article from: Science News; 1/12/2008; ; 700+ words
; The eerie phosphorescence displayed by a rare form of blue...suggest. [ILLUSTRATION OMITTED] Phosphorescence, a "glow-in-the-dark...seconds and then measured its phosphorescence at various wavelengths. Reddish...
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Intramolecular Quenching of Tryptophan Phosphorescence in Short Peptides and Proteins¶
Magazine article from: Photochemistry and Photobiology; 5/1/2005; ; 700+ words
; ABSTRACT The phosphorescence lifetime (τ) of tryptophan...and Phe are able to quench Trp phosphorescence at a detectable rate (k^sub...in proteins that exhibit long phosphorescence lifetimes at ambient temperature...
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phosphorescence
Book article from: The Columbia Encyclopedia, Sixth Edition
phosphorescence , luminescence produced by certain...energy or other types of energy. Phosphorescence is distinguished from fluorescence...radiation causing it has ceased. Phosphorescence was first observed in the 17th cent...
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Becquerel, Antoine-Henri
Book article from: Chemistry: Foundations and Applications
...centered around solar radiation and phosphorescence, as these are phenomena that his...polarized light, the phenomenon of phosphorescence (in which certain compounds glow...which has a strong but short-lived phosphorescence. He carefully wrapped his photographic...
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Bioluminescence
Book article from: Chemistry: Foundations and Applications
...light differ from fluorescence and phosphorescence, which involve the absorption of...the processes of fluorescence and phosphorescence also occur in living organisms and...that have described the apparent "phosphorescence" of the sea. Dinoflagellates are...
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Luminescence
Book article from: Science of Everyday Things
...of luminescence, fluorescence and phosphorescence, distinguished by the delay in reaction...radiation. The ancients observed phosphorescence in the form of a glow emitted by the...chemical phosphor, but, in fact, phosphorescence has nothing at all to do with burning...
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Chemiluminescence
Book article from: Chemistry: Foundations and Applications
...phosphorus. It is unfortunate that the chemiluminescent glow of phosphorus gave rise to the term "phosphorescence." Scientifically, phosphorescence is a process whereby absorbed photons are emitted at a later time, as exemplified by the glow...
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