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quantum mechanics

World Encyclopedia | 2005 | © World Encyclopedia 2005, originally published by Oxford University Press 2005. (Hide copyright information) Copyright

quantum mechanics Branch of physics that uses the quantum theory to explain the behaviour of elementary particles. According to quantum theory, all radiant energy emits and absorbs in multiples of tiny ‘packets’ or quanta. Atomic particles have wavelike properties and thereby exhibit a wave-particle duality. Sometimes the wave properties dominate, and other times the particle aspects dominate. The quantum theory uses four quantum numbers to classify electrons and their atomic states: energy level, angular momentum, energy in a magnetic field and spin. The exclusion principle says any two electrons in an atom cannot have the same energy and spin. A change in an electron, atom or molecule from one quantum state to another, called a quantum jump, is accompanied by the absorption or emission of a quantum. The quantum field theory seeks to explain this exchange. The strong interactions between quarks and between protons and neutrons are described by quantum chronodynamics. The idea that energy radiates and absorbs in packets was first proposed by German theoretical physicist Max Planck in 1900 to explain black body radiation. Using Planck's work, German-born US physicist Albert Einstein quantized light radiation, and in 1905 explained the photoelectric effect. He chose the name of photon for a quantum of light energy. In 1913, Danish physicist Niels Bohr used quantum theory to explain atomic structure and atomic spectra, showing the relationship between the energy levels of an atom's electrons and the frequencies of radiation emitted or absorbed by the atom. In 1924, French physicist Louis de Broglie suggested that particles have wave properties, the converse having been postulated in 1905 by Albert Einstein. In 1926, Austrian physicist Erwin Schrödinger used this hypothesis of wave mechanics to predict particle behaviour on the basis of wave properties, but a year earlier German physicist Werner Heisenberg had produced a mathematical equivalent to Schrödinger's theory without using wave concepts at all. In 1928, English physicist Paul Dirac unified these approaches while incorporating relativity into quantum mechanics (especially when large speeds are involved). This predicted the existence of antimatter and helped develop the quantum electrodynamics theory of how charged subatomic particles interact within electric and magnetic fields. The superstring theory provides a possible answer to gravitational interaction. The complete, modern theory of quantum mechanics is the quantum field theory of quantum electrodynamics, also known as the quantum theory of light. It was derived by US theoretical physicist Richard Feynman in the 1940s. The theory predicts that a collision between an electron and a proton should result in the production of a photon of electromagnetic radiation, which is exchanged between the colliding particles. Quantum mechanics remains a difficult system because the uncertainty principle, formulated in 1927 by Heisenberg, states that nothing on the atomic scale can be measured or observed without disturbing it. This makes it impossible to know the position and momentum of a particle at the same time.

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