Treasure of the Past VI: Standard Potential of the Silver-Silver-Chloride Electrode from 0[degrees] to 95[degrees] C and the Thermodynamic Properties of Dilute Hydrochloric Acid Solutions.(Statistical Data Included)

Journal of Research of the National Institute of Standards and Technology | March 1, 2001| | Copyright

From electromotive-force measurements of the cell without liquid junction:

Pt; [H.sub.2], HCl (m), AgCl; Ag

through the range 0[degrees] to 95[degrees] C, calculations have been made of (1) the standard potential of the silver-silver-ehloride electrode, (2) the activity eoeffieient of hydrochloric aeid in aqueous solutions from m (molality) = 0 to m=0.1 and from 0[degrees] to 90[degrees] C, (3) the relative partial molal heat content of hydrochloric acid, and (4) the relative partial molal heat capacity of hydrochloric acid.

The extrapolations ...

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