The noble hydrocarbons.(Review)

Chemistry and Industry | June 4, 2001| | Copyright

Classics in hydrocarbon chemistry

Henning Hopf

Chichester: Wiley-VCH, 2000

Pp1+547, [pound]32.50, ISBN 3 527 29606 9

In 1968, in a classic paper describing the intermediacy of [[CH.sub.5].sup.+] and related carbonium ions in the protonation of alkanes, Nobel Laureate George Olah recommended that saturated hydrocarbons should only be referred to as alkanes, not paraffins. This suggestion was based on Olah's demonstration of the high chemical reactivity of alkanes in strong acid systems, which was 'no onger compatible with a name referring ...

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