New physical chemistry research from S. Tsushima et al outlined.

Chemicals & Chemistry | December 5, 2008 | Copyright

According to a study from Dresden, Germany, "The redox potential of the Pu(VII)/Pu(VIII) couple was studied by density functional theory calculations. The spin-orbit effect was corrected at the CASSCF level."

"The redox potential (relative to the standard hydrogen potential) of the Pu(VII)/Pu(VIII) couple in alkaline solution was found to vary from 4.36 to 1.06 V depending on the number of Pu-O oxo bonds, coordination numbers, and coordination modes. The redox potential drops substantially as the number of Pu-O oxo bonds increases. Pu(VIII) may be synthesized in ...

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