Mixed-dimer formation in binary systems of 4-substituted benzoic acids and structure considerations (1).(Report) Canadian Journal of Chemistry | June 1, 2008| | COPYRIGHT 2008 NRC Research Press. This material is published under license from the publisher through the Gale Group, Farmington Hills, Michigan.  All inquiries regarding rights should be directed to the Gale Group. (Hide copyright information) Copyright

Abstract: The phase behavior of binary systems of 4-substituted benzoic acids is governed by the formation of mixed dimers. This study was conducted to determine the effect of the components' structural difference on mixed-dimer formation in crystalline and liquid-crystalline phases. The phase diagrams of two systems, with 4-[(S)-(-)-2-methylbutoxy]benzoic acid (MBOBA) as one component and 4-(hex-5-enoxy)benzoic acid (HOBA) and 4-(dec-9-enoxy)benzoic acid (DOBA), respectively, as the second component, were determined by differential scanning calorimetry, polarized-light ...

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