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Asymmetric nitroaldol reaction with a chiral copper complex derived from D-tartaric acid.(Report)
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Abstract: A novel catalytic enantioselective Henry reaction has been developed using a tetradentate copper complex derived from D-tartaric acid to give [beta]-nitroalkanols in moderate to high enantioselectivities.
Key words: Henry reaction, D-tartaric acid, enantioselective, [beta]-nitroalkanols.
Resume : On a developpe le champ d'application de la nouvelle reaction catalytique enantioselective d'Henry en utilisant le complexe tetradentate de cuivre de l'acide D-tartrique pour preparer des [beta]-nitroalcanols avec des enantioselectivites allant de ...
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