Organic chemistry.(research) From: Chemistry and Industry | Date: April 17, 2006| Author: | COPYRIGHT 2006 Society of Chemical Industry. This material is published under license from the publisher through the Gale Group, Farmington Hills, Michigan.  All inquiries regarding rights should be directed to the Gale Group.Copyright information

Diradical dications can be stable

Radical cations are still rarely successfully prepared and characterised, so in their paper in the Journal of Organic Chemistry, the research teams of Walcarius and Schneider proudly proclaim their unusual diradical dication products as 'robust'. The para-binaphthyl design ensures a high degree of non-coplanarity between the two electron-donating halves of the precursor molecule 1. Electrochemical oxidation of 1 produces the diradical dications, which are stable in solution and in the solid state. Electron paramagnetic resonance and cyclic ...

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